|
|
| | (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Basic information | | Reaction |
| Product Name: | (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE | | Synonyms: | (-)-2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine, min. 97% Indenyl-PYBOX;2,6-Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine;(3aS,3'aS,8aR,8'aR)-2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole;(-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine,97%;aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine;(3aS,3'aS,8aR,8'aR)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole],99%e.e.;(-)-2,6-BIS[2-{3AS-(2(3'AR*,8'AS*),3AΑ,8AΑ)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE}]PYRIDINE;2,6-Bis[(3aS,8aR)-(-)-8H-indeno[1,2-d]oxazolin-2-yl)]pyridine | | CAS: | 185346-09-2 | | MF: | C25H19N3O2 | | MW: | 393.44 | | EINECS: | | | Product Categories: | BOX series;Chiral Nitrogen;organic amine | | Mol File: | 185346-09-2.mol | ![(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Structure](CAS/GIF/185346-09-2.gif) |
| | (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Chemical Properties |
| Melting point | 265°C (dec.) | | Boiling point | 633.0±55.0 °C(Predicted) | | alpha | -364.0° (c 1.04, CH2Cl2) | | density | 1.50±0.1 g/cm3(Predicted) | | storage temp. | Sealed in dry,Room Temperature | | pka | 4.35±0.20(Predicted) | | form | Powder | | color | white to off-white | | optical activity | [α]20/D -375°, c = 1 in dichloromethane (typical) |
| | (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Usage And Synthesis |
| Reaction |
- Ligand for Iridium-catalyzed enantio- and diastereoselective reductive aldol reactions
- Ligand for Scandium-catalyzed asymmetric Nazarov reactions
- Ligand for Scandium-catalyzed enantioselective pyrrole alkylations of α,β-unsaturated 2-acyl imidazoles
- Ligand for Scandium-catalyzed enantioselective Friedel-Crafts Alkylations
- Ligand for Nickel-catalyzed asymmetric cross-couplings of racemic propargyl groups with arylzinc reagents
- Ligand for Scandium-catalyzed enantioselective intramolecular carbonyl-ene reaction, the synthesis of (+)-triptophenolide
- Ligand for Scandium-catalyzed asymmetric synthesis of substituted 3-hydroxy-2-oxindoles
- Ligand for Indium-catalyzed enantio- and regioselective addition of pyrroles to isatins
- Ligand for Scandium-catalyzed asymmetric [3+2] annulation of allylsilanes with isatins in the synthesis of spirooxindoles
- Ligand for Scandium-catalyzed enantioselective allylation of isatins using allylsilanes
- Ligand for Scandium-catalyzed enantioselective carboannulation with allylsilanes
| | Chemical Properties | White powder | | Uses | Reactant involved in synthesis of:
- Chiral ruthenium(II)-pybox complexes for use as intramolecular C-H amination catalysts
- Bis(oxazolinyl_pyridine-scandium(III) triflate complex catalyst for enantioselective addition of pyrroles to indoles
- Chiral N,N,N-tridentate pybos and pyboxazine ligands
|
| | (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Preparation Products And Raw materials |
|