CHLOROMETHYL METHYL SULFIDE

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Products Intro: Product Name:Chloromethyl Methyl Sulfide
CAS:2373-51-5
Purity:99% Package:1KG;5USD|10KG;3USD|50KG;2USD
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Products Intro: Product Name:Chloromethyl methyl sulfide
CAS:2373-51-5
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Products Intro: CAS:2373-51-5
Purity:95% Package:g-Kg Remarks:Light yellow to brown liquid
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CAS:2373-51-5
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Products Intro: Product Name:CHLOROMETHYL METHYL SULFIDE
CAS:2373-51-5
Purity:0.98 Package:1KG;10KG;50KG

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CHLOROMETHYL METHYL SULFIDE Basic information
Product Name:CHLOROMETHYL METHYL SULFIDE
Synonyms:alpha-Chlorodimethyl sulfide;alpha-chlorodimethylsulfide;chloro(methylthio)-methan;chloro(methylthio)methane;Chlorodimethyl thioether;chlorodimethylthioether;Chloromethyl methyl thioether;chloromethylmethylthioether
CAS:2373-51-5
MF:C2H5ClS
MW:96.58
EINECS:219-148-4
Product Categories:
Mol File:2373-51-5.mol
CHLOROMETHYL METHYL SULFIDE Structure
CHLOROMETHYL METHYL SULFIDE Chemical Properties
Boiling point 105 °C (lit.)
density 1.153 g/mL at 25 °C (lit.)
refractive index n20/D 1.498(lit.)
Fp 63 °F
storage temp. 2-8°C
form clear liquid
color Colorless to Light orange to Yellow
Water Solubility Soluble in acetonitrile, ether and dichloromethane. Insoluble in water.
Sensitive Moisture Sensitive
BRN 1730851
CAS DataBase Reference2373-51-5(CAS DataBase Reference)
Safety Information
Hazard Codes F,Xi
Risk Statements 11-37
Safety Statements 9-16-33
RIDADR UN 1993 3/PG 2
WGK Germany 3
RTECS WQ3700000
13
HazardClass 3
PackingGroup II
HS Code 2930909899
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
CHLOROMETHYL METHYL SULFIDE Usage And Synthesis
Chemical PropertiesCLEAR YELLOW TO BROWN LIQUID
UsesMethylthiomethylating reagent for carbonyl and aromatic compounds. Methylene transfer reagent for iron(II) mediated cyclopropanation.
UsesChloromethyl methyl sulfide is used as a methylene transfer reagent for iron(II) mediated cyclopropanation and for carbonyl and aromatic compounds. It protects alcohols as their methylthiomethyl (MTM) ethers by reaction, e.g. with NaH/NaI in DME. It is also used for the preparation of MTM esters of carboxylic acids, e.g. by treatment of the K salt of the acid in the presence of NaI and 18-crown-6 and for reaction with cyclopentadienyl iron dicarbonyl dimer in the formation of an iron-containing methylene transfer agent.
Synthesis Reference(s)Tetrahedron Letters, 35, p. 6127, 1994 DOI: 10.1016/0040-4039(94)88094-8
Tag:CHLOROMETHYL METHYL SULFIDE(2373-51-5) Related Product Information
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