Methyl 3-bromobenzoate
- CAS No.
- 618-89-3
- Chemical Name:
- Methyl 3-bromobenzoate
- Synonyms
- RARECHEM AL BF 0052;METHYL M-BROMOBENZOATE;METHYL 3-BROMOBENZOATE;3-Bromobenzoate Methyl;Methyl-3-Bromobenzoate 98%;Methyl 3-Bromobenzoate >Methyl 3-bromobenzoate, 98+%;3-bromo-benzoicacimethylester;Methyl 3-broMobenzoate, 98% 5GR;m-Bromobenzoic acid methyl ester
- CBNumber:
- CB4345734
- Molecular Formula:
- C8H7BrO2
- Molecular Weight:
- 215.04
- MDL Number:
- MFCD00017777
- MOL File:
- 618-89-3.mol
| Melting point | 31-33 °C(lit.) |
|---|---|
| Boiling point | 127-128 °C15 mm Hg(lit.) |
| Density | 1.5313 (rough estimate) |
| refractive index | 1.5575 |
| Flash point | >230 °F |
| storage temp. | Sealed in dry,Room Temperature |
| form | Crystalline Solid or Liquid |
| color | White to light yellow |
| Water Solubility | Slightly soluble in water. |
| BRN | 1940810 |
| InChIKey | KMFJVYMFCAIRAN-UHFFFAOYSA-N |
| CAS DataBase Reference | 618-89-3(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzoic acid, 3-bromo-, methyl ester(618-89-3) |
| EPA Substance Registry System | Benzoic acid, 3-bromo-, methyl ester (618-89-3) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301+H331-H315-H319-H335 | |||||||||
| Precautionary statements | P501-P261-P270-P271-P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P310+P330-P304+P340+P311-P403+P233-P405 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 37/39-26-24/25 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29163990 | |||||||||
| NFPA 704 |
|
Methyl 3-bromobenzoate price More Price(29)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 499625 | Methyl 3-bromobenzoate 98% | 618-89-3 | 5g | $40.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 499625 | Methyl 3-bromobenzoate 98% | 618-89-3 | 25g | $65 | 2024-03-01 | Buy |
| TCI Chemical | B0554 | Methyl 3-Bromobenzoate >99.0%(GC) | 618-89-3 | 5g | $33 | 2024-03-01 | Buy |
| TCI Chemical | B0554 | Methyl 3-Bromobenzoate >99.0%(GC) | 618-89-3 | 25g | $85 | 2024-03-01 | Buy |
| Alfa Aesar | A16174 | Methyl 3-bromobenzoate, 98+% | 618-89-3 | 10g | $56.65 | 2024-03-01 | Buy |
Methyl 3-bromobenzoate Chemical Properties,Uses,Production
Chemical Properties
Methyl 3-bromobenzoate is white to light yellow low melting crystalline
Uses
Methyl 3-bromobenzoate is an halogenated benzoate derivative used as a reagent in organic synthesis.Methyl 3-bromobenzoate is used in the synthesis of a novel series of tetrahydro dibenzazocine as inhibitors of 17β-hydroxysteroid dehydrogenase type 3.
Uses
Methyl 3-bromobenzoate is used as a reagent in organic synthesis. It is used in the synthesis of tetrahydro dibenzazocine, which acts as an inhibitor of 17beta-hydroxysteroid dehydrogenase type 3. Further, it is used to prepare 3-tert-butylphosphanyl-benzoic acid methyl ester by reacting with tert-butyltrimethylsilylphosphine.
General Description
Methyl 3-bromobenzoate is an aryl bromide. It undergoes stereoconvergent cross-coupling with potassium trifluoro(1-phenylethyl)borate to form 1,1-diarylethane derivative. The Negishi cross-coupling reaction between methyl 3-bromobenzoate and diarylzinc reagents in the presence of a palladium catalyst has been reported. Methyl-3-bromobenzoate can be converted into the corresponding benzonitrile using dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium as a C-C cross-coupling catalyst and K4[Fe(CN)6] as a cyanating agent.
Methyl 3-bromobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
1of2
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Zibo Hangyu Biotechnology Development Co., Ltd | +86-0533-2185556 +8617865335152 | Mandy@hangyubiotech.com | China | 11013 | 58 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15932 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4242 | 58 |
| Accela ChemBio Inc. | (+1)-858-699-3322 | info@accelachem.com | United States | 19965 | 58 |
| Changzhou Ditong Chemical Co.,Ltd | +86-0519-88299272 | info@edengenechem.com | China | 2169 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63711 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49390 | 58 |
View Lastest Price from Methyl 3-bromobenzoate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-01-02 | Methyl 3-bromobenzoate
618-89-3
|
US $70.00-700.00 / kg | 10kg | 0.99 | 20tons | Zibo Hangyu Biotechnology Development Co., Ltd | |
 |
2022-01-05 | 3-bromobenzoate Methyl
618-89-3
|
US $0.00-0.00 / KG | 1g | 98%min | 100kgs/month | Shanghai Rlavie Technology Co ltd | |
 |
2019-07-06 | Methyl 3-bromobenzoate
618-89-3
|
US $1.00 / KG | 1KG | 99% | Customized | Career Henan Chemical Co |
-
- Methyl 3-bromobenzoate
618-89-3
- US $70.00-700.00 / kg
- 0.99
- Zibo Hangyu Biotechnology Development Co., Ltd
-
- 3-bromobenzoate Methyl
618-89-3
- US $0.00-0.00 / KG
- 98%min
- Shanghai Rlavie Technology Co ltd
-
- Methyl 3-bromobenzoate
618-89-3
- US $1.00 / KG
- 99%
- Career Henan Chemical Co