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2,5-Diaminotoluene

2,5-Diaminotoluene Structure
2,5-Diaminotoluene structure
CAS No.
95-70-5
Chemical Name:
2,5-Diaminotoluene
Synonyms
ci76042;c.i.76042;C.I. 76042;DIAMINOTOLUENES;p-Toluenediamine;p-Toluylendiamine;2,5-Diaminotoluol;p-Toluilenediamine;4-TOLUYLENEDIAMINE;2,5-DIAMINOTOLUENE
CBNumber:
CB4228730
Molecular Formula:
C7H10N2
Molecular Weight:
122.17
MDL Number:
MFCD00035779
MOL File:
95-70-5.mol
Last updated:2023-05-15 10:43:35
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2,5-Diaminotoluene Properties

Melting point 64°C
Boiling point 273°C
Density 1.0343 (rough estimate)
vapor pressure 0.454Pa at 25℃
refractive index 1.5103 (estimate)
solubility Soluble in water
form powder to crystal
pka 5.98±0.10(Predicted)
color White to Brown
Water Solubility 500g/L at 20℃
Stability Hygroscopic
LogP -0.321 at 25℃
CAS DataBase Reference 95-70-5(CAS DataBase Reference)
EWG's Food Scores 5-8
FDA UNII 24JO8Z0RJU
IARC 3 (Vol. 16, Sup 7) 1987
NIST Chemistry Reference 1,4-Benzenediamine, 2-methyl-(95-70-5)
EPA Substance Registry System Toluene-2,5-diamine (95-70-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  T,N
Risk Statements  20/21-25-43-51/53
Safety Statements  24-37-45-61
RIDADR  2811
RTECS  XS9700000
HazardClass  6.1(b)
PackingGroup  III
HS Code  2921511990

2,5-Diaminotoluene price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical D4628 2,5-Diaminotoluene >98.0%(GC)(T) 95-70-5 5g $57 2024-03-01 Buy
TCI Chemical D4628 2,5-Diaminotoluene >98.0%(GC)(T) 95-70-5 25g $225 2024-03-01 Buy
TRC T535877 2,5-Diaminotoluene(>80%) 95-70-5 5g $65 2021-12-16 Buy
SynQuest Laboratories 3730-1-84 2,5-Diaminotoluene 98% 95-70-5 5G $90 2021-12-16 Buy
SynQuest Laboratories 3730-1-84 2,5-Diaminotoluene 98% 95-70-5 100g $605 2021-12-16 Buy
Product number Packaging Price Buy
D4628 5g $57 Buy
D4628 25g $225 Buy
T535877 5g $65 Buy
3730-1-84 5G $90 Buy
3730-1-84 100g $605 Buy

2,5-Diaminotoluene Chemical Properties,Uses,Production

Description

p-Toluylenediamine is a hair dye associated with contact dermatitis in hairdressers. Cross reactivity is observed with PPD.

Chemical Properties

Colorless plates. Soluble in water, ethanol, ether, and hot benzene 2,5-Toluenediamine is used in hair and fur dyes.

Uses

2,5-Toluenediamine is used primarily in hair dye formulations as one of the major oxidation dye precursors. It is also used in the synthesis of saframine, a family of dyes used as biological stain, and may be present in indelible ink, antifreeze, and nail polish.
As may be expected from its use in hair dye formulations, hairdressers and barbers may be exposed to 2,5-TDA. Workers in the dye manufacturing industry may also be exposed.

Definition

ChEBI: A diamine in which the two amino groups are substituted into toluene at the 2- and 5-positions.

Synthesis Reference(s)

Journal of the American Chemical Society, 102, p. 6182, 1980 DOI: 10.1021/ja00539a054

Flammability and Explosibility

Non flammable

Contact allergens

Toluene-2,5-diamine is a permanent hair dye involved in contact dermatitis in hairdressers and consumers. It does not cross-react with PPD, but cosensitization is frequent.

Safety Profile

Poison by ingestion and subcutaneous routes. A skin irritant. Mutation data reported. Questionable carcinogen. Has a toxic action upon the liver and can cause fatty degeneration of that organ. Its total effect upon the body seems to take place three chfferent ways. It is toxic to the central nervous system, producing jaundice by action on the liver and spleen, and anemia by destruction of the red blood cells. This action is quite similar to that of aniline, although by no means identical with it. Its high boiling point and the fact that the material is solid at room temperature make it somewhat less hazardous than aniline, particularly at ordinary working temperatures. The literature contains a reference to a permanent injury to an eye due to the use of this material as an eyelash dye. It is considered to be an irritating dye material. When heated to decomposition it emits toxic fumes of NOx. See also other toluene diamine entries and AROMATIC AMINES.

Carcinogenicity

The possible carcinogenicity of 2,5-TDA (as sulfate salt [6369-59-1]) was tested by the National Cancer Institute in a dietary feeding study. Groups of 50 male and female F344 rats (600 or 2000 ppm) and B6C3F1 mice (600 or 1000 ppm) were given diets containing 2,5-TDA for 78 weeks and then observed for an additional period of 28–31 weeks for rats and 16–19 weeks for mice. The only statistically significant increased incidence was in lung tumors in high-dose female mice, but the evidence was not convincing enough to be attributed to 2,5-TDA. Overall, the compound was considered noncarcinogenic.

2,5-Diaminotoluene synthesis

202865-85-8
95-70-5
Synthesis of 2,5-Diaminotoluene from 2-BROMO-5-IODOTOLUENE

2,5-Diaminotoluene Preparation Products And Raw materials

Raw materials

azotoluene

Preparation Products

Basic Red 2 toluene-3,5-diamine disodium 2,2'-[(2-methyl-3,6-dioxo-1,4-cyclohexadiene-1,4-diyl)bis[imino(2-methyl-4,1-phenylene)imino]]bis(5-nitrobenzenesulphonate) Basic Red 2

2,5-Diaminotoluene Suppliers

Global( 172)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32480 60
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28180 58
Hubei xin bonus chemical co. LTD 		86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Nanjing jinheyou Trading Co., Ltd. 		15705188088 admin@jheyou.com CHINA 1268 58
career henan chemical co 		+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
SIMAGCHEM CORP 		+86-13806087780 sale@simagchem.com China 17367 58
Shanghai Daeyeon Chemicals Co., Ltd 		021-64478606 +8615900664856 daeyeon001@vip.163.com China 2062 58
Hefei TNJ Chemical Industry Co.,Ltd. 		0551-65418671 sales@tnjchem.com China 34572 58
Supplier Advantage
Capot Chemical Co.,Ltd. 		60
Henan Tianfu Chemical Co.,Ltd. 		55
ATK CHEMICAL COMPANY LIMITED 		60
Hubei Jusheng Technology Co.,Ltd. 		58
Hubei xin bonus chemical co. LTD 		58
Nanjing jinheyou Trading Co., Ltd. 		58
career henan chemical co 		58
SIMAGCHEM CORP 		58
Shanghai Daeyeon Chemicals Co., Ltd 		58
Hefei TNJ Chemical Industry Co.,Ltd. 		58

View Lastest Price from 2,5-Diaminotoluene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,5-Diaminotoluene pictures 2023-03-06 2,5-Diaminotoluene
95-70-5
 US $18.60 / KG 1KG 99% 5000kg Hebei Guanlang Biotechnology Co,.LTD
2,5-Diaminotoluene pictures 2022-02-19 2,5-Diaminotoluene
95-70-5
 US $0.00 / KG 1KG 98.6% 100 tons Honest Joy Holdings Limited
2-methyl-1,4-phenylenediamine pictures 2021-07-09 2-methyl-1,4-phenylenediamine
95-70-5
 US $15.00 / KG 1KG 99% 15tons/day Hebei Xibaijie Biotechnology Co., Ltd.

95-70-5(2,5-Diaminotoluene )Related Search:

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p-Toluilenediamine p-Toluylene-diamine Sodium 5-[(4-nitroph 4-Benzenediamine,2-methyl-1 C.I. 76042 c.i.76042 ci76042 p,m-Tolylenediamine para-meta-tolylenediamine para-toluenediamine para-toluylenediamine para-tolylenediamine p-Toluenediamine 1-METHYL-2,5-DIAMINOBENZENE DIAMINOTOLUENES 4-TOLUYLENEDIAMINE 1,4-DIAMINO-2-METHYLBENZENESULFATE TOLUENE-2,5-DIAMINE(ANDITSSALTS) 2-methyl-p-phenylenediamine 2,5-toluenediamine 2,5-Diaminotoluene,100 μL/mL in MeOH 2,5-DIAMINO TOLUENE FREE 2-Methyl-1,4-phenylene diamine TOLUENE-2,5-DIAMINE 2,5-DIAMINOTOLUENE 2-methyl-1,4-benzenediamine 2-METHYL-BENZENE-1,4-DIAMINE 1,4-benzenediamine,2-methyl 2,5-tolylenediamine 2-methyl-4-benzenediamine 2-methyl-para-phenylenediamine 2-Methyl-p-phenylenediamine 4-Amino-2-methylaniline p-Toluylendiamine Toluylene-2,5-diamine OEM 1,4-Benzenediamine, 2-methyl- China 2-methyl-1,4-phenylenediamine 2,5-Diaminotoluol 2-hydroxy-N-(4-methyl-2-nitrophenyl)-3-nitrobenzamide 2,5-Diaminotoluene (~80%) 2,5-Diaminotoluene > 95-70-5,2,5-Diaminotoluene 95-70-5 Intermediates of Dyes and Pigments