ChemicalBook CAS DataBase List Ferrocenecarboxaldehyde

Ferrocenecarboxaldehyde synthesis

7synthesis methods

Product Name:Ferrocenecarboxaldehyde
CAS Number:12093-10-6
Molecular formula:C11H10FeO10*
Molecular Weight:214.04

1273-86-5 Synthesis

1273-86-5
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$10.00/250mg

12093-10-6
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$8.00/1g

Yield:12093-10-6 92%

Reaction Conditions:

with ferrocene-labeled Merrifield resin-supported ionic liquid ([FemDMMerA]RuO₄) in tetrahydrofuran for 4 h;Reflux;Green chemistry;

Steps:

General procedure for the oxidation of alcohols
General procedure: A mixture of aryl alcohol (1 mmol) and [FemDMMerA]Y (100 mg) in solvent(5 mL) was refluxed in oil bath. After completion of the reaction as monitored byTLC, the reaction mixture was filtered to remove insoluble SILP catalyst.Evaporation of solvent in vacuuo followed by column chromatography over silicagel using petroleum ether/ethyl acetate (95:5 v/v) afforded pure aldehydes.

References:

Kurane, Rajanikant;Bansode, Prakash;Khanapure, Sharanabasappa;Salunkhe, Rajashri;Rashinkar, Gajanan [Research on Chemical Intermediates,2016,vol. 42,# 12,p. 7807 - 7821]

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102-54-5 Synthesis