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4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL

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Products Intro: Product Name:4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL
CAS:1016-58-6
Purity:99% Package:25KG
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Products Intro: Product Name:(4,5-Dimethoxy-2-nitrophenyl)methanol
CAS:1016-58-6
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Products Intro: Product Name:4,5-Dimethoxy-2-nitrobenzyl alcohol
CAS:1016-58-6
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Products Intro: Product Name:4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL
CAS:1016-58-6
Purity:99% Package:1KG;1USD

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4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL Basic information
Product Name:4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL
Synonyms:RARECHEM AL BD 0187;TIMTEC-BB SBB009964;LABOTEST-BB LT00847721;6-NITROVERATRYL ALCOHOL;4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL;4,5-Dimethoxy-2-nitrobenzyl alcohol 98%;6-NITROVERATRYL ALCOHOL 98+%;2-Nitro-4,5-dimethoxybenzenemethanol
CAS:1016-58-6
MF:C9H11NO5
MW:213.19
EINECS:213-806-4
Product Categories:Benzhydrols, Benzyl & Special Alcohols;Alcohols;Building Blocks;C9 to C10;Chemical Synthesis;Organic Building Blocks;Oxygen Compounds
Mol File:1016-58-6.mol
4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL Structure
4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL Chemical Properties
Melting point 145-148 °C (lit.)
Boiling point 383.9±37.0 °C(Predicted)
density 1.307±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form powder to crystal
pka13.59±0.10(Predicted)
color White to Yellow to Green
Water Solubility Soluble in water.
λmax400nm(CH3CN)(lit.)
Sensitive Light Sensitive
BRN 1880093
CAS DataBase Reference1016-58-6(CAS DataBase Reference)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
F 8
HazardClass IRRITANT
HS Code 29094990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Uses4,5-Dimethoxy-2-nitrobenzyl alcohol (6-nitroveratryl alcohol) is suitable reagent used in the synthesis of 4,5-dimethoxy-2-nitrobenzyl methacrylate, a photolabile monomer and 2-(4-((4-(4,5-dimethoxy-2-nitrobenzyloxy)phenyl)cyclohexylidene)methyl)phenoxy)-N,N-dimethylethanamine, a caged cyclofen-OH ligand.

It may be used in the synthesis of the following:
  • 1-[[(chlorocarbonyl)oxy]methyl]-4,5-dimethoxy-2-nitrobenzene
  • bis(4,5-dimethoxy-2-nitrophenyl)ethylene glycol, a photolabile protecting group
  • optically-sensitive monomer
  • nitroveratryl (NV) protected α-hydroxyacetic acid (αG) (NV-αG-OH), required in the preparation of nitroveratryl (NV) protected cyanomethyl (CM) ester of α-hydroxyacetic acid (αG) (NV-αG-CM)
  • 4,5-dimethoxy-2-nitrobenzyl p-nitro-phenylcarbonate
  • 6-nitroveratryloxycarbonyl chloride (NVOCCl), a reagent used in the protection of amino function in amino sugars
Uses4,5-Dimethoxy-2-nitrobenzyl alcohol, is used as Reagent for the protection of alcohols, etc., as ethers which can be cleaved by photolysis involving intramolecular rearrangement to derivatives of o-nitrosobenzaldehyde, which are readily cleaved by hydrolysis. It is also used as photochemical protecting groups in organic synthesis. It is also used as a pharmaceutical intermediate.
General Description4,5-Dimethoxy-2-nitrobenzyl alcohol (6-Nitroveratryl Alcohol) is 2-nitrobenzyl alcohol derivative. It has been reported to be one of the oxidation products of veratryl (3,4-dimethoxybenzyl) alcohol by lignin peroxidase (isolated from Phanerochaete chrysosporium).
4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL Preparation Products And Raw materials
Preparation Products6-Nitroveratraldehyde-->2-Amino-4,5-dimethoxybenzoic acid-->6-NITROVERATRYL CHLOROFORMATE-->T6P unnatural precursors (1-4)
Tag:4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL(1016-58-6) Related Product Information
Methyl 2-nitro-3,4,5-trimethoxybenzoate 4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL 6-NITROVERATRYL CHLOROFORMATE 4-[4-(1-Hydroxyethyl)-2-Methoxy-5-nitrophenoxy]butanoic Acid ETHYL 4,5-DIMETHOXY-2-NITROBENZOATE Methyl 4,5-dimethoxy-2-nitrobenzoate D-ribo-Hexanoic acid, 3-deoxy-, γ-lactone 2-Nitrobenzyl alcohol GLUTAMATE, CAGED 4,5-DIMETHOXY-2-NITROBENZYL ADENOSINE 3',5'-CYCLICMONOPHOSPHATE 4-(4-HYDROXYMETHYL-2-METHOXY-5-NITROPHENOXY)BUTYRIC ACID (4,5-DIMETHOXY-2-NITRO-PHENYL)-PHENYL-METHANOL 3,4,5-TRIMETHOXY-2-NITROBENZOIC ACID D-LUCIFERIN 1-(4,5-DIMETHOXY-2-NITROPHENYL)ETHYL ESTER ARACHIDONIC ACID 1-(4,5-DIMETHOXY-2-NITROPHENYL)ETHYL ESTER ADENOSINE 5'-TRIPHOSPHATE, P3-(1-(4,5-DIMETHOXY-2-NITROPHENYL)ETHYL) ESTER, DISODIUM SALT A-23187, 1-(4,5-DIMETHOXY-2-NITROPHENYL)ETHYL ESTER 4-BROMO A-23187, 1-(4,5-DIMETHOXY-2-NITROPHENYL)ETHYL ESTER