Benzyltriphenylphosphonium chloride
- CAS No.
- 1100-88-5
- Chemical Name:
- Benzyltriphenylphosphonium chloride
- Synonyms
- BTPPC;BPP;BTPPCl;NSC 116712;AURORA KA-1173;Benzyltriphenylphosp;Benzyltriphenylchlorophosphine;Triphenylbenzylidenephosphorane;BENZYLIDENE(TRIPHENYL)PHOSPHORANE;benzyltriphenyl-phosphoniuchloride
- CBNumber:
- CB5738942
- Molecular Formula:
- C25H22ClP
- Molecular Weight:
- 388.87
- MDL Number:
- MFCD00011913
- MOL File:
- 1100-88-5.mol
- MSDS File:
- SDS
| Melting point | ≥300 °C (lit.) |
|---|---|
| Density | 1.18 g/cm3 (20℃) |
| vapor pressure | 0.1 hPa |
| Flash point | 300°C |
| storage temp. | Store at <= 20°C. |
| form | Crystalline Powder |
| color | White to almost white |
| Water Solubility | SOLUBLE |
| Sensitive | Hygroscopic |
| BRN | 3599868 |
| Stability | Stable. Incompatible with strong oxidizing agents. |
| InChIKey | USFRYJRPHFMVBZ-UHFFFAOYSA-M |
| LogP | -0.7 at 20℃ |
| CAS DataBase Reference | 1100-88-5(CAS DataBase Reference) |
| FDA UNII | WM5533HY8L |
| EPA Substance Registry System | Phosphonium, triphenyl(phenylmethyl)-, chloride (1100-88-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS05,GHS06,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H300+H330-H318-H335-H372-H410 | |||||||||
| Precautionary statements | P260-P273-P280-P304+P340+P310-P305+P351+P338-P314 | |||||||||
| Hazard Codes | T,Xi | |||||||||
| Risk Statements | 25-36/37/38-24/25 | |||||||||
| Safety Statements | 26-36/37/39-45-36 | |||||||||
| RIDADR | UN 2811 6.1/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | TA2416500 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29310095 | |||||||||
| Toxicity | LD50 orally in Rabbit: 43 mg/kg | |||||||||
| NFPA 704 |
|
Benzyltriphenylphosphonium chloride price More Price(25)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | B32807 | Benzyltriphenylphosphonium chloride 99% | 1100-88-5 | 25g | $32.52 | 2024-03-01 | Buy |
| Sigma-Aldrich | B32807 | Benzyltriphenylphosphonium chloride 99% | 1100-88-5 | 100g | $95.4 | 2024-03-01 | Buy |
| TCI Chemical | B0824 | Benzyltriphenylphosphonium Chloride >98.0%(HPLC)(T) | 1100-88-5 | 25g | $36 | 2024-03-01 | Buy |
| TCI Chemical | B0824 | Benzyltriphenylphosphonium Chloride >98.0%(HPLC)(T) | 1100-88-5 | 500g | $391 | 2024-03-01 | Buy |
| Alfa Aesar | A14034 | Benzyltriphenylphosphonium chloride, 99% | 1100-88-5 | 100g | $77 | 2024-03-01 | Buy |
Benzyltriphenylphosphonium chloride Chemical Properties,Uses,Production
Chemical Properties
Benzyltriphenylphosphonium Chloride is a white to off white powder, It is highly soluble in water and polarizable solvents. It is a quaternary phosphonium salt mainly used in organic synthesis as a wittig reagent and as a phase transfer catalyst in the production of fluoroelastomers and printing inks.
Uses
Benzyltriphenylphosphonium Chloride was used as a reagent in the organic synthesis of several compounds including that of stabilised phosphonium ylides containing saturated oxygen heterocycles. Also used in the synthesis of novel substituted cis-stilbene derivatives which display antimicrobial activity.
Application
Benzyltriphenylphosphonium chloride can be used as a reactant for the synthesis of:
Platinum chloro-tetrazole complexes via azidation.
Trans-stilbenes and cinnamates via Wittig olefination.
Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment.
Pentiptycenes for use as light-driven molecular brakes.
Archipelago structures for formation of petroleum asphaltenes.
It is also used as a crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites.
Crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites
Reactant for synthesis of:
Platinum chloro tetrazole complexes via azidation
Trans-stilbenes and cinnamates via Wittig olefination
Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment
Pentiptycenes for use as light-driven molecular brakes
Reactant for formation of archipelago structures for formation of petroleum asphaltenes
Flammability and Explosibility
Not classified
Purification Methods
Wash it with Et2O and crystallise it from EtOH (six-sided plates). It is hygroscopic and forms crystals with one molecule of H2O. [Michaelis & Soden Justus Liebigs Ann Chem 229 320 1885, Kr.hnke Chem Ber 83 291 1950, Beilstein 16 IV 994.]
Benzyltriphenylphosphonium chloride Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shandong Promise New Material Co.,Ltd. | +86-18678104048 +86-15305334460 | johnwang@promisechemical.com | China | 89 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 8095 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
| JingJiang Connect Chemical manufacturing Co., Ltd. | 0523-80501690 15252623102 | andy@katchemical.com | CHINA | 59 | 55 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 | info@tnjchem.com | China | 2989 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8823 | 58 |
View Lastest Price from Benzyltriphenylphosphonium chloride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-01-14 | Benzyltriphenylphosphonium chloride
1100-88-5
|
US $5.00-0.50 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2023-08-29 | Benzyltriphenylphosphonium chloride
1100-88-5
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | |
 |
2023-03-06 | Benzyltriphenylphosphonium chloride
1100-88-5
|
US $5.00-2.00 / KG | 1KG | 99% | 10000kg | Hebei Guanlang Biotechnology Co,.LTD |
-
- Benzyltriphenylphosphonium chloride
1100-88-5
- US $5.00-0.50 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- Benzyltriphenylphosphonium chloride
1100-88-5
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
-
- Benzyltriphenylphosphonium chloride
1100-88-5
- US $5.00-2.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co,.LTD
Benzyltriphenylphosphonium chloride Spectrum
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