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Trichlorosilane

Physical and chemical properties Trichlorosilane Toxicity Chemical properties Uses Production method Category Toxicity grading Acute oral toxicity Flammability hazard characteristics Storage characteristics Extinguishing agent
Trichlorosilane
Trichlorosilane
CAS No.
10025-78-2
Chemical Name:
Trichlorosilane
Synonyms
silanea-19;trichlorsilan;triclorosilano;trichloro-silan;trichloorsilaan;TRICHLOROSILANE;Silicochloroform;Silane, trichloro;silici-chloroforme;siliciumchloroform
CBNumber:
CB4852559
Molecular Formula:
Cl3HSi
Formula Weight:
135.45
MOL File:
10025-78-2.mol

Trichlorosilane Properties

Melting point:
-127 °C
Boiling point:
32-34 °C(lit.)
Density 
1.342 g/mL at 25 °C(lit.)
vapor density 
1 (vs air)
vapor pressure 
9.75 psi ( 20 °C)
refractive index 
1.4-1.402
Flash point:
7 °F
storage temp. 
Refrigerator
solubility 
Soluble in benzene, ether, heptane, chloroform and carbon tetrachloride.
form 
Liquid
color 
Colorless
explosive limit
70%
Water Solubility 
decomposes
Sensitive 
Air & Moisture Sensitive
Merck 
14,9646
Stability:
Stable, but extremely flammable. Pyrophoric - spontaneously ignites in air. Explosion hazard in air - note wide explosion limits. Reacts violently with water. Incompatible with moisture, acids, bases, strong oxidizing agents, alcohols, amines.
CAS DataBase Reference
10025-78-2(CAS DataBase Reference)
NIST Chemistry Reference
Trichlorosilane(10025-78-2)
EPA Substance Registry System
Silane, trichloro-(10025-78-2)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  F+,C
Risk Statements  12-14-17-20/22-29-35
Safety Statements  16-26-36/37/39-43-45-7/9-43A
RIDADR  UN 1295 4.3/PG 1
WGK Germany  1
RTECS  VV5950000
4.5-21-31
TSCA  Yes
HazardClass  4.3
PackingGroup  I
Hazardous Substances Data 10025-78-2(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H224 Extremely flammable liquid and vapour Flammable liquids Category 1 Danger
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger P210, P222, P280, P302+P334,P370+P378, P422
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231 Handle under inert gas.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.
P422 Store contents under …

Trichlorosilane price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 175552 Trichlorosilane 99% 10025-78-2 5g $27.4 2017-11-08 Buy
Sigma-Aldrich 175552 Trichlorosilane 99% 10025-78-2 100g $47.2 2017-11-08 Buy
Sigma-Aldrich 175552 Trichlorosilane 99% 10025-78-2 500g $104 2017-11-08 Buy

Trichlorosilane Chemical Properties,Uses,Production

Physical and chemical properties

Trichlorosilane is pungent stench flowable volatile colorless liquid at room temperature and pressure. It is highly flammable in air, it also has the risk of fire at below-18 ℃, when meets open fire, it burns strongly with red flames and white smoke, and SiO2, HCl and Cl2 can generate: SiHCl3 + O2 → SiO2 + HCl + Cl2; the vapor of three chlorosilane and air can form a wide range of concentrations of explosive gas mixture, and it can cause violent explosion when be heated. The thermal stability is better than dichlorosilane, it can decompose into toxic fumes chloride (HCl), Cl2 and Si at 900℃. When meets moisture, it can generate smoke, it can react violently with water: 2SiHCl3 + 3H2O → (HSiO) 2O + 6HCl; It can decompose in lye and release hydrogen: SiHCl3 + 3NaOH + H2O → Si (OH) 4 + 3NaCl + H2; and when it contacts oxidative substances, explosive reaction can occur. The reaction with acetylene, hydrocarbons and other organic hydrocarbons can produce chlorosilane: SiHCl3 + CH≡CH → CH2CHSiCl3, SiHCl3 + CH2 = CH2 → CH3CH2SiCl3; In the presence of lithium aluminum hydride, lithium borohydride, SiHCl3 can be reduced to silane. When the container is subjected to strong shock, liquid SiHCl3 will fire. It is soluble in benzene, ether etc.. Anhydrous trichlorosilane can not corrode iron and stainless steel, but in the presence of moisture, it can corrode most metals.

Trichlorosilane

Trichlorosilane is also known as trichlorosilane, silicon chloroform, it can be used the raw material of polymer organic silicon compound.
Trichlorosilane is not only the important intermediate of manufacturing silane coupling agent, and other organic silicon products, but also the major raw material to manufacture polysilicon. Silane coupling agent is an important, high-tech, high value-added silicone composite material, the non-crosslinked resin can crosslink or modify by silane coupling agent, so it is increasingly and widely used in glass fiber, foundry, tires rubber and other industries. Silicon tetrachloride which is the major byproduct in the production of trichlorosilane is also the main raw material of silicone, the manufactures contain silicon ester, silicone oil, high temperature insulation paint, silicone resin, silicone rubber and heat-resistant padded material . High-purity silicon tetrachloride or high-purity silica is important raw material in manufacturing of inorganic silicon compounds, quartz fibers and optical fiber.
The main purpose of the polysilicon product:
1. It can be made into solar cell, the radiant energy can be turned into electrical energy; 2. high purity crystalline silicon is an important semiconductor material; 3. it is important material in cermet, Astronautical; 4. it can be used in optical fiber communication which is recent modern communication means; 5. it can be used in excellent properties of the organosilicon compounds.
The above information is edited by the chemicalbook of Wang Xiaodong.

Toxicity

After several minutes of inhaling trichlorosilane vapor, people show excitement, breathing reflex disorders, respiratory inflammation. When spills on the skin, it can cause necrosis, long-term healing of ulcers. Maximum allowable concentration is 1 mg/m3 (must test HCl). Production staff should wear closed-type overalls, protective masks, sealed glasses, latex gloves and other protective clothing to prevent direct contact with the respiratory organs, eyes and skin. Production equipment must be sealed, workshop should be ventilated. After work, people should take a shower, and aobserve personal hygiene. Production workers should have pre-employment and periodic medical examinations.

Chemical properties

It is colorless liquid. It is soluble in carbon disulfide, carbon tetrachloride, chloroform, benzene etc.

Uses

It can be used the raw material for polymer organic silicon compound, it can also be used in industrial instrumentation.
It can be used the raw material for producing organic silicon compound, it is also the basic raw material of production polysilicon.

Production method

The method of boiling chlorination
Silicon powder after dried is added into boiling chloride furnace, and reacts with dry hydrogen chloride gas which passes into the furnace of at 340 ℃. The generated crude trichlorosilane goes through the wet dust collector, condenser tube and comes into distillation column to separate silicon tetrachloride, trichlorosilane gas from the distillation column is condensed to obtain finished trichlorosilane.
Si + 3HCl → SiHCl3 + H2

Category

Flammable liquid.

Toxicity grading

Mid toxicity.

Acute oral toxicity

rat LD50: 1030 mg/kg; Inhalation-Mouse LC50: 1500 mg/m/2 hours.

Flammability hazard characteristics

It is flammable in case of fire, high temperature, oxidant; it can generate toxic fumes of chlorides and fluorides in case of water or high temperature.

Storage characteristics

Treasury should be ventilated and low-temperature dried; it should be stored separately with oxidants, acids.

Extinguishing agent

Dry powder, dry sand, carbon dioxide, foam.

Chemical Properties

Clear liquid with acrid odor of hydrogen chloride

Uses

In organic synthesis.

General Description

A colorless fuming liquid with a pungent odor. Flash point 7°F. Vapor and liquid cause burns. More dense than water. Vapors are heavier than air.

Air & Water Reactions

Highly flammable. Ignites spontaneously in air [NFPA, 1991]. Reacts violently with water, steam, moisture in air to generate heat and flammable (H2) and corrosive (HCl) gases. [Handling Chemicals Safely 1980. p. 924].

Reactivity Profile

Trichlorosilane reacts with alcohols, acetone, light metals with generation of heat and combustible (H2) and corrosive (HCl) gases [Handling Chemicals Safely 1980. p. 924].

Health Hazard

Inhalation causes severe irritation of respiratory system. Liquid causes severe burns of eyes and skin. Ingestion causes severe burns of mouth and stomach.

Trichlorosilane Preparation Products And Raw materials

Raw materials

Preparation Products


Trichlorosilane Suppliers

Global( 100)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Mainchem Co., Ltd.
0592-6210733
0592-6210733 sales@mainchem.com CHINA 1948 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555
+86-021-57951555 jack.li@time-chemicals.com CHINA 1372 55
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 10013 55
Shanghai wechem chemical co., ltd 021-5198 7501
021-6192 7501 info@wechem.cn China 236 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96820 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40398 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30309 84
TCI (Shanghai) Development Co., Ltd. 800-988-0390
021-67121385 sales@tcishanghai.com.cn China 22830 81
BeiJing Hwrk Chemicals Limted 4006990298;010-57411839;0757-86311057;021-51691807
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Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800 info@energy-chemical.com China 44192 61

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