TriMethyl(broModifluoroMethyl)silane

TriMethyl(broModifluoroMethyl)silane Suppliers list

Company Name:	Zibo Hangyu Biotechnology Development Co., Ltd
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Products Intro:	Product Name:TriMethyl(broModifluoroMethyl)silane CAS:115262-01-6 Purity:99.99% Package:1kg;0.1USD\|1kg;0.1USD\|1kg;0.1USD

Company Name:	Capot Chemical Co.,Ltd.
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Products Intro:	Product Name:[Bromo(difluoro)methyl]trimethylsilane CAS:115262-01-6 Purity:98% Min. Package:1G;1KG;100KG

Company Name:	Nanjing ChemLin Chemical Industry Co., Ltd.
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Products Intro:	CAS:115262-01-6 Purity:97% Package:g-Kg Remarks:Colorless transparent liquid

Company Name:	Accela ChemBio Inc.
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Products Intro:	Product Name:(Bromodifluoromethyl)trimethylsilane CAS:115262-01-6 Purity:98% Package:1g;5g;10g;25g;100g Remarks:SY047583

Company Name:	Changzhou Ditong Chemical Co.,Ltd
Tel:	+86-0519-88299272
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Products Intro:	Product Name:TriMethyl(broModifluoroMethyl)silane CAS:115262-01-6 Purity:0.97 Package:1kg;5kg;25kg

TriMethyl(broModifluoroMethyl)silane manufacturers

TriMethyl(broModifluoroMethyl)silane Basic information

Product Name:	TriMethyl(broModifluoroMethyl)silane
Synonyms:	(Bromodifluoromethyl)trimethylsilane 98%;TriMethyl(broModifluoroMethyl)silane;Bromodifluoro(trimethylsilyl)methane;(Bromodifluoromethyl);Trimethyl(bromodifluoromethyl)silane 97%;(Bromodifluoromethyl)trimethylsilane >;Silane, (bromodifluoromethyl)trimethyl-;Difluorobromomethylsilane
CAS:	115262-01-6
MF:	C4H9BrF2Si
MW:	203.1
EINECS:	806-938-4
Product Categories:
Mol File:	115262-01-6.mol

TriMethyl(broModifluoroMethyl)silane Chemical Properties

Boiling point	108°C(lit.)
density	1.306
refractive index	n/D1.407
Fp	46℃
storage temp.	-20°C
form	liquid
color	clear
InChIKey	WDZVWBWAUSUTTO-UHFFFAOYSA-N
CAS DataBase Reference	115262-01-6

Safety Information

MSDS Information

TriMethyl(broModifluoroMethyl)silane Usage And Synthesis

Uses	Novel difluorocarbene source for the efficient difluoromethylenation of alkenes/alkynes and difluoromethylation of O-, S-, and N-nucleophiles.
Uses	Trimethyl(bromodifluoromethyl)silane can be used as neuroactive steroids.
Uses	As reported by Hu and co-workers, (Bromodifluoromethyl)trimethylsilane is a highly useful reagent for the formation of difluoromethene-containing 3-membered rings and can also difluoromethylate heteroatoms with the assistance of alkaline bases, most effectively KOH.
Reactions	(1) Difluoromethylenation of TMSCN. Ref. J. Org. Chem. 2012, 77, 5850?5855. (2) Difluoromethylenation of benzyl and alkylzinc halides. Ref. Org. Lett. 2013, 15, 917 – 919. (3) Fluorination aminocarbonylation of aldehydes Ref. Angew. Chem. Int. Ed. 2022, e202115467
General Description	(Bromodifluoromethyl)trimethylsilane (TMSCF₂Br) is commonly used as a source to generate dilfluorocarbene. TMSCF₃ (Ruppert–Prakash reagent) and BBr₃ undergoes fast halogen–exchange reaction to form MSCF₂Br.
References	[1]Angewandte Chemie International Edition.DOI :10.1002/anie.202283811 [2]The Journal of Organic Chemistry.DOI :10.1021/acs.orglett.2c02899

TriMethyl(broModifluoroMethyl)silane Preparation Products And Raw materials

Raw materials	(chlorodifluoroMethyl)triMethylsilane-->DIBROMODIFLUOROMETHANE-->(Difluoromethyl)trimethylsilane-->Bromotrimethylsilane-->(Trifluoromethyl)trimethylsilane-->Chlorotrimethylsilane
Preparation Products	BROMODIFLUOROMETHANE-->(Difluoromethyl)trimethylsilane-->[(difluoromethyl)thio]benzene-->benzyl 2-(difluoromethoxy)acetate

Tag:TriMethyl(broModifluoroMethyl)silane(115262-01-6) Related Product Information

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