나트륨 페놀산염

나트륨 페놀산염
나트륨 페놀산염 구조식 이미지
카스 번호:
139-02-6
한글명:
나트륨 페놀산염
동의어(한글):
나트륨페놀산염;나트륨페놀산염;소듐페녹사이드
상품명:
Sodium benzenolate
동의어(영문):
SODIUM PHENOXIDE;SODIUM PHENATE;SODIUM PHENOLATE;Phenolsodium;PHENYL SODIUM;SODIUM PHENYL;Phenoxysodium;phenolatesodium;sodiumcarbolate;Natriumphenolat
CBNumber:
CB7306886
분자식:
C6H5NaO
포뮬러 무게:
116.09
MOL 파일:
139-02-6.mol
MSDS 파일:
SDS

나트륨 페놀산염 속성

녹는점
>300℃
밀도
0,898 g/cm3
RTECS 번호
SM8780000
인화점
28°C
저장 조건
below 5° C
용해도
DMSO(약간 용해됨, 초음파 처리), 메탄올(약간 용해됨)
물리적 상태
고체
물리적 상태
단단한 모양
색상
연한 노란색에서 연한 갈색까지
Specific Gravity
0.898
수용성
물에 매우 잘 녹고, 알코올에 잘 녹습니다. 물, 아세톤, 알코올에 잘 녹습니다.
감도
Hygroscopic
안정성
흡습성
CAS 데이터베이스
139-02-6(CAS DataBase Reference)
EPA
Sodium phenate (139-02-6)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C
위험 카페고리 넘버 34
안전지침서 26-36/37/39-45
유엔번호(UN No.) 3286
TSCA No
위험 등급 8
포장분류 III
HS 번호 2907110000
유해 물질 데이터 139-02-6(Hazardous Substances Data)
기존화학 물질 KE-31576
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
예방조치문구:
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P330+P331 삼켰다면 입을 씻어내시오. 토하게 하려 하지 마시오.
NFPA 704
0
3 0

나트륨 페놀산염 C화학적 특성, 용도, 생산

화학적 성질

Sodium phenate, or sodium phenoxide, NaOC6H5, is a white crystalline substance that easily dissolves in water and alcohol. It decomposes when exposed to carbon dioxide in the air. It is produced by reacting sodium hydroxide solution (not carbonate) with phenol and subsequently evaporating the mixture. Sodium phenate is commonly used in the production of sodium salicylate.

용도

As a general disinfectant, either in solution or mixed with slaked lime, etc., for toilets, stables, cesspools, floors, drains, etc.; for the manufacture of colorless or light-colored artificial resins, many medical and industrial organic Compounds and dyes; as a reagent in chemical analysis. Pharmaceutic aid (preservative).

제조 방법

Sodium phenoxide was freshly prepared by adding sodium metal to phenol (0.45 g, 4.8 mmol) dissolved in diethyl ether (15 cm3), under an atmosphere of dry nitrogen. This was refluxed with (11) (1.0 g, 2.8 mmol) for 23 h. Following evaporation of the ether, water (20 cm3) was added and the mixture extracted into DCM. The DCM solution was dried (MgS04) and evaporated to give a solid (1.2 g). Fractional sublimation and recrystallisation from acetonitrile gave recovery of 2,4,6-tribromo-3,5-difluoropyridine (0.8 g, 80%) and 3-phenoxy-5-fluoro-2,4,6-tribromopyridine (0.2 g, 20%), m.p. 100±1 OC (Found: C, 31.3; H, 1.1; N, 2.9. C11H5Br3FNO requires C, 31.0; H, 1.2; N, 3.3%); IR spectrum no. 15; mass spectrum no. 15; nmr spectrum no. 19.

일반 설명

A white to reddish colored solid in the form of crystalline rods. Used as an antiseptic and in organic synthesis.

공기와 물의 반응

Decomposes in air. Soluble in water. In both cases, a corrosive alkaline solution forms that is a strong irritant to skin and eyes.

반응 프로필

Salts, basic, such as SODIUM PHENOLATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible.

위험도

Strong irritant to skin and tissue.

Safety Profile

Poison by subcutaneous route. A corrosive irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of Na2O. See also PHENOL and SODIUM HYDROXIDE.

Purification Methods

The ground powder is washed with Et2O, then heated at 60o/1mm for 12 to 24hours to remove any free phenol and solvent. [Kornblum & Lurie J Am Chem Soc 81 2710 1959, Beilstein 6 I 718.]

나트륨 페놀산염 준비 용품 및 원자재

원자재

준비 용품


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