2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane
- CAS No.
- 83558-87-6
- Chemical Name:
- 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane
- Synonyms
- 6FAP;AHHFP;BAFA;4,4'-(Perfluoropropane-2,2-diyl)bis(2-aMinophenol);BAPAF;2,2-Bis(3-aMino-4-hydroxylphenyl)hexafluoropropane(6FAP);1,1-Bis(3-aMino-4-hydroxyphenyl)-2,2,2-trifluoro-1-(trifluoroMethyl)ethane;BIS-AP-AF;Bis-AP-AF2;Bis-AP-AF/6FAP
- CBNumber:
- CB7397729
- Molecular Formula:
- C15H12F6N2O2
- Molecular Weight:
- 366.26
- MDL Number:
- MFCD00039147
- MOL File:
- 83558-87-6.mol
- MSDS File:
- SDS
Melting point | 245-248 °C (lit.) |
---|---|
Boiling point | 411.3±45.0 °C(Predicted) |
Density | 1.545±0.06 g/cm3(Predicted) |
storage temp. | under inert gas (nitrogen or Argon) at 2–8 °C |
solubility | DMSO (Slightly), Methanol (Slightly) |
pka | 9.07±0.10(Predicted) |
form | Solid |
color | White to Off-White |
InChI | InChI=1S/C15H12F6N2O2/c16-14(17,18)13(15(19,20)21,7-1-3-11(24)9(22)5-7)8-2-4-12(25)10(23)6-8/h1-6,24-25H,22-23H2 |
InChIKey | MSTZGVRUOMBULC-UHFFFAOYSA-N |
SMILES | C(C1=CC=C(O)C(N)=C1)(C1=CC=C(O)C(N)=C1)(C(F)(F)F)C(F)(F)F |
CAS DataBase Reference | 83558-87-6(CAS DataBase Reference) |
EPA Substance Registry System | Phenol, 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis[2-amino- (83558-87-6) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-36 | |||||||||
WGK Germany | 3 | |||||||||
Hazard Note | Irritant | |||||||||
HS Code | 29222990 | |||||||||
NFPA 704 |
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2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane price More Price(36)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 541710 | 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane 97% | 83558-87-6 | 5g | $67.68 | 2024-03-01 | Buy |
TCI Chemical | B1415 | 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane >98.0%(T) | 83558-87-6 | 5g | $86 | 2024-03-01 | Buy |
TCI Chemical | B1415 | 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane >98.0%(T) | 83558-87-6 | 25g | $257 | 2024-03-01 | Buy |
TRC | B591980 | 2,2-Bis(3-Amino-4-hydroxyphenyl(hexafluoropropane)) | 83558-87-6 | 500mg | $50 | 2021-12-16 | Buy |
SynQuest Laboratories | 4756-3-34 | 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane 99% | 83558-87-6 | 25g | $60 | 2021-12-16 | Buy |
2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane Chemical Properties,Uses,Production
Description
2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane (6FAP) is white crystal. Its boiling point and density are expected to be 411.3±45.0 °C and 1.545±0.06 g/cm3, respectively. It is slightly soluble in DMSO and methanol.The product is non-toxic and can be stored at room temperature away from light and air.
Synthesis
30 g two (3-nitro-4-hydroxyphenyl) hexafluoropropanes are dropped into
the 1000 mL autoclave, add 300 g DMF and 1.5 g palladium/carbon (the
mass fraction of palladium in the palladium/carbon is 5%), press
hydrogen to 1MPa, open stirring and be warmed up to 70 ℃, stop reaction
after two (3-nitro-4-hydroxyphenyl) hexafluoropropane content<0.1%,
target product two (3-amino-4-hydroxyphenyl) hexafluoropropane
Fluoropropane gas phase content is 98%, and the system is black, and the
temperature of the still is lowered to room temperature, filtered, and
the filtrate is de-dried under reduced pressure at 70-80°C to obtain
bis(3-amino-4-hydroxyphenyl) hexafluoropropane crude product , the crude
product is recrystallized, the recrystallization solvent is water and
DMF, and the mass ratio of
bis(3-amino-4-hydroxyphenyl)hexafluoropropane, water and DMF is 1:4:2.
First, the bis(3-nitro-4-hydroxyphenyl) hexafluoropropane crude product
is mixed with the recrystallization solvent to increase the still
temperature to 60 °C and stir, and then the still temperature is reduced
to 10-20 °C for crystallization, filtered, After drying, 25.4 g of pure
bis(3-nitro-4-hydroxyphenyl)hexafluoropropane was obtained. The yield
of bis(3-amino-4-hydroxyphenyl)hexafluoropropane was 98.3% and the
purity was 99.6%. 1H-NMR (400MHz, D6-DMSO) δ (ppm): 4.64 (s, 4H), 6.42 (d, 2H), 7.57 (s, 2H), 6.65 (d, 2H), 9.36 (s, 2H). 19F-NMR (400MHz, D6-DMSO) δ (ppm): -62.78. [1].
Physical properties
White powder
Uses
2,2-bis(3-amino-4-hydroxyphenyl)hexafluoropropane(BisAPAF) is a polyimide monomer.It is mairly used in the aynthesis of the heat resisting polymers,especially in the manufacture of specialty polymeoric electronic material-fluorinated polyimides.
General Description
2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane, also referred to as 4,4′-(1,1,1,3,3,3-hexafluoro-2,2-propanediyl)bis(2-aminophenol), is an aromatic diamine.
2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Fluoropharm Co., Ltd. | +86-0571-85586753; +8613336034509 | sales@fluoropharm.com | China | 1377 | 60 |
CHINATECH(TIANJIN) CHEMICAL CO.,LTD. | +8618222493702 | sales8@chinatechem.com | China | 61 | 58 |
Jinan Finer Chemical Co., Ltd | +86-531-88989536 +86-15508631887 | sales@finerchem.com | China | 2968 | 58 |
Shanghai Daeyeon Chemicals Co., Ltd | 021-64478606 +8615900664856 | daeyeon001@vip.163.com | China | 2062 | 58 |
Henan Allgreen Chemical Co.,LTD | +86-37155567971 +86-13633837469 | info@allgreenchem.com | China | 5986 | 58 |
Heynova (Shanghai) New Material Technology CO., Ltd | +86-17821320848 | zoe@heynovachem.com | China | 431 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 6710 | 58 |
Hangzhou ICH Biofarm Co., Ltd | +undefined8613073685410 | sales@ichemie.com | China | 985 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 16805 | 58 |
Related articles
- Synthesis and Application of 2,2-bis(3-amino-4-hydroxyphenyl)hexafluoropropane
- 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane is an important synthetic intermediate.
- Aug 26,2022
View Lastest Price from 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-04-23 | 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane
83558-87-6
|
US $1.00 / KG | 1KG | 99.91% | 200000 | Ouhuang Engineering Materials (Hubei) Co., Ltd | ||
2024-02-23 | 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane
83558-87-6
|
US $24.00-151.00 / g | 25g | 0.98 | 100kg | Shanghai UCHEM Inc. | ||
2024-01-23 | 2,2-Bis(3-amino-4-hydroxyphenyl)-hexafluoropropane(Bis-AP-AF/6FAP)
83558-87-6
|
US $0.00 / KG | 1KG | 99% | 1500KG/month | Shanghai Daken Advanced Materials Co.,Ltd |
- 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane
83558-87-6
- US $1.00 / KG
- 99.91%
- Ouhuang Engineering Materials (Hubei) Co., Ltd
- 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane
83558-87-6
- US $24.00-151.00 / g
- 0.98
- Shanghai UCHEM Inc.
- 2,2-Bis(3-amino-4-hydroxyphenyl)-hexafluoropropane(Bis-AP-AF/6FAP)
83558-87-6
- US $0.00 / KG
- 99%
- Shanghai Daken Advanced Materials Co.,Ltd