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2,6-Dinitroaniline

2,6-Dinitroaniline Basic information
Product Name:2,6-Dinitroaniline
Synonyms:1-Amino-2,6-dinitrobenzene;2,6-Dinitrobenzenamine;2,6-Dinitroanilin;2,6-DINITROANILINE;2,6-Dinitroaniline,98%;2,6-Dinitroaniline/2,6-DNA;N-Cyanoethyl-Ortho-Chloroaniline;202,6-DINITROANILINE
CAS:606-22-4
MF:C6H5N3O4
MW:183.12
EINECS:210-108-1
Product Categories:Amines;C2 to C6;Nitrogen Compounds;Anilines, Aromatic Amines and Nitro Compounds;Amines and Anilines;Intermediates of Dyes and Pigments
Mol File:606-22-4.mol
2,6-Dinitroaniline Structure
2,6-Dinitroaniline Chemical Properties
Melting point 134 °C (dec.) (lit.)
Boiling point 316.77°C (rough estimate)
density 1.6188 (rough estimate)
refractive index 1.6910 (estimate)
storage temp. Store below +30°C.
form Crystalline Powder or Crystals
pkapK1:-5.23(+1) (25°C)
color White to off-white
Water Solubility practically insoluble
Merck 14,3271
BRN 2214886
InChIKeyQFUSCYRJMXLNRB-UHFFFAOYSA-N
CAS DataBase Reference606-22-4(CAS DataBase Reference)
NIST Chemistry ReferenceBenzenamine, 2,6-dinitro-(606-22-4)
Safety Information
Hazard Codes T,T+
Risk Statements 23/24/25-33-44-26/27/28
Safety Statements 28-37-45-36/37-28A
RIDADR UN 1596 6.1/PG 2
WGK Germany 2
RTECS BX9200000
HazardClass 6.1
PackingGroup II
HS Code 29214210
MSDS Information
ProviderLanguage
2,6-Dinitroaniline English
SigmaAldrich English
ACROS English
ALFA English
2,6-Dinitroaniline Usage And Synthesis
Chemical Propertiesorange-brown crystalline powder
Uses2,6-Dinitroaniline is used for organic synthesis intermediates, dyes intermediates, used in the preparation of 2,6-dinitroiodobenzene. It act as a precursor for various new 1,2,3-trisubstituted halobenzene derivatives.
Production MethodsChlorobenzene-4-sulfonic acid is dinitrated to give 4- chloro-3,5-dinitrobenzenesulfonic acid [88-91-5], which is desulfonated by heating the diluted sulfuric acid solution from the nitration mix to give 2- chloro-1,3- dinitrobenzene [606-21-3]; the latter is aminated to 2,6-Dinitroaniline.
General Description2,6-Dinitroaniline is a dinitroaniline. It serves as precursor to various new 1,2,3-trisubstituted halobenzene derivatives.
Purification MethodsPurify the nitroaniline by chromatography on alumina, then crystallise it from *benzene or EtOH. The N-acetyl derivative has m 197o (from EtOH). [Beilstein 12 IV 1729.]
2,6-Dinitroaniline Preparation Products And Raw materials
Raw materialsFUMING SULFURIC ACID-->Potassium nitrate-->potassium 4-chloro-3,5-dinitrobenzenesulphonate
Preparation Products2-Chloro-1,3-dinitrobenzene-->2-Bromo-3-nitroaniline
Tag:2,6-Dinitroaniline(606-22-4) Related Product Information
4'-Nitroacetanilide N-Methyl-4-nitroaniline N,N-Dimethylaniline Diphenylamine 2,4,6-TRINITROANILINE N-(4-DIMETHYLAMINO-3,5-DINITROPHENYL)MALEIMIDE ISOPROPALIN n,n-dipropyl-4-trifluoromethyl-2,6-dinitroaniline[qr HexanitrodiphenylaMine 1,1-DIPHENYL-2-PICRYLHYDRAZINE 4-AMINO-3,5-DINITROBENZOIC ACID 2,4-DINITROANILINE OEKANAL, 250 MG 2,2-diphenyl-1-picrylhydrazyl 4-AMINO-3,5-DINITROBENZOTRIFLUORIDE N-(1-Ethylpropyl)-3,4-dimethyl-2,6-dinitroaniline,n-(ethylpropyl)-3,4-dimethyl-2,6-dinitroaniline,n-(3-pentyl)-3,4-dimethyl-2,6-dinitroanilin 4-DIMETHYLAMINO-3,5-DINITROBENZOIC ACID 4-Nitroaniline 1,3-Dinitrobenzene