| Product Identification | Back to Contents | 【Product Name】
Allyl acetate | 【Synonyms】
2-Propenyl ethanoate
3-Acetoxypropene | 【CAS】
591-87-7 | 【Formula】
C5H8O2 | 【Molecular Weight】
100.12 | 【EINECS】
209-734-8 | 【RTECS】
AF1750000 | 【RTECS Class】
Tumorigen; Primary Irritant | 【Merck】
12,293 | 【Beilstein/Gmelin】
1742050 | 【Beilstein Reference】
4-02-00-00180 | 【EC Class】
highly flammable, toxic, irritant |
| Physical and Chemical Properties | Back to Contents | 【Appearance】
Colorless liquid, acrid odor. | 【Solubility in water】
Soluble | 【Melting Point】
-96 | 【Boiling Point】
103 | 【Vapor Pressure】
31 (25 C) | 【Density】
0.9376 g/cm3 (0 C) | 【Partition Coefficient】
.97 | 【Heat Of Vaporization】
34.3 kJ/mol | 【Heat Of Combustion】
-2749 kJ/mol | 【Usage】
Synthetic flavor useful in cheese, butter, fruit. | 【Vapor Density】
3.45 | 【Saturation Concentration】
67,000 ppm at 37 C (calculated) (3) | 【Refractive Index】
1.40205 (20 C) |
| First Aid Measures | Back to Contents | 【Ingestion】
Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. May cause irritation of the digestive tract and possible burns. | 【Inhalation】
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. | 【Skin】
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. | 【Eyes】
Get medical aid immediately. Extensive irrigation is required (at least 30 minutes). |
| Handling and Storage | Back to Contents | 【Storage】
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator/flammables. | 【Handling】
Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. |
| Hazards Identification | Back to Contents | 【Inhalation】
May be harmful if inhaled. Vapors may cause dizziness or suffocation. Causes respiratory tract irritation with possible burns. | 【Skin】
May be harmful if absorbed through the skin. May cause blistering of the skin. Causes skin irritation and possible burns. | 【Eyes】
May cause transient corneal injury. Lachrymator. Causes eye irritation and possible burns. | 【Ingestion】
Harmful if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. | 【Hazards】
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion and poison hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. | 【EC Risk Phrase】
R 11 21 23/25 36/37/38 | 【EC Safety Phrase】
S 16 23.2 36/37 45 | 【UN (DOT)】
2333 |
| Exposure Controls/Personal Protection | Back to Contents | 【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | 【Respirators】
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | 【Exposure Effects】
Agitation and syncope, both attributed to panic, have been reported. | 【Exposure limit(s)】
OEL-RUSSIA:STEL 2 mg/m3;Skin | 【Poison Class】
2 |
| Fire Fighting Measures | Back to Contents | 【Flash Point】
6 | 【Autoignition】
374 | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. | 【Upper exp. limit】
13.0 | 【Lower exp. limit】
2.1 | 【Fire Potential】
HIGHLY FLAMMABLE. |
| Accidental Release Measures | Back to Contents | 【Small spills/leaks】
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. |
| Stability and Reactivity | Back to Contents | 【Disposal Code】
9 | 【Stability】
Stable under normal temperatures and pressures. | 【Incompatibilities】
Strong oxidizing agents. | 【Decomposition】
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. | 【Combustion Products】
Fire will produce irritating, corrosive and/or toxic gases. |
|
| Company Name: |
Alfa Aesar |
| Tel: |
400-6106006 |
| Fax: |
021-67582001/03/05 |
| WebSite: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical |
| Tel: |
021-021-58432009 400-005-6266 |
| Fax: |
021-58436166 |
| WebSite: |
http://www.energy-chemical.com |
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