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BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE

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Products Intro: Product Name:BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE
CAS:37891-79-5
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CAS:37891-79-5
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CAS:37891-79-5
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Products Intro: Product Name:Bis(Methylthio)(Trimethylsilyl)Methane
CAS:37891-79-5
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Products Intro: Product Name:Bis(Methylthio)(Trimethylsilyl)Methane
CAS:37891-79-5
Purity:99 Package:5KG;1KG,25kg
BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Basic information
Product Name:BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE
Synonyms:TRIMETHYLBIS(METHYLTHIO)METHYLSILANE;Bis(methylthio)methyltrimethylsilane Trimethylbis(methylthio)methylsilane;BIS(METHYLTHIO)METHYLTRIMETHYLSILANE;BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE;Silane, [bis(methylthio)methyl]trimethyl-;Bis(methylthio)(trimethylsilyl)methane >
CAS:37891-79-5
MF:C6H16S2Si
MW:180.41
EINECS:
Product Categories:Si (Classes of Silicon Compounds);Si-(C)4 Compounds;Silicon Compounds (for Synthesis);Sulfur Compounds (for Synthesis);Synthetic Organic Chemistry
Mol File:37891-79-5.mol
BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Structure
BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Chemical Properties
Boiling point 82 °C(Press: 10.0 Torr)
density 0.941±0.06 g/cm3(Predicted)
refractive index 1.5060-1.5100
solubility insol H2O; sol organic solvents.
form clear liquid
color Colorless to Light yellow to Light orange
Safety Information
HS Code 2931.90.9010
MSDS Information
BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Usage And Synthesis
Physical propertiesbp 67–70°C/10 mmHg.
UsesBis(methylthio)(trimethylsilyl)methane is a reagent used for synthesis of bis(methylthio)ketene acetals from aldehydes and ketones;acyl anion synthon for conjugate additions to enones and enoates;useful for one-carbon homologations.
The bis(methylthio)ketene acetals are useful synthetic intermediates because they are readily converted into S-methyl thioesters (eq 9) or the corresponding carboxylic acids and esters.Uses of Bis(methylthio)(trimethylsilyl)methane
Preparationprepared from lithiobis(methylthio)- methane by silylation with chlorotrimethylsilane (eq 1).Both bis(methylthio)methane and chlorotrimethylsilane are commercially available.

37891-79-5 synthesis

BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Preparation Products And Raw materials
Tag:BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE(37891-79-5) Related Product Information
BIS(TRIMETHYLSILYL) SULFIDE 2-(TRIISOPROPYLSILYL)-1 3-DITHIANE 97 BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE 2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE 2-TRIMETHYLSILYL-1,3-DITHIANE DIMETHYL-[3-(2-TRIMETHYLSILANYL-[1,3]DITHIAN-2-YL)-PROPYL]-AMINE