사이클로펜타논

사이클로펜타논
사이클로펜타논 구조식 이미지
카스 번호:
120-92-3
한글명:
사이클로펜타논
동의어(한글):
사이클로펜타논;사이클로펜탄온
상품명:
Cyclopentanone
동의어(영문):
Cyclopentanon;ADIPIC KETONE;Cyclopentan-1-one;KETOCYCLOPENTANE;KETOPENTAMETHYLENE;Dumasin;FEMA 3910;opentanone;Adipinketon;Cyclopentsnon
CBNumber:
CB8709022
분자식:
C5H8O
포뮬러 무게:
84.12
MOL 파일:
120-92-3.mol
MSDS 파일:
SDS

사이클로펜타논 속성

녹는점
-51 °C (lit.)
끓는 점
130-131 °C (lit.)
밀도
0.951 g/mL at 25 °C (lit.)
증기 밀도
2.97 (vs air)
증기압
11.5 hPa (20 °C)
FEMA
3910 | CYCLOPENTANONE
굴절률
n20/D 1.437(lit.)
인화점
87 °F
저장 조건
Store below +30°C.
용해도
9.18g/l 약간 용해됨
물리적 상태
액체
색상
무색투명~미황색
냄새
기분 좋은 냄새
폭발한계
1.6-10.8%(V)
?? ??
민트 맛
수용성
실질적으로 불용성
Merck
14,2743
JECFA Number
1101
BRN
605573
Dielectric constant
16.0(-49℃)
안정성
안정적인. 강한 환원제, 강한 산화제, 강한 염기와 호환되지 않습니다.
LogP
0.7 at 25℃
CAS 데이터베이스
120-92-3(CAS DataBase Reference)
NIST
Cyclopentanone(120-92-3)
EPA
Cyclopentanone (120-92-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 10-36/38
안전지침서 23
유엔번호(UN No.) UN 2245 3/PG 3
WGK 독일 1
RTECS 번호 GY4725000
자연 발화 온도 445 °C
TSCA Yes
HS 번호 2914 29 00
위험 등급 3
포장분류 III
유해 물질 데이터 120-92-3(Hazardous Substances Data)
기존화학 물질 KE-09302
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H226 인화성 액체 및 증기 인화성 액체 구분 3 경고
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
3
2 0

사이클로펜타논 C화학적 특성, 용도, 생산

화학적 성질

Cyclopentanone is a colorless liquid with a pleasant, slightly pepperminty odor. It is soluble in water and miscible with common organic solvents. Cyclopentanone has an agreeable, peppermint-like odor. It tends to polymerize in the presence of acids.

출처

Reported found in roasted onion, baked potato, tomato, gruyere cheese, butter, heated chicken, boiled beef, heated pork, roasted pecan, yellow passion fruit juice.

용도

Cyclopentanone is used as an intermediate in the synthesis of rubber adhesives, synthetic resins, pharmaceuticals and biologically active compounds. It acts as precursor for the preparation of cyclopentamine and also pentethylcyclanone, cyclopentobarbital. It is a useful laboratory reagent and is used as thinner for epoxies. It can also be used as a solvent in paint and varnish removers and for electronic applications. As a dry cleaning agent, it is used for oil extraction. It is also involved in the preparation of cyclopentanone derivatives like cyclopenylamine and cyclopentanol which find application in the perfume industry.

제조 방법

Prepared by heating adipic acid (285 to 295°C) in the presence of barium hydroxide, distilling, ether extraction and then fractionation.

정의

ChEBI: A cyclic ketone that consists of cyclopentane bearing a single oxo substituent.

일반 설명

A clear colorless liquid with a petroleum-like odor. Flash point 87°F. Less dense than water and insoluble in water. Vapors heavier than air.

공기와 물의 반응

Highly flammable. Insoluble in water.

반응 프로필

Cyclopentanone polymerizes easily, especially in the presence of acids. Can react with oxidizing materials, i.e. hydrogen peroxide.

건강위험

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Safety Profile

Moderately toxic by intraperitoneal and subcutaneous routes. A skin and severe eye irritant. Dangerous fire hazard when exposed to heat or flame; can react with oxidizers. To fight fire, use alcohol foam, foam, CO2, dry chemical. Potentially explosive reaction with hydrogen peroxide + nitric acid. When heated to decomposition it emits acrid smoke and fumes. See also KETONES.

Purification Methods

Shake it with aqueous KMnO4 to remove materials absorbing around 230 to 240nm. Dry it with Linde-type 13X molecular sieves and fractionally distil it. It has also been purified by conversion to the NaHSO3 adduct which, after crystallising four times from EtOH/water (4:1), is decomposed by adding to an equal weight of Na2CO3 in hot H2O. The free cyclopentanone is steam distilled from the solution. The distillate is saturated with NaCl and extracted with *benzene which is then dried (anhydrous K2CO3) and evaporated. The residue is then distilled [Allen, et al. J Chem Soc 1909 1960]. [Beilstein 7 IV 5.]

사이클로펜타논 준비 용품 및 원자재

원자재

준비 용품


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