Benzyltriphenylphosphonium bromide
- CAS No.
- 1449-46-3
- Chemical Name:
- Benzyltriphenylphosphonium bromide
- Synonyms
- TZP;SKL082;NSC 54813;CAS1449-46-3;Benzyltriphen;Benzyl triphenyl pho;Benzyl threephosphoniuM broMide;Benzyltriphenylphosphine bromide;Benzyltriphenylphosphanium bromid;Bromo(benzyl)triphenylphosphorane
- CBNumber:
- CB4319243
- Molecular Formula:
- C25H22BrP
- Molecular Weight:
- 433.32
- MDL Number:
- MFCD00031707
- MOL File:
- 1449-46-3.mol
- MSDS File:
- SDS
Melting point | 295-298 °C(lit.) |
---|---|
storage temp. | Inert atmosphere,Room Temperature |
form | solid |
color | White to Almost white |
Water Solubility | Soluble in water. |
Sensitive | Hygroscopic |
BRN | 3599867 |
CAS DataBase Reference | 1449-46-3(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-36/37/39 | |||||||||
WGK Germany | 3 | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29319090 | |||||||||
NFPA 704 |
|
Benzyltriphenylphosphonium bromide price More Price(30)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 430056 | Benzyltriphenylphosphonium bromide 96% | 1449-46-3 | 50g | $109 | 2024-03-01 | Buy |
Sigma-Aldrich | 430056 | Benzyltriphenylphosphonium bromide 96% | 1449-46-3 | 250g | $318 | 2024-03-01 | Buy |
TCI Chemical | B2025 | Benzyltriphenylphosphonium Bromide >98.0%(HPLC)(T) | 1449-46-3 | 25g | $40 | 2024-03-01 | Buy |
Alfa Aesar | B24567 | Benzyltriphenylphosphonium bromide, 98% | 1449-46-3 | 10g | $21.65 | 2024-03-01 | Buy |
Alfa Aesar | B24567 | Benzyltriphenylphosphonium bromide, 98% | 1449-46-3 | 50g | $84.2 | 2024-03-01 | Buy |
Benzyltriphenylphosphonium bromide Chemical Properties,Uses,Production
Preparation
Benzyl triphenylphosphonium bromide is prepared by the following steps:To a solution of Ph3P (22 g, 0.084 mol) in toluene, BnBr (10 ml, 0.084 mol) was added dropwise with ice-cooling and stirred at room temperature for 2 hours. A solid was formed, which was filtered and washed with toluene and then dry pet ether to remove unreacted Ph3P. The salt was dried under vacuum (35 g, 96% yield).
Chemical Properties
WHITE CRYSTALLINE POWDER
Uses
Benzyltriphenylphosphonium bromide is used as a reactant for stereoselective azidolysis of vinyl epoxides, enantioselective aziridination and Friedel-Crafts cyclization for asymmetric synthesis of dihydrexidine, biomimetic iron(III) mediated oxidative dimerization for synthesis of benzoquinone parvistemin A, enantioselective synthesis of syn-diarylheptanoids from D-glucose, preparation of β-amyloid plaque ligands and decarboxylative cyclopropanation. It react with 4-methyl-oxetan-2-one to produce 4-hydroxy-1-phenyl-1-(triphenyl-l5-phosphanylidene)-pentan-2-one.
Benzyltriphenylphosphonium bromide Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 16805 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15932 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8823 | 58 |
Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 | sales@amoychem.com | China | 6387 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
View Lastest Price from Benzyltriphenylphosphonium bromide manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-01-14 | BENZYLTRIPHENYLPHOSPHONIUM BROMIDE
1449-46-3
|
US $5.00-0.50 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | ||
2023-09-04 | Benzyltriphenylphosphonium bromide
1449-46-3
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | ||
2023-02-24 | Benzyltriphenylphosphonium bromide
1449-46-3
|
US $0.00 / KG | 1KG | 98%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD |
- BENZYLTRIPHENYLPHOSPHONIUM BROMIDE
1449-46-3
- US $5.00-0.50 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
- Benzyltriphenylphosphonium bromide
1449-46-3
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
- Benzyltriphenylphosphonium bromide
1449-46-3
- US $0.00 / KG
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
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