ChemicalBook >> CAS DataBase List >>Benzyltriphenylphosphonium bromide

Benzyltriphenylphosphonium bromide

CAS No.
1449-46-3
Chemical Name:
Benzyltriphenylphosphonium bromide
Synonyms
TZP;SKL082;NSC 54813;CAS1449-46-3;Benzyltriphen;Benzyl triphenyl pho;Benzyl threephosphoniuM broMide;Benzyltriphenylphosphine bromide;Benzyltriphenylphosphanium bromid;Bromo(benzyl)triphenylphosphorane
CBNumber:
CB4319243
Molecular Formula:
C25H22BrP
Molecular Weight:
433.32
MDL Number:
MFCD00031707
MOL File:
1449-46-3.mol
MSDS File:
SDS
Last updated:2023-09-04 11:52:49

Benzyltriphenylphosphonium bromide Properties

Melting point 295-298 °C(lit.)
storage temp. Inert atmosphere,Room Temperature
form solid
color White to Almost white
Water Solubility Soluble in water.
Sensitive Hygroscopic
BRN 3599867
CAS DataBase Reference 1449-46-3(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36/37/39
WGK Germany  3
HazardClass  6.1
PackingGroup  III
HS Code  29319090
NFPA 704
1
2 0

Benzyltriphenylphosphonium bromide price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 430056 Benzyltriphenylphosphonium bromide 96% 1449-46-3 50g $109 2024-03-01 Buy
Sigma-Aldrich 430056 Benzyltriphenylphosphonium bromide 96% 1449-46-3 250g $318 2024-03-01 Buy
TCI Chemical B2025 Benzyltriphenylphosphonium Bromide >98.0%(HPLC)(T) 1449-46-3 25g $40 2024-03-01 Buy
Alfa Aesar B24567 Benzyltriphenylphosphonium bromide, 98% 1449-46-3 10g $21.65 2024-03-01 Buy
Alfa Aesar B24567 Benzyltriphenylphosphonium bromide, 98% 1449-46-3 50g $84.2 2024-03-01 Buy
Product number Packaging Price Buy
430056 50g $109 Buy
430056 250g $318 Buy
B2025 25g $40 Buy
B24567 10g $21.65 Buy
B24567 50g $84.2 Buy

Benzyltriphenylphosphonium bromide Chemical Properties,Uses,Production

Preparation

Benzyl triphenylphosphonium bromide is prepared by the following steps:To a solution of Ph3P (22 g, 0.084 mol) in toluene, BnBr (10 ml, 0.084 mol) was  added dropwise with ice-cooling and stirred at room temperature for 2 hours. A solid was  formed, which was filtered and washed with toluene and then dry pet ether to remove  unreacted Ph3P. The salt was dried under vacuum (35 g, 96% yield).

Chemical Properties

WHITE CRYSTALLINE POWDER

Uses

Benzyltriphenylphosphonium bromide is used as a reactant for stereoselective azidolysis of vinyl epoxides, enantioselective aziridination and Friedel-Crafts cyclization for asymmetric synthesis of dihydrexidine, biomimetic iron(III) mediated oxidative dimerization for synthesis of benzoquinone parvistemin A, enantioselective synthesis of syn-diarylheptanoids from D-glucose, preparation of β-amyloid plaque ligands and decarboxylative cyclopropanation. It react with 4-methyl-oxetan-2-one to produce 4-hydroxy-1-phenyl-1-(triphenyl-l5-phosphanylidene)-pentan-2-one.

Benzyltriphenylphosphonium bromide Preparation Products And Raw materials

Global( 327)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12456 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 16805 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15932 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8823 58
Xiamen AmoyChem Co., Ltd
+86-592-6051114 +8618959220845 sales@amoychem.com China 6387 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58

View Lastest Price from Benzyltriphenylphosphonium bromide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
BENZYLTRIPHENYLPHOSPHONIUM BROMIDE pictures 2024-01-14 BENZYLTRIPHENYLPHOSPHONIUM BROMIDE
1449-46-3
US $5.00-0.50 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Benzyltriphenylphosphonium bromide pictures 2023-09-04 Benzyltriphenylphosphonium bromide
1449-46-3
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Benzyltriphenylphosphonium bromide pictures 2023-02-24 Benzyltriphenylphosphonium bromide
1449-46-3
US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
Phosphonium,triphenyl(phenylmethyl)-,bromide benzyl trphenyl phosphonium bromide Benzytriphenyl Phosphonium Bromide Benzyltriphenylphosphanium bromid Triphenylbenzylphosphonium·bromide Benzyltriphenylphosphonium bromide,97% Benzyl triphenylphosphonium bromidedisc Benzyl triphenyl pho BENZYL TRIPHENYL PHOSPHOROUS BROMIDE BENZYLTRIPHENYLPHOSPHONIUM BROMIDE Benzyl triphenyl phosphorus broMide Benzyl threephosphoniuM broMide (Phenylmethyl)triphenylphosphonium bromide Bromo(benzyl)triphenylphosphorane NSC 54813 triphenyl-(phenylmethyl)phosphonium bromide Benzyl Triphenyl Phosphonium Bromide ( Btppb ) Benzyltriphen Benzyltriphenylphosphonium Bromide > SKL082 Phosphonium, triphenyl(phenylmethyl)-, bromide (1:1) CAS1449-46-3 TZP Benzyltriphenylphosphine bromide 1449-46-3 144-94-6 C6H5CH2PBrC6H53 C25H22BrP C6H5CH2PC6H53Br BrC25H22P Wittig Reagents Synthetic Reagents C-C Bond Formation Olefination Wittig Reaction Wittig & Horner-Emmons Reaction Phosphonium Compounds Pharmaceutical Intermediates Wittig Reagents Olefination C-C Bond Formation Wittig Reaction Wittig & Horner-Emmons Reaction Synthetic Organic Chemistry Phosphonium Compounds