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TRIBUTYLSTANNYLACETYLENE

TRIBUTYLSTANNYLACETYLENE structure

CAS No.: 994-89-8

Chemical Name:: TRIBUTYLSTANNYLACETYLENE

Synonyms: TRIBUTYLETHYNYLSTANNANE;SKL1071;NSC 203201;ETHYNYLTRIBUTYLIN;ethenyltributyltin;ETHYNYLTRIBUTYLTIN;TRIBUTYL(ETHYNYL)TIN;TribuTylTin aceTylene;TRI-N-BUTYLETHYNYLTIN;ETHYNYLTRI-N-BUTYLTIN

CBNumber:: CB0161680

Molecular Formula:: C14H28Sn

Molecular Weight:: 315.08

MDL Number:: MFCD00009420

MOL File:: 994-89-8.mol

MSDS File:: SDS

Last updated:2023-04-23 13:52:06

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TRIBUTYLSTANNYLACETYLENE Properties

Boiling point	70 °C0.2 mm Hg(lit.)
Density	1.089 g/mL at 25 °C(lit.)
refractive index	n20/D 1.476(lit.)
Flash point	165 °F
storage temp.	Sealed in dry,Store in freezer, under -20°C
Specific Gravity	1.089
Water Solubility	Not miscible or difficult to mix with water.
Sensitive	Moisture Sensitive
BRN	3537659
InChIKey	YEMJHNYABQHWHL-UHFFFAOYSA-N
CAS DataBase Reference	994-89-8(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS06,GHS08,GHS09

Signal word

Danger

Hazard statements

H301-H312-H315-H319-H360FD-H372-H410

Precautionary statements

P202-P273-P280-P301+P310-P302+P352+P312-P305+P351+P338

Hazard Codes

T,N,Xn

Risk Statements

21-25-36/38-48/23/25-50/53

Safety Statements

35-36/37/39-45-60-61

RIDADR

UN 2788 6.1/PG 3

WGK Germany

TSCA

HazardClass

6.1

PackingGroup

III

HS Code

29319090

NFPA 704

	2
3		0

TRIBUTYLSTANNYLACETYLENE price More Price(19)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	275069	Ethynyltributylstannane 95%	994-89-8	1g	$90.7	2023-06-20	Buy
Sigma-Aldrich	275069	Ethynyltributylstannane 95%	994-89-8	5g	$109	2023-06-20	Buy
Alfa Aesar	L20178	Ethynyltri-n-butyltin, 96%	994-89-8	1g	$75.5	2023-06-20	Buy
Alfa Aesar	L20178	Ethynyltri-n-butyltin, 96%	994-89-8	5g	$246	2023-06-20	Buy
GFS CHEMICALS	10112	TRIBUTYLSTANNYLACETYLENE	994-89-8	5G	$230.2	2021-12-16	Buy

Product number	Packaging	Price	Buy
275069	1g	$90.7	Buy
275069	5g	$109	Buy
L20178	1g	$75.5	Buy
L20178	5g	$246	Buy
10112	5G	$230.2	Buy

TRIBUTYLSTANNYLACETYLENE Chemical Properties,Uses,Production

Chemical Properties

clear colorless liquid

Uses

Ethynyltributylstannane can be used as a reactant to prepare:

Terminal arylacetylene derivatives by Stille coupling reaction with aryl halides in the presence of palladium catalyst.
1,4-bis(tributylstannyl)but-1-en-3-yne by dimerization using a metal complex having bulky ligand catalyst system.
Isoquinolone derivatives by reacting with benzotriazinones via denitrogenative insertion in the presence of nickel catalyst.
Enyne key intermediates in the total synthesis of (-)-acutumine and (-)-dechloroacutumine.

Uses

Used to prepare vinylstannanes and stannylisoxazoles. Ethynylation reagent for azaaromatics.

Purification Methods

Purify it by dissolving the reagent (ca 50g) in heptane (250mL), washing it with H2O (100mL), drying (MgSO4), evaporating and distilling in a vacuum. It has IR: max 3280 ( C), 2950, 2850, 2005 (CC), 1455, 1065 and 865cm-1. [Bottaro et al. J Org Chem 46 5221 1981, Stille & Simpson J Am Chem Soc 109 2138 1987, Zavgorodnii et al. J Gen Chem USSR (Engl Edn) 37 1469 1967.]

TRIBUTYLSTANNYLACETYLENE Preparation Products And Raw materials

Raw materials

Preparation Products

ETHYL 5-TRIBUTYLSTANNANYLISOXAZOLE-3-CARBOXYLATE 4,4'-DIETHYNYLBIPHENYL 1-BROMO-2-ETHYNYLBENZENE Cyanoacetylene

TRIBUTYLSTANNYLACETYLENE Suppliers

Global( 152)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49390	58
career henan chemical co	+86-0371-86658258 15093356674;	factory@coreychem.com	China	29826	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	+8613580539051	joe@yuhengpharm.com	CHINA	21149	58
Kindchem(Nanjing)Co.,Ltd	+86-025-025-85281586 +8618651653755	sales@kindchem.cn	China	1227	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418671	sales@tnjchem.com	China	34572	58
Shaanxi Dideu Medichem Co. Ltd	+86-029-89586680 +86-18192503167	1026@dideu.com	China	9271	58
Dayang Chem (Hangzhou) Co.,Ltd.	571-88938639 +8617705817739	info@dycnchem.com	CHINA	52867	58
Henan Alfa Chemical Co., Ltd	+8618339805032	alfa4@alfachem.cn	China	12755	58
Wuhan Demeikai Biotechnology Co., Ltd	+8618942921723	info@dmksw.xin	China	723	58

Supplier	Advantage
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	58
Kindchem(Nanjing)Co.,Ltd	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Shaanxi Dideu Medichem Co. Ltd	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
Henan Alfa Chemical Co., Ltd	58
Wuhan Demeikai Biotechnology Co., Ltd	58

View Lastest Price from TRIBUTYLSTANNYLACETYLENE manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2022-02-22	Tributylstannylacetylene 994-89-8	US $0.00 / KG	1KG	97.6%	100 tons	Honest Joy Holdings Limited
2021-08-12	TRIBUTYLSTANNYLACETYLENE 994-89-8	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd
2019-12-25	TRIBUTYLSTANNYLACETYLENE 994-89-8	US $1.00 / KG	1KG	99%	200kg	Career Henan Chemical Co

Tributylstannylacetylene
994-89-8
US $0.00 / KG
97.6%
Honest Joy Holdings Limited

TRIBUTYLSTANNYLACETYLENE
994-89-8
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

TRIBUTYLSTANNYLACETYLENE
994-89-8
US $1.00 / KG
99%
Career Henan Chemical Co

TRIBUTYLSTANNYLACETYLENE Spectrum

TRIBUTYLSTANNYLACETYLENE(994-89-8)IR TRIBUTYLSTANNYLACETYLENE(994-89-8)Raman

994-89-8(TRIBUTYLSTANNYLACETYLENE)Related Search:

YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE Scandium trifluoromethanesulfonate GALLIUM(III) TRIFLUOROMETHANESULFONATE Diethyl acetylenedicarboxylate 2-Ethynyl-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Dimethyl acetylenedicarboxylate Acetylenedicarboxylic acid Tributyltin chloride Acetylene PHENYLETHYNYLTRI-N-BUTYLTIN

BIS(TRI-N-BUTYLSTANNYL)ACETYLENE TRIBUTYL(1-PROPYNYL)TIN TRIBUTYLSTANNYLACETYLENE 1-TRIBUTYLSTANNYL-2-TRIMETHYLSILYLACETYLENE

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Ethynyltri-n-butylstannane~Tri-n-butyl(ethynyl)tin~Tri-n-butylstannylacetylene Ethynyltri-n-butyltin,97% TRI-N-BUTYLETHYNYLTIN TRI-N-BUTYLSTANNYLACETYLENE TRIBUTYLSTANNYLACETYLENE TRIBUTYL(ETHYNYL)TIN Tributylethynylstannane,98% Tributylethynylstannane,95% ethynyltri-n-butylstannane ETHYNYLTRIBUTYLIN TribuTylTin aceTylene ethenyltributyltin ETHYNYLTRIBUTYLSTANNANE ETHYNYLTRIBUTYLTIN ETHYNYLTRI-N-BUTYLTIN Tributylstannylacetylene ,95% Ethynyltributylstaane Tributylethynylstannane, 95% 2.5GR (Tributylstannyl)acetylide (Tributylstannyl)ethyne NSC 203201 Ethynyltributylstannane 95% Stannane, tributylethynyl- Ttibutylstannylacetylene TRIBUTYLSTANNYLACETYLENE ISO 9001：2015 REACH SKL1071 TRIBUTYLETHYNYLSTANNANE Acetynyltrin-butyltin 994-89-8 HCCSnCH2CH2CH2CH33 HC8801CSnCH2CH2CH2CH33 C14H28Sn C4H93SnCCH Classes of Metal Compounds Sn (Tin) Compounds Typical Metal Compounds Functionalized Acetylenes Acetylenes Organotin Organotins Organometallic Reagents organic tin Stannanes Acetylenes Classes of Metal Compounds Functionalized Acetylenes Sn (Tin) Compounds Typical Metal Compounds