BENZENESULFINIC ACID

BENZENESULFINIC ACID 구조식 이미지
카스 번호:
618-41-7
상품명:
BENZENESULFINIC ACID
동의어(영문):
Benzolsulfinsure;benzenesulfinicaci;Phenylsulfinic acid;benzenesulphinicacid;BENZENESULFINIC ACID;SODIUMBENZENESULPHINICACID
CBNumber:
CB2111159
분자식:
C6H6O2S
포뮬러 무게:
142.18
MOL 파일:
618-41-7.mol

BENZENESULFINIC ACID 속성

녹는점
84°C
끓는 점
111.5°C (estimate)
밀도
1.365 (estimate)
굴절률
1.5300 (estimate)
저장 조건
under inert gas (nitrogen or Argon) at 2-8°C
산도 계수 (pKa)
1.3(at 20℃)
물리적 상태
고체
물리적 상태
단단한 모양

안전

BENZENESULFINIC ACID C화학적 특성, 용도, 생산

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 35, p. 1770, 1987 DOI: 10.1248/cpb.35.1770

Purification Methods

The acid is purified by dissolving the Na salt in H2O, acidifying to Congo Red paper with HCl and adding a concentrated solution of FeCl3 whereby Fe sulfinate precipitates. Collect the salt, wash it with a little H2O, drain, suspend it in H2O and add a slight excess of 1.5M aqueous NaOH. The Fe(OH)3 precipitates, it is filtered off, the sulfinic acid in the aqueous solution is extracted with Et2O, the extract is dried (Na2SO4) and evaporated to give colourless crystals of benzenesulfinic acid m 84o which are stored under N2 in the dark, as it slowly oxidises in air to the sulfonic acid. [Beilstein 11 H 2, 11 I 3, 11 II 3, 11 III 3, 11 IV 3.]

BENZENESULFINIC ACID 준비 용품 및 원자재

원자재

준비 용품


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