|
|
| | 2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM BIS(HEXAFLUORO-T-BUTOXIDE) Basic information | | Reaction |
| Product Name: | 2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM BIS(HEXAFLUORO-T-BUTOXIDE) | | Synonyms: | 2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM BIS(HEXAFLUORO-T-BUTOXIDE);2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM(VI)BIS(HEXAFLUORO-T-BUTOXIDE);2,6-DIISOPROPYLPHENYLIMIDONEOPHYLIDENEB&;2,6-Diisopropylphenylimidoneophylidenemolybdenum(VI)bis(hexafluorotert-butoxide);2,6-Diisopropylphenylimidoneophylidenemolybdenum(VI)bis(hexafluoro-t-butoxide)SCHROCK'SCATALYST;1,1,1,3,3,3-Hexafluoro-2-methyl-2-propanol - [(2,6-diisopropylphenyl)imino](2-methyl-2-phenylpropylidene)molybdenum (2:1);2,6-diisopropylphenylimido neophylidenemolybdenum(Ⅵ)bis(hexafluoro-t-butoxide);[2,6-Bis(1-methylethyl)benzenaminato(2-)]bis(1,1,1,3,3,3-hexafluoro-2-methyl-2-propanolato-κO)(2-methyl-2-phenylpropylidene)-, (T-4) molybdenum, paraffin pellet | | CAS: | 139220-25-0 | | MF: | C30H35F12MoNO2 | | MW: | 765.53 | | EINECS: | | | Product Categories: | Other Metal | | Mol File: | 139220-25-0.mol |  |
| | 2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM BIS(HEXAFLUORO-T-BUTOXIDE) Chemical Properties |
| form | Powder | | color | yellow to orange | | Sensitive | air sensitive, moisture sensitive, store cold |
| | 2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM BIS(HEXAFLUORO-T-BUTOXIDE) Usage And Synthesis |
| Reaction |
- Unlike Mo(C10H12)(C12H17N)(OC4H9)2, the bis(hexafluoro-t-butoxide) (MoF6) derivative will metathesize many ordinary olefins, especially terminal olefins, and will ROMP many norbornene or substituted norbornadiene monomers to give all cis, and often isotactic, polymers.
- Useful for the "ring-closing" of dienes or the coupling of terminal olefins.
- Useful for cross-metathesis of alphatic alkenes with 2-vinyl aromatics.
|
| | 2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM BIS(HEXAFLUORO-T-BUTOXIDE) Preparation Products And Raw materials |
|