2-Bromoisobutyryl Bromide
- CAS No.
- 20769-85-1
- Chemical Name:
- 2-Bromoisobutyryl Bromide
- Synonyms
- BIBB;2-Bromo-2-methylpropanoyl bromide;2-BROMO-2-METHYLPROPIONYL BROMIDE;α-Bromoisobutyryl bromide;A-BROMOISOBUTYRYL BROMIDE;2-Bromoisobutyric acid bromide;2-Bromo-2-methyl;2-BROMOISOBUTYRYL BROMIDE;2-broMoisobutylyl broMide;α-Bromoisobutyryl bromide
- CBNumber:
- CB8440211
- Molecular Formula:
- C4H6Br2O
- Molecular Weight:
- 229.9
- MDL Number:
- MFCD00000122
- MOL File:
- 20769-85-1.mol
- MSDS File:
- SDS
Boiling point | 162-164 °C(lit.) |
---|---|
Density | 1.86 g/mL at 20 °C |
refractive index |
n |
Flash point | >110°C |
storage temp. | Store below +30°C. |
solubility | Miscible with acetone and carbon disulfide. |
form | Liquid |
Specific Gravity | 1.860 (20/4℃) |
color | Clear light yellow to yellow |
Water Solubility | reacts |
Sensitive | Moisture Sensitive |
BRN | 1746128 |
Stability | Stable, but may react with moisture. Incompatible with water, strong oxidizing agents, strong bases. |
CAS DataBase Reference | 20769-85-1(CAS DataBase Reference) |
FDA UNII | 627F9N9DYA |
NIST Chemistry Reference | Propanoyl bromide, 2-bromo-2-methyl-(20769-85-1) |
EPA Substance Registry System | Propanoyl bromide, 2-bromo-2-methyl- (20769-85-1) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05 |
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Signal word | Danger | |||||||||
Hazard statements | H314 | |||||||||
Precautionary statements | P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
Hazard Codes | C | |||||||||
Risk Statements | 22-34 | |||||||||
Safety Statements | 26-36/37/39-45 | |||||||||
RIDADR | UN 3265 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29159080 | |||||||||
NFPA 704 |
|
2-Bromoisobutyryl Bromide price More Price(25)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 252271 | α-Bromoisobutyryl bromide 98% | 20769-85-1 | 100g | $62.1 | 2024-03-01 | Buy |
Sigma-Aldrich | 252271 | α-Bromoisobutyryl bromide 98% | 20769-85-1 | 500g | $207 | 2024-03-01 | Buy |
TCI Chemical | B0607 | 2-Bromoisobutyryl Bromide >98.0%(GC) | 20769-85-1 | 25g | $28 | 2024-03-01 | Buy |
TCI Chemical | B0607 | 2-Bromoisobutyryl Bromide >98.0%(GC) | 20769-85-1 | 100g | $47 | 2024-03-01 | Buy |
Alfa Aesar | B24249 | 2-Bromoisobutyryl bromide, 97% | 20769-85-1 | 25g | $29.65 | 2024-03-01 | Buy |
2-Bromoisobutyryl Bromide Chemical Properties,Uses,Production
Description
2-Bromoisobutyryl Bromide is a kind of bromide being useful in the chemical industry. It is used as an intermediate for the synthesis of pharmaceuticals, agrochemicals, dyes and other organic chemicals1. It can be used as atom transfer radical polymerization (ATRP) initiator for functionalization of hydroxyl groups present on the surface of graphene oxide; to form an N-protected halodienamide which provided fourand five-membered lactams in the presence of copper (I) and a tertiary amine; in preparation of polycaprolactone macroinitiator via reaction with oligomeric caprolactone dio and mesoporous silica nanoparticles with ATRP initiator anchored on the exterior surface2,3. As a initiator precursor, it can also be used for surface modification of Ethylene-vinyl alcohol (EVOH) copolymer films to grow surface-grafted poly-(acrylamide) chains.
Sources
- http://www.chemicalland21.com/specialtychem/finechem/2-BROMOISOBUTYRYL%20BROMIDE.htm
- https://www.alfa.com/zh-cn/catalog/B24249/
- https://www.sigmaaldrich.com/catalog/product/aldrich/252271?lang=en®ion=US
- https://pubs.acs.org/doi/abs/10.1021/bk-2003-0854.ch025
Chemical Properties
colourless liquid
Uses
α-Bromoisobutyryl bromide has been used:
- as atom transfer radical polymerization (ATRP) initiator for functionalization of hydroxyl groups present on the surface of graphene oxide
- to form an N-protected halodienamide which provided four- and five-membered lactams in the presence of copper (I) and a tertiary amine
- in preparation of polycaprolactone macroinitiator via reaction with oligomeric caprolactone diol and mesoporous silica nanoparticles with ATRP initiator anchored on the exterior surface
Uses
2-Bromoisobutyryl bromide is used to prepare N-protected halodienamide, which provides four- and five-membered lactams in the presence of copper(I) and a tertiary amine. Further, it is used as atom transfer radical polymerization(ATRP) initiator for functionalization of hydroxyl groups present on the surface of graphene oxide. It is also used in preparation of polycaprolactone macroinitiators through reaction with oligomeric caprolactone diol and mesoporous silica nanoparticles with ATRP initiator anchored on the exterior surface.
2-Bromoisobutyryl Bromide Preparation Products And Raw materials
Raw materials
Preparation Products
1of3
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12446 | 58 |
Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5873 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5882 | 58 |
Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 | admin@zlchemi.com | China | 3002 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18628 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +8618949832763 | info@tnjchem.com | China | 2989 | 55 |
Zhejiang ZETian Fine Chemicals Co. LTD | +8618957127338 | stella@zetchem.com | China | 2136 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8820 | 58 |
View Lastest Price from 2-Bromoisobutyryl Bromide manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-09-19 | 2-Bromoisobutyryl Bromide
20769-85-1
|
US $5.00-2.00 / KG | 1KG | 99% | 10000kg | Hebei Chuanghai Biotechnology Co,.LTD | ||
2024-08-15 | 2-Bromoisobutyryl bromide
20769-85-1
|
US $30.00-10.00 / kg | 1kg | 0.99 | 10 tons | Hebei Yanxi Chemical Co., Ltd. | ||
2024-06-04 | 2-Bromoisobutyryl Bromide
20769-85-1
|
US $60.00 / kg | 1kg | 99% | 5000kg/week | Hebei Zhuanglai Chemical Trading Co.,Ltd |
- 2-Bromoisobutyryl Bromide
20769-85-1
- US $5.00-2.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD
- 2-Bromoisobutyryl bromide
20769-85-1
- US $30.00-10.00 / kg
- 0.99
- Hebei Yanxi Chemical Co., Ltd.
- 2-Bromoisobutyryl Bromide
20769-85-1
- US $60.00 / kg
- 99%
- Hebei Zhuanglai Chemical Trading Co.,Ltd