황화 바륨

황화 바륨
황화 바륨 구조식 이미지
카스 번호:
21109-95-5
한글명:
황화 바륨
동의어(한글):
황화바륨;황화바륨;바륨설파이드
상품명:
BARIUM SULFIDE
동의어(영문):
BaS;BARIUM SULPHIDE;Black ash;yellowpowder;BARIUM SULFIDE;Einecs 244-214-4;Sulfurated baryta;Barium monosulfide;bariumsulfide(bas);BARIUMPOLYSULPHIDE
CBNumber:
CB9220421
분자식:
BaHS
포뮬러 무게:
170.4
MOL 파일:
21109-95-5.mol

황화 바륨 속성

녹는점
1200°C
밀도
4.25 g/mL at 15 °C(lit.)
물리적 상태
가루
Specific Gravity
4.25
색상
옅은 회색에서 노란색까지
수용성
물에는 용해되지만 알코올에는 용해되지 않습니다.
감도
Moisture Sensitive
Merck
14,995
안정성
안정적이지만 가열하면 분해됩니다. 산, 산화제, 물과 호환되지 않습니다.
CAS 데이터베이스
21109-95-5(CAS DataBase Reference)
NIST
Barium sulfide(21109-95-5)
EPA
Barium sulfide (21109-95-5)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,N,Xi,C
위험 카페고리 넘버 20/22-31-50-36/37/38-41-35
안전지침서 28-61
유엔번호(UN No.) UN 2813 4.3/PG 2
WGK 독일 2
TSCA Yes
위험 등급 4.3
포장분류 III
HS 번호 2830908500
기존화학 물질 KE-02093
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H290 금속을 부식시킬 수 있음 금속 부식성물질 구분 1 경고 GHS hazard pictograms P234, P390, P404
H301 삼키면 유독함 급성 독성 물질 - 경구 구분 3 위험 GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H332 흡입하면 유해함 급성 독성 물질 흡입 구분 4 경고 GHS hazard pictograms P261, P271, P304+P340, P312
H400 수생생물에 매우 유독함 수생 환경유해성 물질 - 급성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

황화 바륨 C화학적 특성, 용도, 생산

화학적 성질

colourless crystals, or white to grey-brown powder,

물리적 성질

Colorless crystalline solid; density 4.25 g/cm3; refractive index 2.155; melts at 1,200°C; soluble in water (decomposes); insoluble in alcohol.

출처

Barium sulfide occurs in the form of black ash, which is a gray to black impure product obtained from high temperature carbonaceous reduction of barite. It is the starting material in the manufacture of most barium compounds including barium chloride and barium carbonate. It is used in luminous paints; for dehairing hides; as a flame retardant; and for generating H2S.

용도

Barium sulfide has different characters, so it is used in a variety of ways, such as in electronics, paint pigments, dehairing hides, flame retardant, luminous paints, and generating pure hydrogen sulfide. Barium sulfide can deviate X-rays and helps to give clearly image of the soft tissue. Barium sulfide is a precursor to other barium compounds and also used as a short wavelength emitters for electronic displays.

제조 방법

Barium sulfide can be prepared by the direct reaction of the elements, calcined in an inert atmosphere, at a 1:1.05 molecular ratio:
Ba+S+heat→BaS
Barium sulfide is prepared commercially by heating barite (BaO) with coal or petroleum coke in a rotary kiln at 1000°C to 1250°C in an oxygen-free atmosphere. The product, black ash, is a gray or black powder containing carbonaceous impurities and unreacted barite. Barium sulfide is separated from impurities by extraction with hot water and filtration. Barium sulfide may also be made by high temperature reduction of barium sulfate with methane.

생산 방법

Barium sulfide is grayish-white solid, formed by heating barium sulfate and carbon, reactive with H2O to form barium hydrosulfide, Ba(SH)2, solution. The latter is also made by saturation of barium hydroxide solution with H2S. Barium polysulfides are formed by boiling barium hydrosulfide with sulfur.

일반 설명

Barium sulfide (BaS) is an inorganic compound that is used as a precursor in the production of barium compounds. These compounds can be used in a variety of applications, such as ceramics, luminous paints, additives, and flame retardants.

위험도

Highly toxic by ingestion (see Barium).

Safety Profile

A poison. Flammable by spontaneous chemical reaction, air, moisture, or acid fumes may cause it to ignite. For explosion and disaster hazards, see SULFIDES. To fight fire, use CO2, dry chemical. Reacts violently with phosphorus(V) oxide. Mxtures with lead dioxide, potassium chlorate, or potassium nitrite explode when heated. Incompatible with Cl2O, Ca(NO3)2, r(NO3)2, Ca(ClO3)2, Sr(ClO3)2, (ClO3)2. See also BARIUM COMPOUNDS (soluble) and SULFIDES.

황화 바륨 준비 용품 및 원자재

원자재

준비 용품


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