ChemicalBook CAS DataBase List TRIETHYLSILANOL

TRIETHYLSILANOL synthesis

8synthesis methods

Product Name:TRIETHYLSILANOL
CAS Number:597-52-4
Molecular formula:C6H16OSi
Molecular Weight:132.28

617-86-7 Synthesis

617-86-7
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597-52-4
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$44.50/1g

Yield:597-52-4 100%

Reaction Conditions:

with 5%-palladium/activated carbon;water in ethyl acetate

Steps:

Triethylsilanol
To the suspension of Pd/C (5 wt %, 10 mg), water (465 μL, 25.8 mmol, 3.0 equiv) and EtOAc (10 mL) was added triethylsilane (1.0 g, 1.37 mL, 8.60 mmol, 1.0 equiv). Immediately after the addition of triethylsilane H2-formation 8 was observed. After thebubbling ended, the reaction mixture was filtered through a small pad of alumina(neutral) column eluted with EtOAc (20 mL). The filtrate was concentrated in vacuum to afford product 7 as a colorless oil (1.15 g, 8.6 mmol, Quant).

References:

Tuokko, Sakari;Pihko, Petri M. [Synlett,2016,vol. 27,# 11,art. no. ST-2016-B0177-L,p. 1649 - 1652] Location in patent:supporting information

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617-86-7 Synthesis

617-86-7
490 suppliers
$9.00/5g