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2-(Trimethylsilylmethyl)allyl acetate

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Products Intro: Product Name:2-(trimethylsilylmethyl)allyl acetate
CAS:72047-94-0
Purity:99% Package:5KG;1KG
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Products Intro: Product Name:2-(Trimethylsilylmethyl)allyl acetate
CAS:72047-94-0
Purity:98% HPLC Package:5G;10G;25G;50G;100G;250G;1KG
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Products Intro: Product Name:2-(Trimethylsilylmethyl)allyl acetate
CAS:72047-94-0
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Products Intro: Product Name:2-(trimethylsilylmethyl)allyl acetate
CAS:72047-94-0
Purity:99% Package:1kg
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Products Intro: Product Name:2-(Trimethylsilylmethyl)allyl acetate
CAS:72047-94-0
Purity:>=99% Package:1.8KG;9.8USD

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2-(Trimethylsilylmethyl)allyl acetate Basic information
Product Name:2-(Trimethylsilylmethyl)allyl acetate
Synonyms:2-(Acetoxymethyl)allyltrimethyliane;2-(Acetoxymethyl)allyltrimethyliane;2-Acetoxymethyl-3-(trimethylsilyl)propene;2-(Trimethylsilylmethyl)allyl acetate;2-(Trimethylsilylmethyl)-2-propen-1-yl acetate;2-(ACETOXYMETHYL)-3-(TRIMETHYLSILYL)PROPENE;[2-(ACETOXYMETHYL)ALLYL]TRIMETHYLSILANE;2-(ACETOXYMETHYL)ALLYTRIMETHYLSILANE;2-[(TRIMETHYLSILYL)METHYL]-2-PROPEN-1-VL ACETATE;2-(TRIMETHYLSILYLMETHYL)ALLYL ACETATE;3-ACETOXY-2-(TRIMETHYLSILYLMETHYL)-1-PROPENE
CAS:72047-94-0
MF:C9H18O2Si
MW:186.32
EINECS:
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Mol File:72047-94-0.mol
2-(Trimethylsilylmethyl)allyl acetate Structure
2-(Trimethylsilylmethyl)allyl acetate Chemical Properties
Boiling point 95 °C7 mm Hg(lit.)
density 0.877 g/mL at 25 °C(lit.)
refractive index n20/D 1.440(lit.)
Fp 160 °F
storage temp. Inert atmosphere,2-8°C
solubility Solubility most organic solvents.
form Liquid
color Clear colorless
Water Solubility reacts
BRN 1933657
InChIKeyIKQWABMHZKGCLX-UHFFFAOYSA-N
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-14
Safety Statements 26-36/37/39-37/39
WGK Germany 3
HS Code 29319090
MSDS Information
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ACROS English
SigmaAldrich English
2-(Trimethylsilylmethyl)allyl acetate Usage And Synthesis
Chemical PropertiesClear colorless liquid
Physical propertiesbp 68–70°C/6.5 mmHg;60–61°C/2.5 mmHg.
Usesprecursor for palladium trimethylenemethane cycloaddition reactions.
Uses2-[(Acetoxymethyl)allyl]trimethylsilane was used in the cyclopentane synthesis via Pd(0)-catalyzed reactions with 2π acceptors.
Preparationcommercially available but expensive. Several preparations of (1) or the precursor alcohol (2) have been reported. The simplest involves the direct silylation of methallyl alcohol (eq 1).
72047-94-0 synthesis
2-(Trimethylsilylmethyl)allyl acetate Preparation Products And Raw materials
Preparation Products4-METHYL-2(5H)-FURANONE
Tag:2-(Trimethylsilylmethyl)allyl acetate(72047-94-0) Related Product Information
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