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(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine

(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine structure

CAS No.: 167316-27-0

Chemical Name:: (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine

Synonyms: (S,S)-TSDPEN;N-((1S,2S)-2-amino-1,2-diphenylethyl)-4-methylbenzenesulfonamide;(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine;(1S,2S)-TSDPEN;2S)-(+)-N-p-Tosyl-1;2-diphenylethylenediaMine;(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-;(1S,2S)-N-P-TOSYL-1,2-DIPHENYLETHYLENE-D;(1S,2S)-N-Tosyl-1,2-diphenylethylene-1,2-diamine;(1S,2S)-(-)-N-P-TOSYL-1,2-DIPHENYLETHYLENEDIAMINE

CBNumber:: CB4775946

Molecular Formula:: C21H22N2O2S

Molecular Weight:: 366.48

MDL Number:: MFCD03095684

MOL File:: 167316-27-0.mol

MSDS File:: SDS

Last updated:2023-04-23 13:52:06

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(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine Properties

Melting point	128-131 °C (lit.)
Boiling point	537.3±60.0 °C(Predicted)
alpha	61.5 º (C=1, CH2Cl2)
Density	1.1440 (rough estimate)
refractive index	30 ° (C=1, CHCl3)
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
solubility	Solubility in hot Acetonitrile (almost transparency).
form	crystal
pka	10.76±0.50(Predicted)
color	white
optical activity	[α]20/D +35°, c = 1 in chloroform
CAS DataBase Reference	167316-27-0(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-36

WGK Germany

HS Code

29242990

NFPA 704

	0
2		0

(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine price More Price(50)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	484342	(1S,2S)-(+)-N-p-Tosyl-1,2-diphenylethylenediamine 98%	167316-27-0	1g	$41.3	2024-03-01	Buy
TCI Chemical	A1699	(S,S)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide >98.0%(T)	167316-27-0	1g	$145	2024-03-01	Buy
Alfa Aesar	H27006	(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine	167316-27-0	1g	$147.65	2024-03-01	Buy
Alfa Aesar	H27006	(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine	167316-27-0	5g	$470.65	2024-03-01	Buy
Strem Chemicals	07-2370	(1S,2S)-(+)-N-(4-toluenesulfonyl)-1,2-diphenylethylenediamine, 98% (S,S)-TsDPEN	167316-27-0	500mg	$64	2024-03-01	Buy

Product number	Packaging	Price	Buy
484342	1g	$41.3	Buy
A1699	1g	$145	Buy
H27006	1g	$147.65	Buy
H27006	5g	$470.65	Buy
07-2370	500mg	$64	Buy

(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine Chemical Properties,Uses,Production

Chemical Properties

White to slightly yellow crystalline powder

Uses

Chiral diamine ligand for cooperative metal-Bronsted acid catalyzed greener reductive amination using hydrogen gas.

Metal-Br?nsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

Uses

(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine is used as a catalyst in the synthesis of keramamine C, a carboline alkaloid that is isolated from the Okinawan sponge Amphimedon sp. (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine is also used as a catalyst in the synthesis of Tolvaptan (T536650), a selective oral vasopressin V2-receptor agonist that is used to treat hyponatremia.

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine Preparation Products And Raw materials

Raw materials

Preparation Products

(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine Suppliers

Global( 261)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15928	58
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4242	58
Shenzhen Nexconn Pharmatechs Ltd	+86-755-89396905 +86-15013857715	admin@nexconn.com	China	10248	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Accela ChemBio Inc.	(+1)-858-699-3322	info@accelachem.com	United States	19965	58
Xi'an Kono chem co., Ltd.,	029-86107037 13289246953	info@konochemical.com	China	2995	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63711	58

Supplier	Advantage
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
career henan chemical co	58
Changzhou Ansciep Chemical Co., Ltd.	58
Shenzhen Nexconn Pharmatechs Ltd	58
Hubei Jusheng Technology Co.,Ltd.	58
Accela ChemBio Inc.	58
Xi'an Kono chem co., Ltd.,	58
Chongqing Chemdad Co., Ltd	58
Alchem Pharmtech,Inc.	58

View Lastest Price from (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2022-09-20	(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine 167316-27-0	US $0.00-0.00 / kg	1kg	98%	1Ton	Henan Aochuang Chemical Co.,Ltd.
2021-03-17	(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine 167316-27-0	US $60.00 / g	10g	99.8%	10tons	Hebei shuoxi biotechnology co. LTD
2020-11-16	(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine 167316-27-0	US $15.00 / Kg/Bag	25Kg/Bag	99%	20 Tons	Longyan Tianhua Biological Technology Co., Ltd

(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine
167316-27-0
US $0.00-0.00 / kg
98%
Henan Aochuang Chemical Co.,Ltd.

(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine
167316-27-0
US $60.00 / g
99.8%
Hebei shuoxi biotechnology co. LTD

(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine
167316-27-0
US $15.00 / Kg/Bag
99%
Longyan Tianhua Biological Technology Co., Ltd

(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine Spectrum

(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine(167316-27-0)IR

167316-27-0((1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine)Related Search:

N,N,N',N'-Tetramethylethylenediamine 2-(2-Aminoethylamino)ethanol Ethylenediamine 1,2-Diphenylethylenediamine Toluenesulfonamide

Toluene (R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine(Chloro)(p-cymene)ruthenium(II) (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine (1R,2R)-N,N'-DI-P-TOLUENESULFONYL-1,2-DIPHENYL-1,2-ETHYLENEDIAMINE

(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine (1S,2S)-(-)-N,N'-Bis(4-toluenesulfonyl)-1,2-diphenylethylenediamine (1R,2R)-(+)-N,N'-Bis(4-toluenesulfonyl)-1,2-diphenylethylenediamine AURORA KA-7169 CHLORO[(1S,2S)-N-(P-TOLUENESULFONYL)-1,2-DIPHENYL-1,2-ETHANEDIAMINE] (MESITYLENE)RUTHENIUM(II)

CHLORO[(1S,2S)-N-(P-TOLUENESULFONYL)-1,2-DIPHENYL-1,2-ETHANEDIAMINE] (P-CYMENE)RUTHENIUM(II) RU[(S,S)-TSDPEN](P-CYMENE)

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(1S,2S)-(+)-N-p-Tosyl-1,2-diphenylethylenediamine (S,S)-Ts-DPEN, (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine, 98% (S,S)-N-(P-TOLUENESULFONYL)-1,2-DIPHENYLETHYLENEDIAMINE (1S, 2S)-(+)-N-(4-TOLUENE SULFONYL)1,2-DIPHENYL-1,2-ETHANE DIAMINE (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediaMine, 98% 500MG (1S,2S)-(+)-N-p-Tosyl-1,2-diphenylethylenediamine≥ 99% (Assay, Chiral purity) (1S,2S)-N-p-Tosyl-1,2-diphenylethylenediamine,99%e.e. (1S,2S)-(-)-N-p-Tosyl-1,2-diphenylethylenediaMine SynonyMs (S,S)-TsDPEN (1S,2S)-N-Tosyl-1,2-diphenylethylene-1,2-diamine (S,S)-N-(2-AMINO-1,2-DIPHENYLETHYL)-P-TOLUENESULFONAMIDE (1S,2S)-N-(4-TOLUENESULFONYL)-1,2-DIPHENYLETHYLENE-1,2-DIAMINE (1S,2S)-(+)-N-(4-TOLUENESULFONYL)-1,2-DIPHENYLETHYLENEDIAMINE (1S,2S)-(+)-N-(4-TOLUENESULPHONYL)-1,2-DIPHENYLETHYLENEDIAMINE (1S,2S)-TSDPEN (1S,2S)-N-(P-TOLUENESULFONYL)-1,2-DIPHENYL-1,2-ETHANEDIAMINE (1S,2S)-(-)-N-P-TOSYL-1,2-DIPHENYLETHYLENEDIAMINE (1S,2S)-(+)-N-P-TOSYL-1,2-DIPHENYLETHYLENEDIAMINE (1S,2S)-N-P-TOSYL-1,2-DIPHENYLETHYLENE-D (1S,2S)-(+)-N-(4-toluenesulfonyl)-1,2-diphenylethylenediamine,98%(S,S)-TsDPEN (1S,2S)-(+)-N-(4-TOLUENESULFONYL)-1,2-DIPHENYLETHYLENEDIAMINE (S,S)-TSDPEN (1S,2S)-(-)-N-P-TOSYL-1,2-DIPHENYLETHYLENEDIAMINE 98% (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2- 2-diphenylethylenediaMine 2S)-(+)-N-p-Tosyl-1 (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine,98% (1S,2S)-N-p-toluenesulfonyl-1,2-dipheneylethylenediamine (S,S)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide > (1S,2S)-(+)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine Benzenesulfonamide, N-[(1S,2S)-2-amino-1,2-diphenylethyl]-4-methyl- (1S,2S)-(+)-N-(4-toluenesulfonyl)-1,2-diphenylethylenediamine,98%,99%ee (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamin... (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine N-((1S,2S)-2-amino-1,2-diphenylethyl)-4-methylbenzenesulfonamide (S,S)-TSDPEN (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylen (1S,2S)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine / S-DPEN Tos 167316-27-0 CH3C6H4SO2NHCHC6H5CHC6H5NH2 C21H23N2O2S Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Hydrogenation Chiral Nitrogen DPEN Series API intermediates Asymmetric Synthesis Synthetic Organic Chemistry Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents HydrogenationChiral Building Blocks Organic Building Blocks Polyamines organic amine