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BENZENESULFINIC ACID

CAS No.
618-41-7
Chemical Name:
BENZENESULFINIC ACID
Synonyms
Benzolsulfinsure;benzenesulfinicaci;Phenylsulfinic acid;benzenesulphinicacid;BENZENESULFINIC ACID;SODIUMBENZENESULPHINICACID
CBNumber:
CB2111159
Molecular Formula:
C6H6O2S
Molecular Weight:
142.18
MDL Number:
MFCD00800458
MOL File:
618-41-7.mol
MSDS File:
SDS
Last updated:2023-05-04 17:34:40

BENZENESULFINIC ACID Properties

Melting point 84°C
Boiling point 111.5°C (estimate)
Density 1.365 (estimate)
refractive index 1.5300 (estimate)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka 1.3(at 20℃)
form solid
FDA UNII G9560D97PI

BENZENESULFINIC ACID price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
American Custom Chemicals Corporation CHM0312665 BENZENESULFINIC ACID 95.00% 618-41-7 5MG $496.16 2021-12-16 Buy
Ambeed A161190 Benzenesulfinicacid 95% 618-41-7 10g $766 2021-12-16 Buy
Ambeed A161190 Benzenesulfinicacid 95% 618-41-7 25g $1307 2021-12-16 Buy
Alichem 618417 Benzenesulfinicacid 618-41-7 25g $1683.67 2021-12-16 Buy
Ambeed A161190 Benzenesulfinicacid 95% 618-41-7 100g $4055 2021-12-16 Buy
Product number Packaging Price Buy
CHM0312665 5MG $496.16 Buy
A161190 10g $766 Buy
A161190 25g $1307 Buy
618417 25g $1683.67 Buy
A161190 100g $4055 Buy

BENZENESULFINIC ACID Chemical Properties,Uses,Production

Definition

ChEBI: Benzenesulfinic acid is an organosulfinic acid. It is a conjugate acid of a benzenesulfinate.

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 35, p. 1770, 1987 DOI: 10.1248/cpb.35.1770

Purification Methods

The acid is purified by dissolving the Na salt in H2O, acidifying to Congo Red paper with HCl and adding a concentrated solution of FeCl3 whereby Fe sulfinate precipitates. Collect the salt, wash it with a little H2O, drain, suspend it in H2O and add a slight excess of 1.5M aqueous NaOH. The Fe(OH)3 precipitates, it is filtered off, the sulfinic acid in the aqueous solution is extracted with Et2O, the extract is dried (Na2SO4) and evaporated to give colourless crystals of benzenesulfinic acid m 84o which are stored under N2 in the dark, as it slowly oxidises in air to the sulfonic acid. [Beilstein 11 H 2, 11 I 3, 11 II 3, 11 III 3, 11 IV 3.]

71-43-2
618-41-7
Synthesis of BENZENESULFINIC ACID from Benzene
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benzenesulphinicacid SODIUMBENZENESULPHINICACID BENZENESULFINIC ACID Phenylsulfinic acid Benzolsulfinsure benzenesulfinicaci 618-41-7 C6H5SO2H Industrial/Fine Chemicals fine chemicals