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(1S)-(+)-Camphor-10-sulphonic acid

CAS No.
3144-16-9
Chemical Name:
(1S)-(+)-Camphor-10-sulphonic acid
Synonyms
CSA;CaMsylate;MOT;D-CAMPHOR-10-SULFONIC ACID;camphersulfosaeure;camphorsulfonicacid;D-CAMPHORSULPHONIC ACID;D-10-CAMPHORSULFONIC ACID;D(-)-CAMPHORSULFONIC ACID;MOT2
CBNumber:
CB0395928
Molecular Formula:
C10H16O4S
Molecular Weight:
232.3
MDL Number:
MFCD00064157
MOL File:
3144-16-9.mol
MSDS File:
SDS
Last updated:2024-03-29 23:06:43

(1S)-(+)-Camphor-10-sulphonic acid Properties

Melting point 196-200 °C (dec.)(lit.)
alpha 22 º (589nm, c=20, H2O 25 ºC)
Boiling point 344.46°C (rough estimate)
Density 1.2981 (rough estimate)
refractive index 21.5 ° (C=5, H2O)
storage temp. Store below +30°C.
solubility Exhibit moderate solubility in HCCl.
pka 1.17±0.50(Predicted)
form Crystalline Powder
color White to off-white
PH 0.3 (200g/l, H2O)
optical activity [α]20/D +21.5±1°, c = 10% in H2O
Water Solubility SOLUBLE
Sensitive Hygroscopic
Merck 14,1734
BRN 2809675
Stability Stable. Protect from moisture. Incompatible with strong oxidizing agents, strong bases.
InChIKey MIOPJNTWMNEORI-GMSGAONNSA-N
CAS DataBase Reference 3144-16-9(CAS DataBase Reference)
FDA UNII 9TLZ01S15L
EPA Substance Registry System Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S,4R)- (3144-16-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H290-H314
Precautionary statements  P234-P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45-25-27
RIDADR  UN 3261 8/PG 2
WGK Germany  3
RTECS  ED1550000
3-10
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29147090
NFPA 704
0
3 0

(1S)-(+)-Camphor-10-sulphonic acid price More Price(42)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich SRP5102 Mortalin (47-end), GST tagged human recombinant, expressed in baculovirus infected Sf9 cells, ≥70% (SDS-PAGE), buffered aqueous glycerol solution 753517-83-8 50μG $360 2024-03-01 Buy
Sigma-Aldrich 21360 (+)-Camphor-10-sulfonic acid purum, ≥98.0% (T) 3144-16-9 100g $55.3 2024-03-01 Buy
Sigma-Aldrich 8.22311 (1S)-(+)-Camphor-10-sulfonic acid for resolution of racemates for synthesis 3144-16-9 100g $56.7 2024-03-01 Buy
Sigma-Aldrich 21360 (+)-Camphor-10-sulfonic acid purum, ≥98.0% (T) 3144-16-9 500g $125 2024-03-01 Buy
Sigma-Aldrich 1087520 (+)-Camphor-10-sulfonic acid United States Pharmacopeia (USP) Reference Standard 3144-16-9 100mg $472 2024-03-01 Buy
Product number Packaging Price Buy
SRP5102 50μG $360 Buy
21360 100g $55.3 Buy
8.22311 100g $56.7 Buy
21360 500g $125 Buy
1087520 100mg $472 Buy

(1S)-(+)-Camphor-10-sulphonic acid Chemical Properties,Uses,Production

Synthesis

(1S)-(+)-Camphor-10-sulphonic acid can be obtained from natural camphor by brominated sulfonation .

Chemical Properties

white to light beige powder

Uses

(1S)-(+)-Camphor-10-sulfonic acid is used as stabilizer. (+)-(1S)-camphor-10-sulfonic acid being a very effective resolving agent. . Chiral polyaniline(PANI) nanofibers were synthesized via facilely potentiostatic electropolymerization method without template in the presence of(1S)-(+)camphor-10-sulfonic acid(D-CSA) or(1R)-(-)camphor-10-sulfonic acid(L-CSA) as the dopant. Synthesis of QUATs derived from (1S)-(+)camphor-10-sulfonic acid.

Uses

Used as a resolving agent, and as a catalyst for coupling dipeptides.

Definition

ChEBI: (S)-camphorsulfonic acid is the S enantiomer of camphorsulfonic acid. It is a conjugate acid of a (S)-camphorsulfonate. It is an enantiomer of a (R)-camphorsulfonic acid.

Purification Methods

Crystallise the acid from ethyl acetate and dry it under vacuum (deliquescent). [Loudon J Chem Soc 823 1933, Komppa J Prakt Chem 162 19 1943, Beilstein 11 IV 642.] See above for RS-isomer.

(1S)-(+)-Camphor-10-sulphonic acid Preparation Products And Raw materials

Global( 650)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12456 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 5993 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 7845 58
airuikechemical co., ltd.
+undefined86-15315557071 sales02@airuikechemical.com China 994 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15928 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1807 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58

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View Lastest Price from (1S)-(+)-Camphor-10-sulphonic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(1S)-(+)-Camphor-10-sulphonic acid pictures 2024-04-26 (1S)-(+)-Camphor-10-sulphonic acid
3144-16-9
US $100.00-95.00 / KG 1KG 99% EX:20T Hebei Yime New Material Technology Co., Ltd.
d-camphorsulfonic acid pictures 2024-03-29 d-camphorsulfonic acid
3144-16-9
US $0.00-0.00 / Kg 1Kg 99.9% 200tons airuikechemical co., ltd.
(1S)-(+)-Camphor-10-sulphonic acid pictures 2024-03-23 (1S)-(+)-Camphor-10-sulphonic acid
3144-16-9
US $10.00-0.10 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
D-CAMPHORSULFONIC ACID D(-)-CAMPHORSULPHONIC ACID D-REYCHLER'S ACID D-OXO-10-BORNANESULFONIC ACID (+)-BETA-CAMPHORSULFONIC ACID (+)-CAMPHOR-10-SULFONIC ACID (+)-CAMPHOR-10-SULFONIC ACID (BETA) (1S)-(+)-CAMPHOR-10-SULFONIC ACID (1S)-CAMPHOR-10-SULFONIC ACID (1S)-(+)-CAMPHOR-10-SULPHONIC ACID (1S)-BETA-CAMPHOR-10-SULFONIC ACID (1S,4R)-2-OXO-10-BORNANESULFONIC ACID (1S)-(+)-10-CAMPHORSULFONIC ACID 2-Oxobornane-10-sulphonic acid (+)-10-CAMPHORSULFONIC ACID (S)-(+)-CAMPHOR-10-SULFONIC ACID (S)-7,7-DIMETHYL-2-OXOBICYCLO[2.2.1]HEPTANE-1-METHANESULFONIC ACID 2-oxo-,(1s,4r)-(+)-10-bornanesulfonicaci 7,7-dimethyl-2-oxo-,(1S)-Bicyclo[2.2.1]heptane-1-methanesulfonicacid 7-dimethyl-2-oxo-(1s)-bicyclo(2.2.1)heptane-1-methanesulfonicaci 7-dimethyl-2-oxo-(1s)-bicyclo[2.2.1]heptane-1-methanesulfonicaci (+)-camphorsulfonicacid (1s)-(+)-10-camphorsulfonic Bicyclo2.2.1heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S,4R)- (1S)-(+)-CAMPHER-10-SULFONSURE DELTA-CAMPHORSULPHONICACID 2-oxo-, (1s,4r)-(+)-10-bornanesulfonic acid (1S)-(+)-10-Camphosulfonic acid D - Campho 10 Sulphonic Acid (1S)-(+)-Camphor-10-sulfonic acid, 98+% (1S)-(+)-Camphor-10-sulphonic acid, 98+% 1S-(+)-10-CAMPHORSULPHONIC ACID pure (1S)-(+)-10-CAMPHOR SULFONIC ACID AKA D-CAMPHOR SU (1S)-(+)-10-CAMPHORSULFONIC ACID 99% (+)-Camphor-10-sulfonic acid (β), (1S)-Camphor-10-sulfonic acid D(+)-10-Camphorsulfonic acid 99% (1S)-2-Oxo-10-bornanesulfonic acid (1S)-2-Oxo-7,7-dimethylbicyclo[2.2.1]heptane-1-methanesulfonic acid (1S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonic acid (1S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1β-methanesulfonic acid [1S,4R,(+)]-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonic acid (1S)-(+)-Camphor-10-sulfonic acid, 98+% (dry wt.), water <2% D-Camphor-10-surfonicacid reychler’sacid (+)-β-camphorsulfonic acid,(1S)-camphor-10-sulfonic acid D-(+)-CAMPHOR-10-SULFONIC ACID 99% (1S)-(+)-CAMPHOR-10-SULPHONIC ACIDCaMphorSulfonic Acid D(+)-10-Camphorsulfonic acid,99% (S)-(+)-Camphor-10-sulfonice Acid Camphor-beta-d-sulfonic acid (1S)-(+)-Camphor-10-Sulfonic Acid(Dry wt.), Water <2% (1S)-(+)-10-Camphorsulfonic acid ,99% (+)-Camphor-10-sulfonic acid,(+)-β-Camphorsulfonic acid, (1S)-(+)-Camphor-10-sulfonic acid (1S)-(+)-10-Camphorsulfonic acid,(+)-Camphor-10-sulfonic acid (β), (1S)-Camphor-10-sulfonic acid (1S)-(+)-10-Camphors ((1S,4R)-7,7-diMethyl-2-oxobicyclo[2.2.1]heptan-1-yl)Methanesulfonic acid GRP75 HSPA9