9-Phenyl-3-[4-(1-phenyl-1H-benzimidazol-2-yl)phenyl]-9H-carbazole synthesis

5synthesis methods

Product Name:9-Phenyl-3-[4-(1-phenyl-1H-benzimidazol-2-yl)phenyl]-9H-carbazole
CAS Number:1294411-24-7
Molecular formula:C37H25N3
Molecular Weight:511.61

1153-85-1 Synthesis

1153-85-1
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4-(1-Phenyl-1H-benzimidazol-2-yl)phenylboronic acid

952514-79-3
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$45.00/100mg

9-Phenyl-3-[4-(1-phenyl-1H-benzimidazol-2-yl)phenyl]-9H-carbazole

1294411-24-7
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Yield:1294411-24-7 80%

Reaction Conditions:

with tetrakis(triphenylphosphine) palladium⁽⁰⁾;potassium carbonate in ethanol;water;toluene; for 6 h;Inert atmosphere;Reflux;

Steps:

2.3 Synthesis of BnImCz

3-BrPCz (6.44g, 0.02mol) was added to a three-necked flask, BnImBA (6.91g, 0.022mol), aqueous potassium carbonate (38.3g, 0.06mol), 100ml of toluene, 50ml of ethanol; under nitrogen with stirring was added Pd (PPh₃)₄(0.23g, 0.2mmol), after the replacement with nitrogen, the reaction was refluxed for 6 hours; after completion of the reaction, was cooled to room temperature, the layers were separated and the organic phase was washed with saturated aqueous sodium chloride solution until neutral, dried over anhydrous sodium sulfate and filtered to give a brown liquid; The solvent was removed by rotary evaporation, silica gel column, eluent V_{Petroleum ether}: V_{Ethyl acetate}= 1: 1 was purified to obtain the white solid in 80% yield.

References:

CN104370904,2016,B Location in patent:Paragraph 0062; 0067-0069

1153-85-1 Synthesis

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2620-76-0 Synthesis