| Identification | More | [Name]
N-NITROSOPIPERIDINE | [CAS]
100-75-4 | [Synonyms]
1-NITROSOPIPERIDINE
N-NITROSOPIPERIDINE
1-nitroso-piperidin
hexahydro-n-nitroso-pyridin
Nitrosopiperidin
N-Nitroso-piperidin
N-N-Pip
No-Pip
NPIP
n-pip
Pyridine, hexahydro-N-nitroso-
pyridine,hexahydro-n-nitroso
Rcra waste number U179
rcrawastenumberu179
tl266
N-NITROSOPIPERIDINE, 1X1ML, MEOH, 5000UG /ML
1-nitrosopiperidine solution
NITROSOPIPERIDINE
N-NITROSO-4-PIPERIDINE
N-NITROSOAPERIDINE | [EINECS(EC#)]
202-886-6 | [Molecular Formula]
C5H10N2O | [MDL Number]
MFCD00023652 | [Molecular Weight]
114.15 | [MOL File]
100-75-4.mol |
| Chemical Properties | Back Directory | [Appearance]
N-Nitrosopiperidine is a clear, yellow, oily
liquid. | [Melting point ]
170℃ (decomposition) | [Boiling point ]
219℃ | [density ]
1.06 g/mL(lit.)
| [refractive index ]
1.4933 (589.3 nm 19℃) | [Fp ]
11 °C | [storage temp. ]
2-8°C
| [form ]
buffered aqueous solution | [pka]
-3.18±0.20(Predicted) | [color ]
Light-yellow oil | [Stability:]
Stable. Combustible. Incompatible with strong oxidizing agents. | [Water Solubility ]
76.48g/L(24 ºC) | [CAS DataBase Reference]
100-75-4(CAS DataBase Reference) | [IARC]
2B (Vol. 17, Sup 7) 1987 | [EPA Substance Registry System]
N-Nitrosopiperidine (100-75-4) |
| Safety Data | Back Directory | [Hazard Codes ]
T,F | [Risk Statements ]
R25:Toxic if swallowed.
R40:Limited evidence of a carcinogenic effect.
R39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R11:Highly Flammable. | [Safety Statements ]
S53:Avoid exposure-obtain special instruction before use .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37:Wear suitable protective clothing and gloves .
S16:Keep away from sources of ignition-No smoking .
S9:Keep container in a well-ventilated place . | [RIDADR ]
UN 2810 6.1/PG 3
| [WGK Germany ]
3
| [RTECS ]
TN2100000
| [HazardClass ]
6.1(b) | [PackingGroup ]
III | [Safety Profile]
Confirmed carcinogen
with experimental carcinogenic,
neoplastigenic, and tumorigenic data. Poison
by ingestion, intravenous, and subcutaneous
routes. An experimental teratogen. Human
mutation data reported. When heated to
decomposition it emits toxic fumes of NOx.
See also N-NITROSO COMPOUNDS. | [Hazardous Substances Data]
100-75-4(Hazardous Substances Data) | [Toxicity]
LD50 orl-rat: 200 mg/kg ZEKBAI 69,103,67 |
| Hazard Information | Back Directory | [General Description]
Light yellow oil or liquid. May be a carcinogen. | [Reactivity Profile]
N-NITROSOPIPERIDINE(100-75-4) may react with strong oxidizing agents, especially peroxyacids. . | [Air & Water Reactions]
Water soluble. | [Health Hazard]
ACUTE/CHRONIC HAZARDS: When heated to decomposition this compound emits highly toxic fumes. | [Potential Exposure]
N-Nitrosopiperidine is found in some
foods and tobacco smoke. Used as a research chemical. | [Fire Hazard]
Flash point data are not available for this chemical, but N-NITROSOPIPERIDINE is probably combustible. | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately. If this chemical contacts the
skin, remove contaminated clothing and wash immediately
with soap and water. Seek medical attention immediately.
If this chemical has been inhaled, remove from exposure,
begin rescue breathing (using universal precautions, including
resuscitation mask) if breathing has stopped and CPR if
heart action has stopped. Transfer promptly to a medical
facility. When this chemical has been swallowed, get medical
attention. Give large quantities of water and induce
vomiting. Do not make an unconscious person vomit. | [Shipping]
UN2810 Toxic liquids, organic, n.o.s., Hazard
Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name
Required. UN3082 Environmentally hazardous substances,
liquid, n.o.s., Hazard Class: 9; Labels: 9-Miscellaneous hazardous
material, Technical Name Required | [Incompatibilities]
Nitrated organics range from slight to
strong oxidizing agents. If mixed with reducing agents,
including hydrides, sulfides and nitrides, they may begin a
vigorous reaction. Reaction with aliphatic amines can
release carcinogenic nitrosamines. Incompatible with oxidizers
(chlorates, nitrates, peroxides, permanganates, perchlorates,
chlorine, bromine, fluorine, etc.); contact may cause
fires or explosions. Keep away from alkaline materials,
strong bases, strong acids, oxoacids, epoxides. Light and
UV may cause decomposition | [Chemical Properties]
light yellow oily liquid | [Chemical Properties]
N-Nitrosopiperidine is a clear, yellow, oily
liquid. | [Waste Disposal]
Consult with environmental
regulatory agencies for guidance on acceptable disposal
practices. Generators of waste containing this contaminant
(≥100 kg/mo) must conform with EPA regulations governing
storage, transportation, treatment, and waste disposal.
Under 40 CFR 261.5 small quantity generators of this
waste may qualify for partial exclusion from hazardous
waste regulations. | [Uses]
A carcinogenic nitrosocompound. | [Definition]
ChEBI: A nitrosamine that is piperidine in which the hydrogen attached to the nitrogen is replaced by a nitroso group. One of the many carcinogens detected in cigarette smoke, it is found in meat, cheese and spices that have been treated with the preservative sod
um nitrite. | [Synthesis Reference(s)]
Chemical and Pharmaceutical Bulletin, 36, p. 459, 1988 DOI: 10.1248/cpb.36.459 | [Carcinogenicity]
N-Nitrosopiperidine is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals. |
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