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ChemicalBook >> CAS DataBase List >> Dichloroacetic acid methyl ester

Dichloroacetic acid methyl ester

Dichloroacetic acid methyl ester price.
  • $5 - $215
  • Product name: Dichloroacetic acid methyl ester
  • CAS: 116-54-1
  • MF: C3H4Cl2O2
  • MW: 142.97
  • EINECS:204-146-8
  • MDL Number:MFCD00000843
  • Synonyms:Methyl dichloroacetate solution;1,1-Dichloro-2-methoxy-2-oxoethane;Dichloroacetic acid methyl;Methyl dichloroacetate, synthesis grade;Methyl dichloroacetate,purum;TwoMethyl chloroacetate;dichloro-aceticacimethylester ;ethanoicacid,dichloro-,methylester
13 prices
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Brand
  • AK Scientific
  • Alfa Aesar
  • Azepine
  • Matrix Scientific
  • Sigma-Aldrich
  • TCI Chemical
  • TRC
Package
  • 100mg
  • 500mg
  • 2.500g
  • 5G
  • 25g
  • 100g
  • 500ml
  • 500g
  • ManufacturerAK Scientific
  • Product numberJ53124
  • Product descriptionMethyl dichloroacetate
  • Packaging100g
  • Price$20
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberB24399
  • Product descriptionMethyl dichloroacetate, 99%
  • Packaging100g
  • Price$33.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberB24399
  • Product descriptionMethyl dichloroacetate, 99%
  • Packaging500g
  • Price$65.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAzepine
  • Product numberAZ0001-0076
  • Product descriptionMethyl dichloroacetate 98
  • Packaging5G
  • Price$5
  • Updated2021-12-16
  • Buy
  • ManufacturerAzepine
  • Product numberAZ0001-0076
  • Product descriptionMethyl dichloroacetate 98
  • Packaging25g
  • Price$15
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number134240
  • Product descriptionMethyl2,2-dichloroacetate 95%+
  • Packaging100mg
  • Price$53
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number134240
  • Product descriptionMethyl2,2-dichloroacetate 95%+
  • Packaging500mg
  • Price$87
  • Updated2021-12-16
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  • ManufacturerMatrix Scientific
  • Product number134240
  • Product descriptionMethyl2,2-dichloroacetate 95%+
  • Packaging2.500g
  • Price$215
  • Updated2021-12-16
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  • ManufacturerSigma-Aldrich
  • Product number36547
  • Product descriptionMethyl dichloroacetate PESTANAL?, analytical standard
  • Packaging100mg
  • Price$30
  • Updated2022-05-15
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number35840
  • Product descriptionMethyl dichloroacetate ≥99%
  • Packaging500ml
  • Price$97.3
  • Updated2024-03-01
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  • ManufacturerTCI Chemical
  • Product numberD0309
  • Product descriptionMethyl Dichloroacetate >99.0%(GC)
  • Packaging25g
  • Price$17
  • Updated2024-03-01
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  • ManufacturerTCI Chemical
  • Product numberD0309
  • Product descriptionMethyl Dichloroacetate >99.0%(GC)
  • Packaging500g
  • Price$57
  • Updated2024-03-01
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  • ManufacturerTRC
  • Product numberD432005
  • Product descriptionDichloroaceticAcidMethylEster
  • Packaging5g
  • Price$85
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific J53124 Methyl dichloroacetate 100g $20 2021-12-16 Buy
Alfa Aesar B24399 Methyl dichloroacetate, 99% 100g $33.65 2024-03-01 Buy
Alfa Aesar B24399 Methyl dichloroacetate, 99% 500g $65.65 2024-03-01 Buy
Azepine AZ0001-0076 Methyl dichloroacetate 98 5G $5 2021-12-16 Buy
Azepine AZ0001-0076 Methyl dichloroacetate 98 25g $15 2021-12-16 Buy
Matrix Scientific 134240 Methyl2,2-dichloroacetate 95%+ 100mg $53 2021-12-16 Buy
Matrix Scientific 134240 Methyl2,2-dichloroacetate 95%+ 500mg $87 2021-12-16 Buy
Matrix Scientific 134240 Methyl2,2-dichloroacetate 95%+ 2.500g $215 2021-12-16 Buy
Sigma-Aldrich 36547 Methyl dichloroacetate PESTANAL?, analytical standard 100mg $30 2022-05-15 Buy
Sigma-Aldrich 35840 Methyl dichloroacetate ≥99% 500ml $97.3 2024-03-01 Buy
TCI Chemical D0309 Methyl Dichloroacetate >99.0%(GC) 25g $17 2024-03-01 Buy
TCI Chemical D0309 Methyl Dichloroacetate >99.0%(GC) 500g $57 2024-03-01 Buy
TRC D432005 DichloroaceticAcidMethylEster 5g $85 2021-12-16 Buy

Properties

Melting point :-52 °C (lit.)
Boiling point :143 °C (lit.)
Density :1.381 g/mL at 25 °C (lit.)
refractive index :n20/D 1.442(lit.)
Flash point :176 °F
storage temp. :room temp
solubility :4g/l
form :Liquid
color :Clear colorless
PH :3.8 (4g/l, H2O, 20℃)
Water Solubility :Slightly soluble
BRN :1747542
CAS DataBase Reference :116-54-1(CAS DataBase Reference)
NIST Chemistry Reference :Acetic acid, dichloro-, methyl ester(116-54-1)
EPA Substance Registry System :Acetic acid, 2,2-dichloro-, methyl ester (116-54-1)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning GHS hazard pictograms P261, P271, P304+P340, P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Methyl dichloroacetate may be used in the diastereoselctive synthesis of bicyclic chlorocyclopropane, as difunctional initiator during atom transfer radical polymerization of methyl or n-butyl acrylate, as reagent during CrCl2-induced olefination of aldehydes. It is a reactant involved in nucleophilic substitution reactions with nitro(pentafluorosulfanyl)benzenes, azide-alkyl halide cycloaddition and atom transfer radical addition, Chemical modification of STn antigen for enhancement of synthetic carbohydrate vaccines, three component reaction of arynes with cyclic ethers and active methines, catalytic radical haloalkylation for synthesis of neodysidenin and addition reactions for syntehsis of enantiopure 3,4-diamino esters or amides.

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