Mannose Triflate
- CAS No.
- 92051-23-5
- Chemical Name:
- Mannose Triflate
- Synonyms
- MANNOSE TRIFLATE;TATM;TATM USP/EP/BP;MANNOSE TRIFLATE F;beta-D-Mannopyranose;Mannose Triflate?New;Mannose triflate≥ 99%(GC);1,3,4,6-Tetra-O-acetyl-2-O-;Mannose Triflate, ultra pure;Mannose Triflate PLUS, ultra pure
- CBNumber:
- CB7774955
- Molecular Formula:
- C15H19F3O12S
- Molecular Weight:
- 480.36
- MDL Number:
- MFCD00012353
- MOL File:
- 92051-23-5.mol
- MSDS File:
- SDS
Melting point | 118-122 °C |
---|---|
alpha | [α]D20 -14~-17゜(c=1,CHCl3) |
Boiling point | 481.6±45.0 °C(Predicted) |
Density | 1.50±0.1 g/cm3(Predicted) |
refractive index | -16 ° (C=1, CHCl3) |
storage temp. | -20°C |
solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) |
form | Solid |
color | White to Off-White |
optical activity | [α]22/D -16°, c = 1 in chloroform |
BRN | 4341413 |
InChI | InChI=1/C15H19F3O12S/c1-6(19)25-5-10-11(26-7(2)20)12(27-8(3)21)13(14(29-10)28-9(4)22)30-31(23,24)15(16,17)18/h10-14H,5H2,1-4H3/t10-,11-,12+,13+,14-/s3 |
InChIKey | OIBDVHSTOUGZTJ-UBBZJQTNNA-N |
SMILES | [C@H]1(OC(=O)C)[C@H](OC(=O)C)[C@H](O[C@@H](OC(=O)C)[C@H]1OS(=O)(=O)C(F)(F)F)COC(=O)C |&1:0,5,10,12,17,r| |
FDA UNII | 0KI8FFQ6TT |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H335-H315-H319 |
Precautionary statements | P261-P280-P271 |
Hazard Codes | Xi |
Safety Statements | 24/25 |
WGK Germany | 3 |
F | 10-21 |
HS Code | 29329990 |
Mannose Triflate price More Price(38)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | M1568 | Mannose triflate For PET imaging, ≥98% (TLC) | 92051-23-5 | 20mg | $27.3 | 2024-03-01 | Buy |
Sigma-Aldrich | Y0001087 | Tetra-O-acetyl-mannose triflate European Pharmacopoeia (EP) Reference Standard | 92051-23-5 | 2each | $144 | 2024-03-01 | Buy |
Sigma-Aldrich | 655112 | β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate 98% | 92051-23-5 | 100mg | $28.4 | 2024-03-01 | Buy |
Sigma-Aldrich | Y0001087 | Tetra-O-acetyl-mannose triflate European Pharmacopoeia (EP) Reference Standard | 92051-23-5 | 2EA | $144 | 2023-06-20 | Buy |
TCI Chemical | T2307 | 1,3,4,6-Tetra-O-acetyl-2-O-(trifluoromethanesulfonyl)-beta-D-mannopyranose >98.0%(GC) | 92051-23-5 | 100mg | $39 | 2024-03-01 | Buy |
Mannose Triflate Chemical Properties,Uses,Production
Description
Mannose triflate is a glucose analog. Mannose triflate is a well-known precursor for 18F-FDG synthesis for PET applications. 18F-FDG is an imaging technique for cancer.
Physical properties
White to off-white powder or crystal
Uses
1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-beta-D-mannopyranose is a radiolabelled pharmaceutical preparation for diagnostic aims used in positron emission tomography.
Preparation
The tetraacetyl mannose (1.8 g, 5 mmol) was dissolved in anhydrous CH2Cl2(14 mL) containing dry pyridine (0.9 mL, 11 mmol). This solution was cooled to -15°C, and trifluoromethanesulfonic anhydride (triflic anhydride) (0.9 mL, 5.2 mmol) was added dropwise over 25 min under a nitrogen atmosphere with vigorous stirring. The mixture was then allowed to reach room temperature overnight. The reaction mixture was successively washed with ice-cold saturated aqueous NaHCO3(50 mL) and water (50 mL). The organic layer was dried over anhydrous Na2SO4, filtered, and concentrated on a rotary evaporator.2-Tf-O-AcManwas isolated by column chromatography on silica with hexane :EtOAc=1: 1 as the eluant as white solid Mannose triflate(1.4 g, 56percent).
Mannose Triflate Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Qingdao Yonghefeng Economic and Trade Co., Ltd. | +86-13375559818 +86-13375559818 | cfy69@163.com | China | 195 | 58 |
Zibo Hangyu Biotechnology Development Co., Ltd | +86-0533-2185556 +8617865335152 | Mandy@hangyubiotech.com | China | 10991 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20293 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18629 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21667 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32836 | 60 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29888 | 58 |
SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | sales@sdzschem.com | China | 2931 | 58 |
Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 7621 | 58 |
Hebei Jimi Trading Co., Ltd. | +86 319 5273535 | bestoneforyou@sina.com | CHINA | 288 | 58 |
View Lastest Price from Mannose Triflate manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-09-18 | Mannose Triflate
92051-23-5
|
US $0.00 / G | 1G | 98%min | 30kg/month | WUHAN FORTUNA CHEMICAL CO., LTD | ||
2024-08-27 | TATM
92051-23-5
|
US $50.00-500.00 / kg | 10kg | 0.99 | 20tons | Zibo Hangyu Biotechnology Development Co., Ltd | ||
2024-03-29 | TATM
92051-23-5
|
US $6.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd |
- Mannose Triflate
92051-23-5
- US $0.00 / G
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
- TATM
92051-23-5
- US $50.00-500.00 / kg
- 0.99
- Zibo Hangyu Biotechnology Development Co., Ltd
- TATM
92051-23-5
- US $6.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
92051-23-5(Mannose Triflate)Related Search:
1of4