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SILVER TRIFLUOROMETHANESULFONATE

CAS No.
2923-28-6
Chemical Name:
SILVER TRIFLUOROMETHANESULFONATE
Synonyms
AGOTF;SILVER TRIFLATE;SILVER TRIFLUOROMETHANESULPHONATE;Silver (trifluoromethyl)sulfonate;TRIFLUOROMETHANESULFONIC ACID SILVER SALT;fonate;ver trifL;uoromethanesuL;Silver(I)triflate;Indiumtrifluorometha
CBNumber:
CB3157655
Molecular Formula:
CAgF3O3S
Molecular Weight:
256.94
MDL Number:
MFCD00013226
MOL File:
2923-28-6.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

SILVER TRIFLUOROMETHANESULFONATE Properties

Melting point 286 °C (lit.)
storage temp. Store below +30°C.
solubility Methanol (Slightly), Water (Slightly)
form Powder
color White to light beige
Water Solubility Soluble in water and also in most organic solvents.
Sensitive Light Sensitive
Hydrolytic Sensitivity 6: forms irreversible hydrate
BRN 3598402
Stability Stable, but may be light sensitive. Incompatible with strong acids, strong oxidizing agents.
InChI InChI=1S/CHF3O3S.Ag/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
InChIKey QRUBYZBWAOOHSV-UHFFFAOYSA-M
SMILES C(F)(F)(F)S([O-])(=O)=O.[Ag+]
CAS DataBase Reference 2923-28-6(CAS DataBase Reference)
FDA UNII UK2MGY9YSF
EPA Substance Registry System Methanesulfonic acid, trifluoro-, silver(1+) salt (2923-28-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H315-H318
Precautionary statements  P264-P280-P302+P352-P305+P351+P338-P332+P313-P362+P364
Hazard Codes  Xi,C
Risk Statements  36/37/38-50-34
Safety Statements  26-36-61-45-36/37/39
RIDADR  3260
WGK Germany  3
8
Hazard Note  Corrosive
TSCA  Yes
HazardClass  8
HS Code  28432900
NFPA 704
1
2 1

SILVER TRIFLUOROMETHANESULFONATE price More Price(56)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.14325 Silver trifluoromethanesulfonate for synthesis 2923-28-6 5G $103 2024-03-01 Buy
Sigma-Aldrich 8.14325 Silver trifluoromethanesulfonate for synthesis 2923-28-6 25g $342 2024-03-01 Buy
Sigma-Aldrich 176435 Silver trifluoromethanesulfonate ≥99% 2923-28-6 1g $40.4 2024-03-01 Buy
Sigma-Aldrich 176435 Silver trifluoromethanesulfonate ≥99% 2923-28-6 10g $122 2024-03-01 Buy
TCI Chemical T1331 Silver Trifluoromethanesulfonate >98.0%(T) 2923-28-6 1g $28 2024-03-01 Buy
Product number Packaging Price Buy
8.14325 5G $103 Buy
8.14325 25g $342 Buy
176435 1g $40.4 Buy
176435 10g $122 Buy
T1331 1g $28 Buy

SILVER TRIFLUOROMETHANESULFONATE Chemical Properties,Uses,Production

Reactions

  1. Silver precatalyst for the asymmetric allylation of aldehydes
  2. Silver catalyst for intramolecular additions of alcohols and carboxylic acids to inert olefins
  3. Silver catalyst for the fluorination of boronic acids
  4. Silver catalyst for the fluorination of functionalized aryl stannanes
  5. Silver catalyst for cyclopropenation of internal alkynes with donor/acceptor substituted diazo compounds
  6. Silver catalyst for the reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate
Reactions of 2923-28-6_1
Reactions of 2923-28-6_2

Chemical Properties

light beige crystalline powder

Uses

Silver Trifluoromethanesulfonate is used to generate cationic rhodium catalysts from chlororhodium complexes for the hydrophosphination of acetylenes. It is also employed as a catalyst for the preparation of silyl ethers by hydrosilylation of aldehydes.

General Description

Silver trifluoromethanesulfonate p-complexes of monoenes, dienes, trienes, monoynes and diynes have been prepared. It reacts with 2-fluoro- and 3-fluoro-4-alkoxystilbazoles to afford the mesomorphic complexes. Iodine monochloride/AgOTf constitutes an efficient promoter system for the O-glycoside synthesis.

Purification Methods

Recrystallise it twice from hot CCl4 [Alo et al. J Chem Soc, Perkin Trans 1 805 1986]. Store it in the dark. [Beilstein 3 IV 34.]

Global( 392)Suppliers
Supplier Tel Email Country ProdList Advantage
Nanjing Sinoda Biological Technology Co., Ltd
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Capot Chemical Co.,Ltd.
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career henan chemical co
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View Lastest Price from SILVER TRIFLUOROMETHANESULFONATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
SILVER TRIFLUOROMETHANESULFONATE pictures 2023-03-10 SILVER TRIFLUOROMETHANESULFONATE
2923-28-6
US $0.00 / KG 1KG 99.0% 1000KG LY Global chemicals co.,ltd .
SILVER TRIFLUOROMETHANESULFONATE pictures 2022-10-10 SILVER TRIFLUOROMETHANESULFONATE
2923-28-6
US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
SILVER TRIFLUOROMETHANESULFONATE pictures 2022-09-23 SILVER TRIFLUOROMETHANESULFONATE
2923-28-6
US $0.00 / kg 1kg 99% 1000kg henan kanbei chemical co.,ltd
SILVER (I) TRIFLUOROMETHANE SULFONATE SILVER(I) TRIFLUOROMETHANESULPHONATE SILVER TRIFLUOROMETANESULFONATE SILVER TRIFLUOROMETHANESULFONATE TRIFLUOROMETHANESULFONATE SILVER SALT Silver triflate, Trifluoromethanesulfonic acid silver salt (Trifluoromethylsulfonyloxy) silver(I) Trifluoromethanesulfonic acid silver Trifluoromethanesulfonic acid silver(I) Trifluoromethylsulfonyloxysilver(I) Silver trifluoromethanesulfonate,Silver triflate, Trifluoromethanesulfonic acid silver salt Silver trifluoromethanesulfonate/ 97+% LVER TRIFLUOROMETHANESULFONATE Silver trifluoroMethanesulfonate,98% (Silver triflate) Ag(CF3SO3) SILVER TRIFLUOROMETHANESULFONATE FOR SYN (trifluoroMethylsulfonyloxy)silver, TfOAg SILVER (I) TRILUOROMETHANE SULFONATE silver(I) 4-(trifluoroMethyl)benzenesulfonate Silver trifluoroMethanesulfonate >=99.95% trace Metals basis Silver trifluoromethanesulfonate purum, >=98.0% (Ag) trifluoro-methanesulfonicacisilver(1++)salt Silvertrifluoromethanesulfonate,99%(Silvertriflate) Methanesulfonic acid, trifluoro-, silver(1+) salt Silver trifluoromethanesulphonate 99% Silver trifluormethanesulfonate Silver(I) triflate~Trifluoromethanesulphonic acid silver(I) salt SILVER TRIFLUOROMETHANESULFONATE, 99.95+ % SILVER TRIFLUOROMETHANESULFONATE, 99+% Silver(I)triflate Trifluoromethanesulfonicacidsilver(I)salt Silvertrifluoromethanesulphonate99% SILVER TRIFLUOROMETHANESULFONATE (SILVER TRIFLATE) SILVER TRIFLUOROMETHANESULFOTE Silver trifluoromethanesulfonate (99.95%-Ag) (Silver triflate) TRIFLUOROMETHYLSULFONYLOXYSILVER Indiumtrifluorometha Silver Trifluoromethanesulfonate (AgOTf) SILVER TRIFLUOROMETHANESULFONATE, 99%SILVER TRIFLUOROMETHANESULFONATE, 99%SILVER TRIFLUOROMETHANESULFONATE, 99%SILVER TRIFLUOROMETHANESULFONATE, 99% silver trifluoromethanesulphonate CHF3O3S.Ag fonate uoromethanesuL ver trifL Silver trifluoromethanesulfonate, 98%, for synthesis Powdered silver trifluoromethanesulfonate Methanesulfonic acid, 1,1,1-trifluoro-, silver(1+) salt (1:1) SILVER TRIFLUOROMETHANESULFONATE ISO 9001:2015 REACH Silver Trifluoromethanesulfonate extrapure, 98% SILVER TRIFLATE SILVER TRIFLUOROMETHANESULPHONATE TRIFLUOROMETHANESULFONIC ACID SILVER SALT Silver (trifluoromethyl)sulfonate AGOTF Silver(Ⅰ) trifluorometanesulfonate SILVER TRIFLATE Silver trifluoromethanesulfonate 2923-28-6 AgSO3CF3 AgOSO2CF3 CHF3O3SAg