α-Methylcinnamaldehyde
- CAS No.
- 101-39-3
- Chemical Name:
- α-Methylcinnamaldehyde
- Synonyms
- α-Methylcinnamaldehyde;a-Methyl-trans-cinnaMaldehyde;A-METHYLCINNAMALDEHYDE;FEMA 2697;alpha-Methylzimtaldehyd;METHYL CINNAMIC ALDEHYDE;2-methyl-3-phenyl-2-propenal;METHYLZIMTALDEHYD;AKOS BBS-00003193;α-MethylcinnaMalde
- CBNumber:
- CB1694703
- Molecular Formula:
- C10H10O
- Molecular Weight:
- 146.19
- MDL Number:
- MFCD00006976
- MOL File:
- 101-39-3.mol
- MSDS File:
- SDS
Boiling point | 148-149 °C27 mm Hg(lit.) |
---|---|
Density | 1.047 g/mL at 25 °C(lit.) |
refractive index |
n |
FEMA | 2697 | ALPHA-METHYLCINNAMALDEHYDE |
Flash point | 175 °F |
storage temp. | Inert atmosphere,2-8°C |
solubility | Chloroform, Methanol (Slightly) |
form | Oil |
color | Colourless |
Odor | at 100.00 %. sweet cinnamon spicy cassia |
Odor Type | spicy |
Water Solubility | <0.1 g/100 mL at 21 ºC |
Sensitive | Air Sensitive |
JECFA Number | 683 |
BRN | 507514 |
Stability | Stable. Combustible. Incompatible with strong oxidizing agents, strong bases. |
InChIKey | VLUMOWNVWOXZAU-VQHVLOKHSA-N |
LogP | 2.68 |
CAS DataBase Reference | 101-39-3(CAS DataBase Reference) |
Substances Added to Food (formerly EAFUS) | ALPHA-METHYLCINNAMALDEHYDE |
FDA 21 CFR | 172.515 |
FDA UNII | 1C647N9853 |
NIST Chemistry Reference | 2-Propenal, 2-methyl-3-phenyl-(101-39-3) |
EPA Substance Registry System | .alpha.-Methylcinnamaldehyde (101-39-3) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H227-H335-H315-H319 | |||||||||
Precautionary statements | P210e-P261-P280a-P305+P351+P338-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 24/25 | |||||||||
WGK Germany | 1 | |||||||||
RTECS | GD6600000 | |||||||||
TSCA | Yes | |||||||||
HS Code | 29122900 | |||||||||
NFPA 704 |
|
α-Methylcinnamaldehyde price More Price(18)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 112275 | α-Methyl-trans-cinnamaldehyde 98% | 101-39-3 | 50g | $45.6 | 2024-03-01 | Buy |
Sigma-Aldrich | W269700 | α-Methylcinnamaldehyde ≥97%,FCC,FG | 101-39-3 | 10Kg | $273 | 2023-01-07 | Buy |
Sigma-Aldrich | W269700 | α-Methylcinnamaldehyde ≥97%, FCC, FG | 101-39-3 | sample-k | $52 | 2022-05-15 | Buy |
TCI Chemical | M0584 | alpha-Methylcinnamaldehyde >95.0%(GC) | 101-39-3 | 25g | $86 | 2024-03-01 | Buy |
TCI Chemical | M0584 | alpha-Methylcinnamaldehyde >95.0%(GC) | 101-39-3 | 500g | $345 | 2024-03-01 | Buy |
α-Methylcinnamaldehyde Chemical Properties,Uses,Production
Description
α-Methylcinnamaldehyde has a characteristic cinnamon-type odor with a soft, spicy flavor. May be synthesized by condensing benzaldehyde with propionic aldehyde in the presence of a 1% caustic soda solution; also by the controlled hydrogenation of α-methylcinnamic aldehyde.
Chemical Properties
α-Methylcinnamaldehyde has a characteristic cinnamon-type odor and a soft, spicy flavor.
Chemical Properties
yellow liquid
Occurrence
Reported found in peppermint oil, sherry and mint
Uses
alpha-Methyl-trans-cinnamaldehyde is a compound with antifungal activity for proteomics research use.
Preparation
By condensing benzaldehyde with propionic aldehyde in the presence of a 1% caustic soda solution; also by the controlled hydrogenation of α-methylcinnamic aldehyde
Taste threshold values
Taste characteristics at 30 ppm: spice, cinnamon, sweet, woody with a slight pungent and hot bite
Synthesis Reference(s)
The Journal of Organic Chemistry, 55, p. 2878, 1990 DOI: 10.1021/jo00296a059
Tetrahedron Letters, 28, p. 1263, 1987 DOI: 10.1016/S0040-4039(00)95341-3
General Description
Clear yellow liquid.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
alpha-Methylcinnamaldehyde is incompatible with strong oxidizing agents and strong bases.
Fire Hazard
alpha-Methylcinnamaldehyde is combustible.
Biochem/physiol Actions
α-Methyl trans cinnamaldehyde has antifungal activity. It is self coupled and complexed with Co(II) and Ni(II) to synthesize ligand and complexes.
Safety Profile
Moderately toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
α-Methylcinnamaldehyde Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5892 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12446 | 58 |
Hebei Kingfiner Technology Development Co.Ltd | +86-15532196582 +86-15373005021 | lisa@kingfinertech.com | China | 2990 | 58 |
Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 | admin@zlchemi.com | China | 3002 | 58 |
Shandong Deshang Chemical Co., Ltd. | +86-0531-8875-2665 +8613153039501 | info@deshangchem.com | China | 645 | 58 |
JINING XINHE CHEMICAL CO., LTD | +8615318402391 | sales@xinhepharma.com | China | 808 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18628 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21667 | 55 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +8618949832763 | info@tnjchem.com | China | 2989 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29888 | 58 |
View Lastest Price from α-Methylcinnamaldehyde manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-09-23 | Alpha-Methylcinnamaldehyde
101-39-3
|
US $9.00 / KG | 1KG | 99.8% | 100tons | Hebei Chuanghai Biotechnology Co,.LTD | ||
2024-09-13 | α-Methylcinnamaldehyde
101-39-3
|
US $8.90-5.20 / kg | 1kg | 99% | 10 tons | Shandong Deshang Chemical Co., Ltd. | ||
2024-07-22 | α-Methylcinnamaldehyde
101-39-3
|
US $0.00-0.00 / kg | 1kg | 98% | 10ton | JINING XINHE CHEMICAL CO., LTD |
- Alpha-Methylcinnamaldehyde
101-39-3
- US $9.00 / KG
- 99.8%
- Hebei Chuanghai Biotechnology Co,.LTD
- α-Methylcinnamaldehyde
101-39-3
- US $8.90-5.20 / kg
- 99%
- Shandong Deshang Chemical Co., Ltd.
- α-Methylcinnamaldehyde
101-39-3
- US $0.00-0.00 / kg
- 98%
- JINING XINHE CHEMICAL CO., LTD