| Company Name: |
J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788 |
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jkinfo@jkchemical.com |
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Product Name:(+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene)1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (R,R)-i-Pr-DUPHOS-Rh
CAS:569650-64-2
Purity:98% Package:100mg;2g;500mg
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| Company Name: |
Meryer (Shanghai) Chemical Technology Co., Ltd.
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021-61259108 18621169109 |
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market03@meryer.com |
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Product Name:1,2-Bis((2R,5R)-2,5-diisopropylphospholano)benzene(cyclooctadiene)rhodiuM(I) tetrafluoroborate
CAS:569650-64-2
Purity:97% Remarks:43520
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| Company Name: |
Alfa Aesar
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400-6106006 |
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saleschina@alfa-asia.com |
| Products Intro: |
Product Name:(-)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, 97%
CAS:569650-64-2
Package:100Mg Remarks:047042
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| | (+)-1,2-BIS((2R,5R)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE)1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Basic information | | Reaction |
| Product Name: | (+)-1,2-BIS((2R,5R)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE)1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE | | Synonyms: | (R,R)-I-PR-DUPHOS-RH;(+)-1,2-BIS((2R,5R)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE)1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE;(+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene)1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.98%(R,R)-i-Pr-DUPHOS-Rh;1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;(+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;1,2-Bis((2R,5R)-2,5-diisopropylphospholano)benzene(cyclooctadiene)rhodium(I) tetrafluoroborate, 97%;(+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene(1,5-cyclooctadiene)
rhodium (I) tetrafluoroborate, min. 98% (R,R)-i-Pr-DUPHOS-Rh;(+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene)1,5-cyclooctadiene)rhodium(I) tetrafluoroborate | | CAS: | 569650-64-2 | | MF: | C34H56BF4P2Rh | | MW: | 716.47 | | EINECS: | | | Product Categories: | metal phosphine complex;Chiral Catalysts, Ligands, and Reagents;DuPhos/BPE;Privileged Ligands and Complexes | | Mol File: | 569650-64-2.mol |  |
| | (+)-1,2-BIS((2R,5R)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE)1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Chemical Properties |
| form | Powder | | color | Yellow to orange to red to brown | | Sensitive | air sensitive | | CAS DataBase Reference | 569650-64-2 |
| WGK Germany | 3 | | HS Code | 29310099 |
| | (+)-1,2-BIS((2R,5R)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE)1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Usage And Synthesis |
| Reaction |
- The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
- Forms superior catalysts for asymmetric reductive aminations.
- Catalyst used for the asymmetric hydrogenation of enol phosphonates.
- A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines.
- Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
- Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
- Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
- Palladium catalyzed asymmetric phosphination.
| | Uses | DuPhos and BPE Ligands: Highly Efficient Privileged Ligands |
| | (+)-1,2-BIS((2R,5R)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE)1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Preparation Products And Raw materials |
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