|
| (+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANE Basic information |
Product Name: | (+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANE | Synonyms: | (2R,3R)-1,1,4,4-TETRAPHENYL-2,3-O-(1-PHENYLETHYLIDENE)-1,2,3,4-BUTANETETROL;(2R,3R)-2,3-O-(1-PHENYLETHYLIDENE)-1,1,4,4-TETRAPHENYL-1,2,3,4-BUTANETETROL;(+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANE;(+)-(4R,5R)-BIS[HYDROXY(DIPHENYL)METHYL]-2-PHENYL-1,3-DIOXOLANE;(+)-4,5-Bis[hydroxy(diphenyl)methyl-2-phenyl-1,3-dioxolane;Bishydroxydiphenylmethylphenyldioxolane;(2R,3R)-2,3-O-(1-Phenylethylidene)-1,1,4,4-tetraphenyl-1,2,3,4-butanetetrol
(2R,3R)-1,1,4,4-Tetraphenyl-2,3-O-(1-phenylethylidene)-1,2,3,4-butanetetrol
[(4R,5R)-2-Methyl-2-phenyl-1,3-dioxolane-4,5-diyl]bis(diphenylmethanol);[(4R,5R)-2-Methyl-2-phenyl-1,3-dioxolane-4,5-diyl]bis(diphenylMethanol) | CAS: | 109306-21-0 | MF: | C36H32O4 | MW: | 528.64 | EINECS: | | Product Categories: | Asymmetric Synthesis;Dioxanes & Dioxolanes;Dioxolanes;Synthetic Organic Chemistry | Mol File: | 109306-21-0.mol | |
| (+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANE Chemical Properties |
Melting point | 120 °C | Boiling point | 701.9±55.0 °C(Predicted) | density | 1?+-.0.06 g/cm3(Predicted) | pka | 12.28±0.29(Predicted) | form | powder to crystal | color | White to Orange to Green |
| (+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANE Usage And Synthesis |
Uses | (+)-4,5-Bis[hydroxy(diphenyl)methyl]-2-methyl-2-phenyl-1,3-dioxolane (CAS# 109306-21-0) is a TADDOL (α,α,α'',α''-tetraaryl-2,2-disubstituted 1,3-dioxolane-4,5-dimethanol) and is a chiral building block used in the perparation of optically active organotin derivatives. Via Ni catalyzation, (+)-4,5-Bis[hydroxy(diphenyl)methyl]-2-methyl-2-phenyl-1,3-dioxolane has been used in the cycloisomerization of dienes. |
| (+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANE Preparation Products And Raw materials |
|