클로로벤질산

클로로벤질산
클로로벤질산 구조식 이미지
카스 번호:
510-15-6
한글명:
클로로벤질산
동의어(한글):
클로로벤질레이트;클로로벤질산;4,4'-다이클로로벤질산, 에틸 에스터;4-클로로-알파-(4-클로로페닐)-알파-하이드록시벤젠아세트산, 에틸 에스터;벤젠아세트산, 4-클로로-알파-(4-클로로페닐)-알파-하이드록시, 에틸 에스터;벤질산, 4,4'-다이클로로-, 에틸 에스터;에틸 4,4'-다이클로로벤질레이트;에틸 4-클로로-알파-(4-클로로페닐)-알파-하이드록시벤젠아세테이트;에틸 p,p'-다이클로로벤질레이트;에틸 다이클로로벤질레이트
상품명:
CHLOROBENZILATE
동의어(영문):
g338;Acar;Akar;G 338;G23922;akar50;Folbex;AKAR(R);G 23992;Akar 50
CBNumber:
CB1431322
분자식:
C16H14Cl2O3
포뮬러 무게:
325.19
MOL 파일:
510-15-6.mol
MSDS 파일:
SDS

클로로벤질산 속성

녹는점
37-38℃
끓는 점
bp0.04 146-148°
밀도
1.332
굴절률
1.5727
저장 조건
0-6°C
산도 계수 (pKa)
11.11±0.29(Predicted)
수용성
13mg/L(20℃)
Merck
13,2141
안정성
안정적인. 타기 쉬운. 강한 산화제, 강산, 알칼리, 석회와 호환되지 않습니다.
CAS 데이터베이스
510-15-6(CAS DataBase Reference)
IARC
3 (Vol. 30, Sup 7) 1987
EPA
Chlorobenzilate (510-15-6)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,N,T
위험 카페고리 넘버 22-50/53-63-43-36/37/38-23/24/25-45-67-40
안전지침서 60-61-36/37-24/25-23-53
유엔번호(UN No.) UN 1593 6.1/PG 3
WGK 독일 3
RTECS 번호 DD2275000
HS 번호 29181800
유해 물질 데이터 510-15-6(Hazardous Substances Data)
독성 LD50 in male, female rats (mg/kg): 1040, 1220 orally (Gaines)
기존화학 물질 KE-05574
유해화학물질 필터링 99-1-497;06-4-29
함량 및 규제정보 물질구분: 금지물질; 혼합물(제품)함량정보: 클로로벤질레이트 및 이를 1% 이상 함유한 혼합물
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

클로로벤질산 C화학적 특성, 용도, 생산

개요

Chlorobenzilate is an organochlorine pesticide belonging to the same class as dichlorodiphenyltrichloroethane (DDT). It was originally developed by Ciba–Geigy and introduced in 1952.

화학적 성질

Ethyl 4,40 -dichlorobenzilate is a yellow solid when pure. The technical product is a brownish liquid.

용도

The primary use of chlorobenzilate is as an acaricide for mite control on citrus crops and in beehives. It has a narrow insecticidal action, killing only mites and ticks. Historically, chlorobenzilate was used as a synergist for DDT. Although now banned for use in the United States and Europe, it is believed to be used on crops other than citrus in other countries.

일반 설명

Viscous yellow liquid or pale yellow crystals. Light brown crystalline solid.

공기와 물의 반응

Insoluble in water.

반응 프로필

CHLOROBENZILATE is hydrolyzed by alkalis and strong acids. Incompatible with lime .

건강위험

Moderately toxic by oral route; toxic symptoms similar to DDT and Perthane; ingestionof large dose can produce nausea, vomiting,tremor and convulsions; skin or eye contactcan cause irritation; application of 25 mgproduced moderate irritation of eye inrabbits; adequate evidence of carcinogenicityin experimental animals; produced tumors inrats and mice; evidence of carcinogenicity inhumans remains unknown.
LD50 oral (rat): 700 mg/kg
LD50 oral (mouse): 729 mg/kg.

화재위험

Flash point data for CHLOROBENZILATE are not available; however, CHLOROBENZILATE is probably combustible.

Safety Profile

Suspected carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Moderately toxic by ingestion. A skin and eye irritant. A pesticide. When heated to decomposition it emits toxic fumes of Cl-.

잠재적 노출

It is a buffer in many chemical intermediates; an organochlorine miticide; to kill mites, ticks, and other insects; as a synergist for DDT. Incompatibilities: Strong acids, strong bases; lime.

환경귀착

Biological. Rhodotorula gracilis, a yeast isolated from an insecticide-treated soil, degraded chlorobenzilate in a basal medium supplemented by sucrose. Metabolites identified by this decarboxylation process were 4,4′-dichlorobenzilic acid, 4,4′-dichlorobenzophenone and carbon dioxide (Miyazaki et al., 1969, 1970).
Soil. Though no products were identified, the half-life of chlorobenzilate in two fine sandy soils was estimated to be 1.5–5 weeks (Wheeler, 1973).
Photolytic. Chlorobenzilate should not undergo direct photolysis since it does not absorb UV light at wavelengths greater than 290 nm (Gore et al., 1971).

운송 방법

UN2996 Organochlorine pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.UN2761 Organochlorine pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

폐기물 처리

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform to EPA regulations governing storage, transportation, treatment, and waste disposal. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

클로로벤질산 준비 용품 및 원자재

원자재

준비 용품


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