5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one

5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one 구조식 이미지
카스 번호:
1167-58-4
상품명:
5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one
동의어(영문):
Neronine;5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one;[1,3]Dioxolo[6,7][2]benzopyrano[3,4-g]indol-7(1H)-one, 2,3,5,5a,12b,12c-hexahydro-5-hydroxy-12-methoxy-1-methyl-, (5S,5aS,12bS,12cS)-
CBNumber:
CB42308238
분자식:
C18H19NO6
포뮬러 무게:
345.34656
MOL 파일:
1167-58-4.mol

5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one 속성

녹는점
196-7°C
끓는 점
558.7±50.0 °C(Predicted)
밀도
1.49±0.1 g/cm3(Predicted)
산도 계수 (pKa)
12.97±0.20(Predicted)

안전

5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one C화학적 특성, 용도, 생산

개요

This alkaloid possesses a similar structure to that of Nerinine (q.v.) and is found in Nerine krigeii. It may be crystallized from AcOEt and is dextrorotatory with [0:]54 + 161.6° (c 0.57, CHC13). It is hygroscopic and behaves as a monoacidic base yielding a picrate as yellow prisms, m.p. 205-9°C (dec.); a methiodide, m.p. 260-5°C (dec.) and a crystalline O-acetate, m.p. 20t-2°C. It contains a lactone ring which may be opened by alkalies and regenerated by acids.

참고 문헌

Briggs et at., J. Arner. Chern. Soc., 78,2899 (1956)
Jeffs, Hawksworth., Tetrahedron Lett., 217 (1963)

5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one 준비 용품 및 원자재

원자재

준비 용품


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