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| | TRIBUTYL(1-ETHOXYVINYL)TIN Basic information | | Reaction |
| | TRIBUTYL(1-ETHOXYVINYL)TIN Chemical Properties |
| Melting point | <0°C | | Boiling point | 85-86 °C0.1 mm Hg(lit.) | | density | 1.069 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.476(lit.) | | Fp | >230 °F | | storage temp. | 2-8°C | | solubility | Choroform (Slightly), Ethyl Acetate (Slightly) | | form | liquid | | color | colorless | | Specific Gravity | 1.069 | | Sensitive | Moisture Sensitive | | InChIKey | HGXJOXHYPGNVNK-UHFFFAOYSA-N |
| | TRIBUTYL(1-ETHOXYVINYL)TIN Usage And Synthesis |
| Reaction | Versatile tin reagent used for the introduction of a 1-ethoxyvinyl group via a Stille cross-coupling reaction, (palladium-catalyzed coupling of an organohalide (or pseudohalide) with an organotin compound).
| | Chemical Properties | Clear colorless liquid | | Uses | Electrophilic methyl ketone equivalent used in a recent synthesis of a 13-oxophorbine (chlorophyll) from the corresponding 13-bromochlorin. | | General Description | This vinylstannane undergoes Stille coupling with a vinyl triflate, giving, after hydrolysis, an α,β?unsaturated ketone, thus acting as an acetyl anion equivalent. |
| | TRIBUTYL(1-ETHOXYVINYL)TIN Preparation Products And Raw materials |
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