1,1'-FERROCENEDICARBOXALDEHYDE synthesis
- Product Name:1,1'-FERROCENEDICARBOXALDEHYDE
- CAS Number:1271-48-3
- Molecular formula:C12H10FeO210*
- Molecular Weight:242.05
2591-86-8
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$14.00/5g
102-54-5
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$5.00/25g
1271-48-3
113 suppliers
$45.00/100mg
Yield:1271-48-3 80%
Reaction Conditions:
with n-butyllithium;N,N,N,N,-tetramethylethylenediamine in diethyl ether;hexaneAr; ferrocene (53.8 mmol) suspnd. in hexane, hexane soln. of BuLi (107.5mmol) added, TMEDA (55.7 mmol) added dropwise, stirred at room temp. fo r 14 h, Et2O soln. of ligand (104.1 mmol) added dropwise, stirred for 30min; extd. (H2O), reextd. (CH2Cl2), org. layer washed (aq. HCl), dried (MgSO4), filtered, concd., chromd. (SiO2, CH2Cl2/hexane=1/1), dried;
References:
Barry, Kevin P.;Nataro, Chip [Inorganica Chimica Acta,2009,vol. 362,# 6,p. 2068 - 2070]
102-54-5
445 suppliers
$5.00/25g
1271-48-3
113 suppliers
$45.00/100mg
102-54-5
445 suppliers
$5.00/25g
93-61-8
283 suppliers
$10.00/5 g
12093-10-6
190 suppliers
$8.00/1g
1271-48-3
113 suppliers
$45.00/100mg