COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX manufacturers
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| COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX Basic information |
| COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX Chemical Properties |
Melting point | 160 °C (dec.) (lit.) | Fp | 45 °F | storage temp. | Inert atmosphere,2-8°C | form | Powder | color | Gray-greenish | InChIKey | OGHGYDFTMBZZJU-UHFFFAOYSA-M | CAS DataBase Reference | 42152-46-5 |
Hazard Codes | F | Risk Statements | 11-36/37/38 | Safety Statements | 16-26-36 | RIDADR | UN 3175 4.1/PG 2 | WGK Germany | 3 | HazardClass | 4.1 | PackingGroup | II | HS Code | 29049090 |
| COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX Usage And Synthesis |
Chemical Properties | Grey-greenish powder | Uses | Copper(I) trifluoromethanesulfonate benzene complex can be used as a catalyst:
- To synthesize enol-esters via copper(I) carboxylate intermediate formation.
- In the enantioselective allylic oxidation of cyclic alkenes.
- To prepare 2,5-disubstituted pyrrolidine derivatives from N-alkenyl, alkynyl and alkyl N-benzoyloxysulfonamides via the sulfonamidyl radical formation.
It can also be used in combination with amino acid-based chiral phosphine ligands to catalyze asymmetric conjugate additions of alkylzincs to acyclic α,β-unsaturated ketones, affording β-alkylcarbonyls in high yield and with excellent enantioselectivity. |
| COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX Preparation Products And Raw materials |
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