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ALLYL IODIDE

CAS No.
556-56-9
Chemical Name:
ALLYL IODIDE
Synonyms
3-IODOPROPENE;3-IODO-1-PROPENE;CH2CHCH2I;Allyljodid;Allyliodid;3-Jodpropen;3-Iodpropen;ALLYL IODIDE;3-iodo-propen;3-Jod-1-propen
CBNumber:
CB6186678
Molecular Formula:
C3H5I
Molecular Weight:
167.98
MDL Number:
MFCD00001094
MOL File:
556-56-9.mol
MSDS File:
SDS
Last updated:2023-11-28 16:31:43

ALLYL IODIDE Properties

Melting point -99 °C
Boiling point 102103°C
Density 1.837 g/mL at 25 °C(lit.)
refractive index n20/D 1.554
Flash point 65 °F
storage temp. 2-8°C
solubility alcohol: miscible(lit.)
form Liquid
color Clear yellow to orange, red or red-brown
Water Solubility Soluble in alcohol, chloroform, ether, and diethyl ether. Insoluble in water.
Sensitive Air & Light Sensitive
Merck 14,294
BRN 1697594
Exposure limits ACGIH: TWA 0.01 ppm
Dielectric constant 6.1(19℃)
InChIKey HFEHLDPGIKPNKL-UHFFFAOYSA-N
CAS DataBase Reference 556-56-9(CAS DataBase Reference)
FDA UNII 46830QOA4D
EPA Substance Registry System 1-Propene, 3-iodo- (556-56-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS06
Signal word  Danger
Hazard statements  H225-H300-H314
Precautionary statements  P210-P233-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  C,T,F
Risk Statements  10-34-11
Safety Statements  7-26-45-16
RIDADR  UN 1723 3/PG 2
WGK Germany  1
RTECS  UD0450000
8-13
TSCA  T
HazardClass  3
PackingGroup  II
HS Code  29033990
NFPA 704
3
3 1

ALLYL IODIDE price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 238325 Allyl iodide 98% 556-56-9 25g $124 2024-03-01 Buy
Sigma-Aldrich 238325 Allyl iodide 98% 556-56-9 100g $233 2024-03-01 Buy
TCI Chemical I0070 Allyl Iodide (stabilized with Copper chip) >98.0%(GC) 556-56-9 5g $114 2024-03-01 Buy
TCI Chemical I0070 Allyl Iodide (stabilized with Copper chip) >98.0%(GC) 556-56-9 25g $451 2024-03-01 Buy
Alfa Aesar A11822 Allyl iodide, 97+%, stab. with copper 556-56-9 50g $101 2024-03-01 Buy
Product number Packaging Price Buy
238325 25g $124 Buy
238325 100g $233 Buy
I0070 5g $114 Buy
I0070 25g $451 Buy
A11822 50g $101 Buy

ALLYL IODIDE Chemical Properties,Uses,Production

Chemical Properties

clear orange, red or red-brown liquid

Uses

Allyl iodide is used as a reagent used with allylindium sesquiiodide in the cis-double allylation of cyclopropenes. It is used in synthesis of other organic compounds such as N-alkyl 2-pyrrolidone, Sorbic acid ester etc,.

Synthesis Reference(s)

Synthetic Communications, 20, p. 41, 1990 DOI: 10.1080/00397919008054613

General Description

A yellow liquid with a pungent odor. Denser than water and insoluble in water. Hence sinks in water. Vapors are heavier than air. Flash point is less than 75°F. Very irritating to skin, eyes and mucous membranes. Poisonous by ingestion and inhalation. Used to make other chemicals.

Air & Water Reactions

Highly flammable. Darkens on exposure to light and air liberating Iodine [Merck 11th ed. 1989]. Insoluble in water.

Reactivity Profile

ALLYL IODIDE is moderately reactive. Incompatible with strong oxidizing and reducing agents. Also, incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Health Hazard

May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Safety Profile

Poison by inhalation and ingestion. Mutation data reported. A powerful irritant. A flammable liquid. Incompatible with oxidizing materials. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits hghly toxic fumes of I-. See also ALLYL COMPOUNDS and IODIDES.

Purification Methods

Purify allyl iodide in a dark room by washing with aqueous Na2SO3 to remove free iodine, then dry with MgSO4 and distil at 43o/90 mm or at atmospheric pressure to give a very pale yellow liquid. (This material, dissolved in hexane, can be stored in a light-protected tight container at -5o for up to three months before free iodine could be detected, by its colour in the solution.) Store it away from light. [Sibbett & Noyes J Am Chem Soc 75 761 1953, Beilstein 1 H 202, 1 I 84, 1 II 172, 1 III 714, 1 IV 761.]

106-95-6
556-56-9
Synthesis of ALLYL IODIDE from Allyl bromide
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View Lastest Price from ALLYL IODIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
ALLYL IODIDE pictures 2020-01-13 ALLYL IODIDE
556-56-9
US $1.00 / KG 1KG 98%-99.9% 200kg Career Henan Chemical Co
  • ALLYL IODIDE pictures
  • ALLYL IODIDE
    556-56-9
  • US $1.00 / KG
  • 98%-99.9%
  • Career Henan Chemical Co
1-propene,3-iodo- 2-Propene, 1-iodo 2-Propenyliodide 3-iodo-1-propen 3-iodo-prop-1-ene 3-iodo-propen 3-Iodpropen 3-Jod-1-propen 3-Jodpropen Allyliodid Allyljodid CH2CHCH2I Propene, 3-iodo- Allyl Iodide  Allyl iodide, stabilized, 98% 25ML 3-Iodo-1-propene 3-Iodopropylene 3-Iodo-1-propene for synthesis Allyl iodide, Stabilized with copper propene,3-iodo- 3-IODOPROPYLENE ALLYL IODIDE ALLYL IODIDE, STAB. Allyliodide,97% Allyl iodide, stabilized, 98% Allyl iodide;3-Iodopropene Allyl iodide, 97+%, stab. with copper Allyl Iodide (stabilized with Copper chip) 3-iodpropene allyl iodide Allyl iodide, 98%, stabilized 3-Iodopropene 1g [556-56-9] Allyl iodide, 97%, stabilized, AllylIodide(stabilizedwithCopperchip)> 3-IODOPROPENE 3-IODO-1-PROPENE 556-56-9 ICH2CHCH2 C3H5I ALKYNE 蠅-Unsaturated Halides 蠅-Functional Alkanols, Carboxylic Acids, Amines & Halides Organic Building Blocks Building Blocks Alkenes Acyclic omega-Functional Alkanols, Carboxylic Acids, Amines & Halides omega-Unsaturated Halides