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1S-(+)-Camphor-10-sulfonic acid(3144-16-9)

1S-(+)-Camphor-10-sulfonic acid(3144-16-9)
Product IdentificationBack to Contents
【Product Name】

1S-(+)-Camphor-10-sulfonic acid
【Synonyms】

D-Camphor-b-sulfonic acid
(+)-2-Oxo-10-bornanesulfonic acid
(+)-Camphor-10-sulfonic acid
(S)-(+)-Camphor-10-sulfonic acid
Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S,4R)-
Reychler's acid
【CAS】

3144-16-9
【Formula】

C10H16O4S
【Molecular Weight】

232.3
【EINECS】

221-554-1
【RTECS】

ED1550000
【RTECS Class】

Other
【Merck】

13,1741
【Beilstein/Gmelin】

2809675
【Beilstein Reference】

4-13-00-00356
【EC Class】

corrosive
Physical and Chemical PropertiesBack to Contents
【Appearance】

White powder.
【Solubility in water】

Very soluble
【Melting Point】

195
【Boiling Point】

375
【Partition Coefficient】

1.31
【Usage】

Resolution of optically active isomers.
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Store in a tightly closed container. Corrosives area. Store protected from moisture.
【Handling】

Wash thoroughly after handling. Wash hands before eating. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use with adequate ventilation. Do not allow contact with water. Discard contaminated shoes. Keep from contact with moist air and steam.
Hazards IdentificationBack to Contents
【Ingestion】

May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause nausea and vomiting.
【Inhalation】

May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
【Skin】

Causes skin burns.
【Eyes】

Contact with eyes may cause severe irritation, and possible eye burns.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】

R 34
【EC Safety Phrase】

S 26 36/37/39 45
【UN (DOT)】

1759
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Fire Fighting MeasuresBack to Contents
【Autoignition】

193
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam. Do NOT get water inside containers.
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.
Stability and ReactivityBack to Contents
【Disposal Code】

4
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong acids, strong bases, strong oxidizing agents, strong reducing agents.
【Decomposition】

Carbon monoxide, oxides of sulfur, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1759
【Hazard Class】

8
【Packing Group】

I; II; III
【HS Code】

2914 70 90
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