4-ニトロベンジル クロリド

4-ニトロベンジル クロリド MSDS

a-Chloro-4-nitrotoluene

4-ニトロベンジル クロリド 化学特性,用途語,生産方法

外観

白色～うすい黄色、結晶～結晶性粉末

用途

有機合成原料 (NITE総合検索 (ACCESS ON JAN. 2011)

化学的特性

white to light yellow crystal powde

使用

4-Nitrobenzyl chloride was used to prepare unsymmetrically N,N′-bis(substituted) 4,13-diaza-18-crown-6-ether derivatives.

調製方法

Chlorination of 4-nitrotoluene at 190 ℃ without catalyst gives 4-Nitrobenzyl chloride. The alternative process of nitration of benzylchloride coproduces 2-nitrobenzyl chloride and requires a difficult separation stage.

定義

ChEBI: A C-nitro compound that is nitrobenzene in which the hydrogen at position 4 is replaced by a chloromethyl group.

一般的な説明

Solid.

空気と水の反応

May react slowly with water.

反応プロフィール

Incompatible with sodium hydroxide. [EPA, 1998]. A halogenated aromatic nitro compound. Aromatic nitro compounds range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.

健康ハザード

Poisonous if swallowed or dust is inhaled.

火災危険

Incompatible with sodium hydroxide.

職業ばく露

A chloronitrobenzene compound, used in organic synthesis.

輸送方法

UN3261 Corrosive solid, acidic, organic, n.o.s., Hazard class: 8; Labels: 8—Corrosive material, Technical Name Required. UN1578 Chloronitrobenzenes, solid or liquid, Hazard Class: 6.1; Labels: 6.1—Poisonous materials.

純化方法

Crystallise the chloride from CCl4, dry diethyl ether, or n-heptane, and dry it under vacuum. IRRITANT.[Beilstein 5 IV 856.]

不和合性

Can react with sulfuric acid. Keep away from oxidizers, amines, bases: sodium hydroxide, and potassium hydroxide; may cause fire and explosions. Incompatible with strong oxidizing and reducing agents such as hydrides, certain amines, nitrides, azo/diazo compounds, alkali metals (potassium), and epoxides. Corrodes steel, some plastics and human tissue.

4-ニトロベンジル クロリド 上流と下流の製品情報

原材料

準備製品

100-14-1(4-ニトロベンジル クロリド)キーワード:

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• 100-14-1
• α-Chloro-4-nitrotoluene
• Nitrobenzylchloride
• p-Nitrobenzylchloride 4-Nitrobenzylchloride
• p-nitrochloride
• à-chloro-4-nitrotoluene
• ALPHA-CHLORO-PARA-NITROTOLUENE
• TOLUENE,ALPHA-CHLORO-PARA-NITRO-
• 4-Nitrobenzyl chloride,α-Chloro-4-nitrotoluene
• 4-Nitrobenzyl chloride, 99% 100GR
• 4-Nitrobenzyl chloride, 99% 10GR
• 4-NITROBENZYL CHLORIDE 99%
• Benzene, 1-(chloromethyl)-4-nitro-: (p-Nitrobenzyl chloride)
• 1-CHLORO-4-NITROTOLUENE
• 4-Nitrophenylmethyl chloride
• 4-Nitro-1-(chloromethyl)benzene
• α-Chloro-p-nitrotoluene
• 4-Nitrobenzyl chloride,99%
• Nitrobenzyl chlorid
• [(4-nitrophenyl)Methyl]chloranuide
• toluene,alpha-chloro-p-nitro-[qr]
• alpha-chloro-p-nitro-toluen
• alpha-chloro-p-nitrotoluene[qr]
• Benzene, 1-(chloromethyl)-4-nitro-
• benzene,1-(chloromethyl)-4-nitro-[qr]
• benzylchloride,4-nitro[qr]
• p-(Chloromethyl)nitrobenzene
• p-nitrobenzylchloride[qr]
• Toluene, alpha-chloro-p-nitro
• Toluene, alpha-chloro-p-nitro-
• 1-(Chloromethyl)-4-nitrobenzene, 4-(Chloromethyl)nitrobenzene
• 4-ニトロベンジル クロリド
• 1-(クロロメチル)-4-ニトロベンゼン
• 4-(クロロメチル)-1-ニトロベンゼン
• 4-ニトロ-1-(クロロメチル)ベンゼン
• 1-ニトロ-4-(クロロメチル)ベンゼン
• p-ニトロベンジルクロリド
• 4-ニトロベンジルクロリド
• α-クロロ-p-ニトロトルエン
• 1-クロロメチル-4-ニトロベンゼン
• α-クロロ-4-ニトロトルエン
• 4-ニトロベンジルクロライド
• 塩化P-ニトロベンジル
• 1‐(クロロメチル)‐4‐ニトロベンゼン
• Α‐クロロ‐P‐ニトロトルエン
• 塩化4-ニトロベンジル