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PHENYLMAGNESIUM BROMIDE

PHENYLMAGNESIUM BROMIDE Suppliers list
Company Name: Beijing Kaida Technology Development Co., Ltd.  Gold
Tel:+86 (10) 5664-5598 / +86 13811060439
Email:bjkaida@163.com
Products Intro:Product Name:PHENYLMAGNESIUM BROMIDE
CAS:100-58-3
Purity:3M/L Package:800Ml
Company Name: Infinity SCI  Gold
Tel:400-106-2016
Email:sales@infsci.com
Products Intro:Product Name:Phenylmagnesium bromide
CAS:100-58-3
Purity:99% Package:1g;5g;25g
Company Name: Shanghai Heng Yue Chemical Technology Co., Ltd.  Gold
Tel:+86-021-51691771
Email:sales@hyscientific.com
Products Intro:Product Name:Phenylmagnesium bromide solution
CAS:100-58-3
Purity:3.0 M solution in diethyl ether, HySeal Package:100mL;500mL;800mL Remarks:H81313
Company Name: Shanghai Macklin Biochemical Co.,Ltd.  Gold
Tel:15221275939
Email:shenlinxing@macklin.cn
Products Intro:Product Name:Phenylmagnesium Bromide
CAS:100-58-3
Purity:2.8 M solution in 2-methyl-THF, MkSeal Package:800ml
Company Name: Adamas Reagent, Ltd.  Gold
Tel:400-600-9262
Email:bxy@titansci.com
Products Intro:Product Name:Phenylmagnesium Bromide
CAS:100-58-3
Purity:1.0 M solution in THF, SafeSeal Package:800RMB/800ml
PHENYLMAGNESIUM BROMIDE Basic information
Reduction agent for preparation of metal carbonyl compound Related chemical reaction
Product Name:PHENYLMAGNESIUM BROMIDE
Synonyms:bromophenylmagnesium;PHENYLMAGNESIUM BROMIDE, 3.0M SOLUTION I N DIETHYL ETHER;PHENYLMAGNESIUM BROMIDE SOLUTION, ~1 M I N THF;PHENYLMAGNESIUM BROMIDE SOL., ~3 M IN DI ETHYL ETHER;PHENYLMAGNESIUM BROMIDE, 1.0M SOLUTION I N TETRAHYDROFURAN;Phenylmagnesium Bromide 1.0 M In Tetrahydrofuran;Phenylmagnesium Bromide 3.0 M In Diethyl Ether;Phenylmagnesium bromide, 1M solution in THF
CAS:100-58-3
MF:C6H5BrMg
MW:181.31
EINECS:202-867-2
Product Categories:Organometallics;GRIGNARD REAGENTS;Classes of Metal Compounds;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;Aryl;Grignard Reagents;Organometallic Reagents;grignard reagent;Chemical Synthesis;Organometallic Reagents;WB;Imidazoles ,Benzimidazoles
Mol File:100-58-3.mol
PHENYLMAGNESIUM BROMIDE Structure
PHENYLMAGNESIUM BROMIDE Chemical Properties
density 1.134 g/mL at 25 °C
Fp −40 °F
storage temp. water-free area
solubility Miscible with tetrahydrofuran.
form Liquid
color Yellow to brown
Water Solubility reacts
Sensitive Air & Moisture Sensitive
CAS DataBase Reference100-58-3(CAS DataBase Reference)
EPA Substance Registry SystemMagnesium, bromophenyl-(100-58-3)
Safety Information
Hazard Codes F+,C,F
Risk Statements 12-14-22-34-19-11-67-40-37
Safety Statements 16-26-36/37/39-45-33-29-7/8-6A-43B
RIDADR UN 3399 4.3/PG 1
WGK Germany 1
1-3-10
TSCA Yes
HazardClass 4.3
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
PHENYLMAGNESIUM BROMIDE Usage And Synthesis
Reduction agent for preparation of metal carbonyl compoundIn 1890, L.Mond found that when carbon monoxide was burned after being put through the active metal nickel powder, it emitted green light flame. After the resulting gas was cooled, he could obtain colorless liquid (melting point 298K, the boiling point of 316K); if this gas is flowed through a heated glass tube, then it can be seen that the metallic nickel was deposited on the wall. This gas is tetracarbonyl nickel Ni(CO)4. Since the 1960s, people have synthesized a hundreds kinds of such carbonyl compounds and their derivatives. Almost all of the transition metal can form such compounds. This kind of special complex formed through transition metal with carbon monoxide ligands is called metal carbonyls, otherwise known as carbonyl complexes. Metal carbonyl occupies an important position in both theoretical research and practical application in modern inorganic chemistry.
Preparation of metal carbonyl compound can usually via the following methods:
1. Direct synthesis. Most metal carbonyl complexes are prepared by direct combination between metal and carbon monoxide. However, the metal must be new reduction products, and is in a very activated state.
2. Reduction carbonylation effect at high pressure. Apply reducing agent under high pressure to enable the carbonylation reaction between the metal and carbonyl group with the major reducing agents mainly including hydrogen, active metals, phenylmagnesium bromide (C6H5MgBr) and so on.
3. With thermal decomposition or UV irradiation decomposition, we can obtain certain polynuclear carbonyl compounds.
4. Two different kinds of metal carbonyl compounds can interact with each other to give hetero-nuclear carbonyl compound.
Related chemical reaction1. Phenylmagnesium bromide can react with ferric chloride to give the coupling product. Cyclopentadienyl magnesium bromide can react with ferric chloride to give ferrocene.
2. It can react with chromium trichloride in diethyl ether solution to generate dibenzenechromium.
3. Hexaphenyldilead can be used as the antioxidant of polyphenylene ether lubricant that can be produced from the reaction of lead chloride with phenyl lithium or phenyl magnesium bromide.
4. Take tetrahydrofuran as the solvent, have phenylmagnesium bromide reacted with germanium tetrachloride to obtain tetraphenyl germane.
5. It can be obtained through the low-temperature reaction between lead chloride and phenylmagnesium bromide (Or phenyllithium) in the presence of iodobenzene to derive tetraphenyl lead.
6. Sodium tetraphenylborate is mainly used for the determination of potassium ion, ammonium ion, rubidium ion and cesium ion. It can be obtained with the following process: phenylmagnesium bromide is interacted with boron trifluoride/diethyl ether to generate Tetraphenylboron magnesium bromide first. Evaporate the diethyl ether; add water and then used the calculated amount of sodium carbonate for treatment to obtain it.
The above information is edited by the chemicalbook of Dai Xiongfeng.
Chemical PropertiesClear light brown to brown solution when properly
Tag:PHENYLMAGNESIUM BROMIDE(100-58-3) Related Product Information
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