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ChemicalBook >> CAS DataBase List >>PICRIC ACID

PICRIC ACID suppliers

PICRIC ACID

CAS:
88-89-1
MF:
C6H3N3O7
MW:
229.1

Company Type

Properties

Melting point:
122-123 °C (dried material, Lit. Merck Index 12th Ed.)(lit.)
Boiling point:
300℃
Density 
1.00 g/mL at 20 °C
vapor density 
7.9 (vs air)
vapor pressure 
1 mm Hg ( 195 °C)
refractive index 
1.7630 (estimate)
Flash point:
150℃
storage temp. 
Store at RT.
solubility 
alcohol: soluble1 (g/12 mL)(lit.)
pka
0.38(at 25℃)
form 
solution (saturated aqueous)
Colour Index 
10305
Specific Gravity
1.005
color 
yellow solution
PH Range
0.2(colourless)-1(yellow)
explosive limit
0.01%
Water Solubility 
(mg/L):
66,670 at 100 °C (quoted, Windholz et al., 1983)
14,000 at 20 °C, 68,000 at 100 °C (quoted, Verschueren, 1983)
λmax
354nm
Merck 
13,7492
BRN 
423400
Exposure limits
TLV-TWA skin 0.1 mg/m3 (ACGIH, OSHA, and MSHA).
Stability:
Stability Unstable; may detonate if struck, heated or ground. Highly flammable if dry. May explode if dry - keep wet at all times. Keep water content above 20%. Flammable. Incompatible with strong oxidizing agents, bases, most common metals, ammonia, strong reducing agents. Avoid shock, friction, heat. Compounds formed by reaction with
Major Application
Explosives, power circuits, energetic materials, liquefied gas fuels, thin films, power generation, batteries, fuel cells, steel, gold films, nanopowder, antifreeze fluid for automobiles, polymerization inhibitors, tattoo removal from skin, antiinfiammatroy agent, treatment of neoplasm
InChIKey
OXNIZHLAWKMVMX-UHFFFAOYSA-N

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictograms
GHS01,GHS06
Signal word 
Danger
Hazard statements 
H201-H301+H311+H331
Precautionary statements 
P210-P230-P250-P280-P301+P310-P370+P372+P380+P373-P503
Hazard Codes 
F,T,E,Xn
Risk Statements 
1-4-11-23/24/25-2-36-20/21/22-3
Safety Statements 
35-45-37-28-36/37-36-26-16-25
RIDADR 
UN 1344 4.1/PG 1
WGK Germany 
2
RTECS 
TJ7875000
HazardClass 
4.1
PackingGroup 
I
Toxicity
LC50 (48-h) for red killifish 513 mg/L (Yoshioka et al., 1986).
IDLA
75 mg/m3

Use

Picric acid is a white to yellowish crystalline substance, soluble in most organic solvents and highly flammable. Picric acid is a derivative of phenol. It reacts with metals to form metal picrates, which like picric acid itself are highly sensitive. It is often used for tissue fixative (Bouin solution) for histology specimens, as a booster to detonate another, less sensitive explosive, such as trinitotoluene (TNT). It is used in the manufacture of fireworks, matches, electric batteries, coloured glass, dyes, antiseptics, explosives, disinfectants, leather industries, pharmaceutical, and textile. Picric acid is also used as a yellow dye, as an antiseptic, and in the synthesis of chloropicrin, or nitro-trichloromethane. Picric acids are highly sensitive to heat, shock, or friction and because of the explosive nature it is among the most hazardous substances found in the laboratory.

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