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Toluene

CAS No. 108-88-3
Chemical Name: Toluene
Synonyms: TOL;cp25;HOXC6;Dracyl;Toluen;TOLUNE;HHO.C8;Hox-3C;TOLUOL;Tolueen
CBNumber: CB4233905
Molecular Formula: C7H8
Formula Weight: 92.14
MOL File: 108-88-3.mol
Toluene Property
Melting point : -95 °C
Boiling point : 111 °C
density : 0.866
vapor density : 3.2 (vs air)
vapor pressure : 22 mm Hg ( 20 °C)
refractive index : n/D 1.496(lit.)
Fp : 40 °F
storage temp. : 0-6°C
pka: 40(at 25℃)
form : Liquid
color : Colorless
Relative polarity: 0.099
Water Solubility : 0.5 g/L (20 ºC)
Merck : 14,9529
BRN : 635760
CAS DataBase Reference: 108-88-3(CAS DataBase Reference)
NIST Chemistry Reference: Toluene(108-88-3)
EPA Substance Registry System: Benzene, methyl-(108-88-3)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes : F,Xn,T
Risk Statements : 11-38-48/20-63-65-67-39/23/24/25-23/24/25
Safety Statements : 36/37-46-62-45-16-7
RIDADR : UN 1294 3/PG 2
WGK Germany : 2
RTECS : XS5250000
F : 3-10
TSCA : Yes
HazardClass : 3
PackingGroup : II
HS Code : 29023000
Hazardous Substances Data: 108-88-3(Hazardous Substances Data)
Symbol(GHS):
Signal word:
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H333 May be harmful if inhaled Acute toxicity,inhalation Category 5 P304+P312
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H361 Suspected of damaging fertility or the unborn child Reproductive toxicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P405 Store locked up.

Toluene Chemical Properties,Usage,Production

Chemical Properties
Colorless liquid
Definition
ChEBI: The simplest member of the class toluenes consisting of a benzene core which bears a single methyl substituent.
General Description
A clear colorless liquid with a characteristic aromatic odor. Flash point 40°F. Less dense than water (7.2 lb / gal) and insoluble in water. Hence floats on water. Vapors heavier than air. May be toxic by inhalation, ingestion or skin contact. Used in aviation and automotive fuels, as a solvent, and to make other chemicals.
Air & Water Reactions
Highly flammable. Insoluble in water.
Reactivity Profile
Toluene reacts vigorously with allyl chloride or other alkyl halides even at minus 70° C in the presence of ethyl aluminum dichloride or ethyl aluminum sesquichloride. Explosions have been reported [NFPA 491M 1991]. Incompatible with strong oxidizing agents. When added to a tank of sulfur dichloride, the tank over pressurized and ruptured in a reaction thought to be catalyzed by iron or iron(III) chloride [Chem. Eng. News, 1988, 66(32), 2].
Health Hazard
Vapors irritate eyes and upper respiratory tract; cause dizziness, headache, anesthesia, respiratory arrest. Liquid irritates eyes and causes drying of skin. If aspirated, causes coughing, gagging, distress, and rapidly developing pulmonary edema. If ingested causes vomiting, griping, diarrhea, depressed respiration.
Fire Hazard
Behavior in Fire: Vapor is heavier than air and may travel a considerable distance to a source of ignition and flash back.
Toluene Preparation Products And Raw materials
Raw materials
Diethylene glycol Platinum Motor benzol heavy benzol light benzol COAL TAR Petroleum toluene PETROLEUM ETHER Benzene COUMARONE RESIN Sodium hydroxide Carbomer 940 Coke (coal) Sulfuric acid
Preparation Products
Chloroprene-phenolic adhesive 801 3-Amino-3-azabicyclo[3.3.0]octane hydrochloride QUINOLINE-2-CARBONYL CHLORIDE 2-Thienyl isocyanate FLUORESCEIN CHLORIDE (R)-Glycidyl butyrate 1-(2-CHLOROBENZYL)PIPERAZINE 5-BROMOPYRIDINE-2-CARBONYL CHLORIDE 2-(2-HEXYLOXYETHOXY)ETHANOL Asphalt antifouling paint L40-32 METHYL 4-OXOTETRAHYDROTHIOPHENE-3-CARBOXYLATE (Methoxymethyl)triphenylphosphonium chloride 1,2-DIAMINO-2-METHYLPROPANE N-(Chloromethyl)phthalimide TRIS(NONYLPHENYL) PHOSPHITE Bis(benzonitrile)palladium chloride 1,3-DIMETHYL-2-(2-FURYL)IMIDAZOLIDINE 1-Butyl-3-methylimidazolium bromide Antimony triacetate 1-(3-CHLOROBENZYL)PIPERAZINE 3-Thiophenecarbonyl chloride 2-AMINO-4-METHOXYPYRIMIDINE 3-Cyanophenyl isocyanate Dichloro(1,5-cyclooctadiene)palladium(II) 6-FLUORO-4-HYDROXY-2-(TRIFLUOROMETHYL)QUINOLINE 4-AMINO-6-CHLORO-PYRIMIDINE-5-CARBALDEHYDE TRIMETHYLAMINE N-OXIDE HYDROCHLORIDE (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Phenylephrine hydrochloride N,O-Bis(trimethylsilyl)acetamide 5-Methoxypyridine-3-boronic acid 2-ISOCYANATO-4,6-DIMETHOXYPYRIMIDINE Chromocene 1-(2,6-DIMETHYLPHENYL)PIPERAZINE 5-ACETYLAMINO-2-CHLORO-4-PICOLINE 2,4-DI-(TERT-BUTOXY)-5-BROMOPYRIMIDINE 2-ETHOXYPYRIMIDIN-4-YLAMINE 2,2-DIMETHYLCYCLOHEXANONE 3,4-(METHYLENEDIOXY)PHENYL ISOCYANATE Heptyl 4-hydroxybenzoate
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108-88-3(Toluene)Related Search:
Xylene Ethylbenzene Benzene 2-HYDROXYPYRIDINIUM TOLUENE-4-SULFONATE,1,2-DIHYDRO-2-OXOPYRIDINIUM TOLUENE-4-SULFONATE 1-(4-CHLOROPHENOXY)-3-IODOPROPANE, TOLUENE 2-[ISOCYANO-(TOLUENE-4-SULFONYL)-METHYL]-NAPHTHALENE 4-Tolylboronic acid 3-(TRIFLUOROMETHOXY)TOLUENE 4,5-DIMETHYL-1-(TOLUENE-4-SULFONYL)-4,5-DIHYDRO-1H-CYCLOPENTA[B]PYRROL-6-ONE Tosyl chloride 2'-Bromoacetophenone SALCOMINE 2,3,4,5,6-PENTABROMOETHYLBENZENE Xylyl bromide. 2-Bromobiphenyl Pentabromotoluene 2-Bromostyrene 3-Bromobiphenyl
caswellno859 cp25 Dracyl Methane, phenyl- methyl-benzen Monomethyl benzene NCI-C07272 phenyl-methan Rcra waste number U220 rcrawastenumberu220 Retinaphtha Tolueen Toluen toluen(czech) tolueno Toluolo Tolu-sol Standard Solution of Volatile Organic Compounds for Water & Soil Analysis Standard Solutions (VOC) Solvents for HPLC & Spectrophotometry Solvents for Spectrophotometry TOLUNE TOLUENE PESTANAL TOLUENE 99.5+% A.C.S. REAGENT (SAFETY& TOLUENE 99.8% B&J BRAND TOLUENE FOR RESIDUE ANALYSIS TOLUENE, FOR HPLC TOLUENE, ABSOLUTE, OVER MOLECULAR SIEVE (H2O <0.005%) TOLUENE, 99.5+%, A.C.S. REAGENT TOLUENE CHROMASOLV FOR HPLC >=99.9%& TOLUENE, 99.5+%, A.C.S. SPECTROPHOTOMETR IC GRADE TOLUENE, CHROMASOLV PLUS, FOR HPLC, 99.& TOLUENE, ACS REAGENT, >=99.5% TOLUENE DRIED, (MAX. 0,001 % H2O),PURISS. P.A., REAG. ACS, REAG. TOLUENE DIST. TOLUENE, 4X25 ML TOLUENE 'B&J BRAND' 1 L TOLUENE, ANHYDROUS, 99.8% TOLUENE D FOR ANALYSIS OF DIOXINES, FURA NES AND PCB TOLUENE EXTRA PURE TOLUENE, ANHYDROUS, 99.8% (MINI-BULK) TOLUENE P CHROMASOLV FOR PREPARATIVELIQU ID CHROMATOGRAPHY, unpaid duty TOLUENE R. G., REAG. ACS, REAG. ISO, REAG. PH. EUR. TOLUENE, 5000MG, NEAT TOLUENE E PESTANAL IDRANAL II-ZINC R. G. TOLUENE PURIFICATION GRADE 99.8% TOLUENE, 99.5+%, A.C.S. REAGENT (SAFETY CAN) TOLUENE 'B&J BRAND' TOLUENE, STANDARD FOR GC TOLUENE ACS REAGENT TOLUENE, 99.8+%, PRA GRADE TOLUENE PURE TOLUENE >=99.5% A.C.S. SPECTROPHOTOMET TOLUENE, REAGENTPLUS, 99% TOLUENE, 99.8%, HPLC GRADE TOLUENE OEKANAL TOLUENE CHROMASOLV FOR HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY
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