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Thiophanate-methyl

Description References
Thiophanate-methyl
Thiophanate-methyl
CAS No.
23564-05-8
Chemical Name:
Thiophanate-methyl
Synonyms
DO;nf44;ROKO;ditek;f6385;COVER;SIGMA;3336G;easout;pei190
CBNumber:
CB7249734
Molecular Formula:
C12H14N4O4S2
Formula Weight:
342.39
MOL File:
23564-05-8.mol

Thiophanate-methyl Properties

Melting point:
172°C
storage temp. 
0-6°C
Water Solubility 
<0.1 g/100 mL at 20 ºC
Merck 
13,9427
Stability:
Stable. Incompatible with strong oxidizing agents, alkalies, copper salts.
EPA Substance Registry System
Carbamic acid, [1,2-phenylenebis(iminocarbonothioyl)] bis-, dimethyl ester(23564-05-8)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xn;N,N,Xn
Risk Statements  20-43-50/53-68
Safety Statements  36/37-46-60-61
RIDADR  UN 3077
RTECS  BA3675000
Hazardous Substances Data 23564-05-8(Hazardous Substances Data)
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

Thiophanate-methyl price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 45688 Thiophanate-methyl PESTANAL 23564-05-8 250mg $30.5 2017-11-08 Buy

Thiophanate-methyl Chemical Properties,Uses,Production

Description

Thiophanate methyl is a member of benzimidazole and a systemic fungicide with protective and curative activity against a broad spectrum of fungal diseases including leaf spots, blotches, blights, fruit spots, rots, sooty mould, scabs, bulb/corn/tuber decays, blossom blights, powdery mildews, certain rusts, and common soil borne crown and root rots. It is used on a variety of tree, vine, root crops, canola, and wheat, as well as on lawns and ornamentals. Thiophanate methyl is absorbed by the roots and leaves. Thiophanate-methyl has a low mammalian toxicity. But, it is an irritant and a skin sensitizer. It may also be mutagen. Moderate toxicity of thiophanate methyl is observed for aquatic organisms and earthworms. In EU, thiophanate methyl is approved to control fungal diseases on crops, while in Australia it is not registered for use on food-producing species, while it is only for the control of soil-borne diseases of ornamentals plants. For application, Thiophanate-methyl is formulated into wettable powders containing 50 and 70% active ingredient.

References

  1. https://apvma.gov.au
  2. https://www.epa.gov
  3. https://sitem.herts.ac.uk
  4. http://www.inchem.org
  5. Terry R Roberts, David H Hutson, Philip W Lee, Peter H Nicholls, and Jack R Plimmer, Metabolic Pathways of Agrochemicals: Part 2: Insecticides and Fungicides, 1999, ISBN 978-0-85404-499-3

Chemical Properties

colourless crystals, or white or light brown powder

Uses

Thiophanate-Methyl is a systematic fungicide of the thiophanate class. Thiophanate-Methyl is commonly used in agriculture to protect against powdery mildew, rot and other fungal diseases in fruits, ve getables and other crops.

Definition

ChEBI: A member of the class of thioureas that is the dimethyl ester of (1,2-phenylenedicarbamothioyl)biscarbamic acid. A fungicide effective against a broad spectrum of diseases in fruit, vegetables, turf and other crops including eyespot, scab, powdery mildew a d grey mould.

Uses

Systemic fungicide.

General Description

Colorless crystals or light brown powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Thiophanate-methyl is incompatible with strong acids and bases, and with strong reducing agents such as hydrides. Produces flammable gaseous hydrogen with active metals or nitrides. Incompatible with strong oxidizing acids, peroxides. Incompatible with alkaline material. Forms complexes with copper salts .

Fire Hazard

Flash point data for Thiophanate-methyl are not available. Thiophanate-methyl is probably combustible.

Thiophanate-methyl Preparation Products And Raw materials

Raw materials

Preparation Products


Thiophanate-methyl Suppliers

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Mainchem Co., Ltd.
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China Langchem Inc. 0086-21-58956006,021-38701807;021-58950017
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Shanghai Ruji Biology Technology Co., Ltd. +86-21-65211385-8001 36031160
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