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ChemicalBook >> CAS DataBase List >>Phenyl isocyanate

Phenyl isocyanate suppliers

Phenyl isocyanate

CAS:
103-71-9
MF:
C7H5NO
MW:
119.12

Company Type

Properties

Melting point:
?30 °C (lit.)
Boiling point:
162-163 °C (lit.)
Density 
1.096 g/mL at 25 °C (lit.)
vapor pressure 
1.4 mm Hg ( 20 °C)
refractive index 
n20/D 1.535(lit.)
Flash point:
132 °F
storage temp. 
2-8°C
solubility 
Miscible with ether.
form 
Liquid
color 
Clear colorless to slightly yellow
Water Solubility 
decomposes
Sensitive 
Moisture Sensitive
Merck 
14,7296
BRN 
471391
Dielectric constant
8.8(20℃)
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents, water, moisture, alcohols, amines, strong bases, strong acids. Protect from air.
LogP
2.59 at 25℃

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS06,GHS08
Signal word 
Danger
Hazard statements 
H226-H302-H314-H317-H330-H334-H335
Precautionary statements 
P210-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes 
T+,T,C
Risk Statements 
10-22-26-34-42-52-36/37/38
Safety Statements 
16-26-28-36/37/39-45-38-28A
RIDADR 
UN 2487 6.1/PG 1
WGK Germany 
2
RTECS 
DA3675000
21
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
I
HS Code 
29291000

Use

Isocyanates and thioisocyanates, such as Phenyl isocyanate, are incompatible with many classes of compounds, reacting exothermically to release toxic gases. Reactions with amines, aldehydes, alcohols, alkali metals, ketones, mercaptans, strong oxidizers, hydrides, phenols, and peroxides can cause vigorous releases of heat. Acids and bases initiate polymerization reactions in these materials. Some isocyanates react with water to form amines and liberate carbon dioxide. Polyurethanes are formed by the condensation reaction of diisocyanates with, for example, ethyl glycol. Phenyl isocyanate, cobalt pentamine triazo perchlorate, and nitrosyl perchlorate mixture was stirred for 2-3 minutes. When the stirring was interrupted, the mixture exploded [Chem. Eng. News 46(8):39. 1968].

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