Allylacetic acid
- CAS No.
- 591-80-0
- Chemical Name:
- Allylacetic acid
- Synonyms
- PENT-4-ENOIC ACID;4-PENTYNOIC ACID;4-PENTENOIC ACID;PROPARGYLACETIC ACID;4 PA;FEMA 2843;4-Pentensαure;PENT-4-ENOATE;AUYLACETICACID;Anulacetic acid
- CBNumber:
- CB6264516
- Molecular Formula:
- C5H8O2
- Molecular Weight:
- 100.12
- MDL Number:
- MFCD00004408
- MOL File:
- 591-80-0.mol
- MSDS File:
- SDS
| Melting point | -22.5 °C (lit.) |
|---|---|
| Boiling point | 83-84 °C/12 mmHg (lit.) |
| Density | 0.981 g/mL at 25 °C (lit.) |
| vapor density | >1 (vs air) |
| refractive index |
n |
| FEMA | 2843 | 4-PENTENOIC ACID |
| Flash point | 193 °F |
| storage temp. | 2-8°C |
| solubility | soluble in Chloroform, Methanol |
| pka | pK1:4.677 (25°C) |
| form | Liquid |
| Specific Gravity | 0.981 |
| color | Clear colorless to light yellow |
| Odor | at 0.10 % in propylene glycol. cheese parmesan romano ricotta |
| Odor Type | cheesy |
| explosive limit | 1.58%(V) |
| Water Solubility | Soluble in alcohol, Slightly soluble in water |
| JECFA Number | 314 |
| BRN | 1633696 |
| InChIKey | HVAMZGADVCBITI-UHFFFAOYSA-N |
| LogP | 0.99 |
| CAS DataBase Reference | 591-80-0(CAS DataBase Reference) |
| Substances Added to Food (formerly EAFUS) | 4-PENTENOIC ACID |
| FDA 21 CFR | 172.515 |
| EWG's Food Scores | 1 |
| FDA UNII | D4S77Y29FB |
| NIST Chemistry Reference | 4-Pentenoic acid(591-80-0) |
| EPA Substance Registry System | 4-Pentenoic acid (591-80-0) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H314 | |||||||||
| Precautionary statements | P280-P301+P312+P330-P301+P330+P331-P303+P361+P353-P305+P351+P338+P310 | |||||||||
| Hazard Codes | C,T | |||||||||
| Risk Statements | 34-22 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 3261 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | SC4751000 | |||||||||
| F | 8-10-23 | |||||||||
| TSCA | T | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29161980 | |||||||||
| Toxicity | LD50 oral in rat: 470mg/kg | |||||||||
| NFPA 704 |
|
Allylacetic acid price More Price(33)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | W284300 | 4-Pentenoic acid ≥98%, stabilized, FG | 591-80-0 | 25g | $90.5 | 2024-03-01 | Buy |
| Sigma-Aldrich | W284300 | 4-Pentenoic acid ≥98%, stabilized, FG | 591-80-0 | 100g | $98.8 | 2024-03-01 | Buy |
| Sigma-Aldrich | W284300 | 4-Pentenoic acid ≥98%, stabilized, FG | 591-80-0 | 1kg | $959 | 2024-03-01 | Buy |
| Sigma-Aldrich | 245925 | 4-Pentenoic acid 97% | 591-80-0 | 5g | $40.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 245925 | 4-Pentenoic acid 97% | 591-80-0 | 25g | $173 | 2024-03-01 | Buy |
Allylacetic acid Chemical Properties,Uses,Production
Description
Allylacetic acid (allyl acetate) is a derivative of acetate. It is the acetate ester of allyl alcohol. It is useful industrial intermediate. It is the precursor of some special polymer such as drying oils. It can also be used as a useful allylating reagent for catalyzing the allylation of aldehydes, and also allylation of aryl bromides in the palladium-catalyzed cross-coupling reaction. It has also demonstrated that it is a potential fumigant against grain beetle pests; study has shown that doses of 50–150 mg litre?1 with 24–120-h exposures are necessary to achieve 100% mortality of all life stages against grain beetle pests. Study has also shown that ally acetate is an effective oxidants during the Palladium— Iminophosphine-Catalyzed Homocoupling of Alkynylstannanes and Other Organostannanes
References
Denmark, S. E., and S. T. Nguyen. "Catalytic, nucleophilic allylation of aldehydes with allyl acetate. " Organic Letters 11.3 (2009):781-4.
Yokoyama, Y., et al. "ChemInform Abstract: Palladium- Catalyzed Cross-Coupling Reaction: Direct Allylation of Aryl Bromides with Allyl Acetate."Chemischer Informationsdienst 26.52 (1986):6457-6460.
Rajendran, Dr Somiahnadar, and N. Muralidharan. "Effectiveness of allyl acetate as a fumigant against five stored grain beetle pests." Pest Management Science 61.1(2005):97-101.
Shirakawa, Eiji, et al. "Palladium—Iminophosphine-Catalyzed Homocoupling of Alkynylstannanes and Other Organostannanes Using Allyl Acetate or Air as an Oxidant." Journal of Organometallic Chemistry670.1(2003):132-136.
Chemical Properties
4-Pentenoic acid has a sour, caramellic flavor with sweet aftertaste. It has an acrid flavor and odor at high levels.
Chemical Properties
clear colorless to light yellow liquid
Uses
4-Pentenoic acid (Allylacetic acid) was used to inhibit fatty acid oxidation in rat heart mitochondria.
Uses
The sulfonation of 4-pentenoic acid (Allylacetic acid) yields the corresponding γ-lactone. It was used to inhibit fatty acid oxidation in rat heart mitochondria.
Uses
Sulfonation yields the corresponding γ-lactone.1
Preparation
By decarboxylation via heating allylmalonic acid; from the corresponding ethyl ester prepared by boiling ethyl 4-chloron- valerate in quinoline.
Definition
ChEBI: A pentenoic acid having the double bond at position 4.
Synthesis Reference(s)
Synthetic Communications, 13, p. 889, 1983 DOI: 10.1080/00397918308059542
General Description
4-Pentenoic acid is a volatile acid reported to be found in tobacco.
Safety Profile
Poison by subcutaneous and intraperitoneal routes. Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes.
Allylacetic acid Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15933 | 58 |
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8823 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49390 | 58 |
| SIMAGCHEM CORP | +86-13806087780 | sale@simagchem.com | China | 17367 | 58 |
| WUHAN CIRCLE POWDER TECHNOLOGY CO.,LTD | +8615377521700 | wangwendy93@gmail.com | China | 868 | 58 |
View Lastest Price from Allylacetic acid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-03-16 | Allylacetic acid
591-80-0
|
US $0.00 / KG | 100g | 98%+ | 100kg | WUHAN CIRCLE POWDER TECHNOLOGY CO.,LTD | |
 |
2023-03-23 | Allylacetic Acid
591-80-0
|
US $5.00-2.00 / KG | 1KG | 99% | 10000kg | Hebei Guanlang Biotechnology Co,.LTD | |
 |
2023-02-13 | 4-Pentenoic acid
591-80-0
|
US $10.00 / KG | 1KG | 99% | 50MT | Hebei baicao biology science and technology co., ltd |
-
- Allylacetic acid
591-80-0
- US $0.00 / KG
- 98%+
- WUHAN CIRCLE POWDER TECHNOLOGY CO.,LTD
-
- Allylacetic Acid
591-80-0
- US $5.00-2.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co,.LTD
-
- 4-Pentenoic acid
591-80-0
- US $10.00 / KG
- 99%
- Hebei baicao biology science and technology co., ltd
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