(R)-2,6-ジメチル-7-オクテン-2-オール 化学特性,用途語,生産方法
説明
Dihydromyrcenol is a colorless liquid with a fresh citrus-like odor and a lavender note. It is obtained from 3,7-dimethyl-1,6- octadiene (citronellene), the pyrolysis product of cis-pinane and can be prepared by three different processes: (i) by addition of hydrogen chloride and subsequent hydrolysis of the resulting 2,6-dimethyl-2-chloro-7-octene; or (ii) by addition of formic acid and subsequent saponification of the resulting dihydromycrenyl formate; or (iii) by direct hydroxylation with 60–80% sulfuric acid.Dihydromyrcenol is used in fine fragrances as well as in soap and detergent perfumes for fresh lime and citrus-like floral notes.
化学的特性
Clear Colorless liquid, insoluble in water, soluble in 4-6 volumes of 55% ethanol or 1-2 volumes of 70% ethanol, also soluble in oily fragrances. The aroma is sweet and powerful, with fresh and spicy citrus, pine and cypress, lavender, fruity, floral, sweet and sour aromas, and has white lemon and cologne flavors.
天然物の起源
Has apparently not been reported to occur in nature.
使用
Dihydromyrcenol is an organic compound from the group of the acyclic terpenoidal alcohols. It is a fragrance with a powerful, fresh, lavender like, sweet citrus and floral fragrance, which is synthetically prepared. The pure substance appears as a colorless viscous liquid, which is practically insoluble in water.
製造方法
Dihydromyrcenol is prepared by addition of dihydromyrcene (generated from the cleavage of pinane, the hydrogenation product of pinene), with water and formic acid under acid catalysis.
By controlled, partial hydrogenation of myrcenol (Arctander, 1969).
(R)-2,6-ジメチル-7-オクテン-2-オール 上流と下流の製品情報
原材料
準備製品