| Identification | Back Directory | [Name]
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride | [CAS]
100163-29-9 | [Synonyms]
RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM
(R)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE
(S)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE
Rac-Ethylenebis(4,5,7-tetrahydro-1-indenyl)zirconium(Ⅳ)Dichloride
RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE
RAC-DICHLOROETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV)
DICHLORO[RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)]ZIRCONIUM(IV)
RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM(IV) DICHLORIDE
DICHLORO-(S,S)-ETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV)
DICHLORO-(R,R)-ETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV)
Dichloro[rel-(7aR,7′aR)-1,2-ethanediylbis[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]zirconium | [EINECS(EC#)]
202-303-5 | [Molecular Formula]
C20H24Cl2Zr 10* | [MDL Number]
MFCD00672123 | [MOL File]
100163-29-9.mol | [Molecular Weight]
426.53 |
| Chemical Properties | Back Directory | [Melting point ]
267-271 °C(lit.)
| [form ]
Powder | [color ]
white to pale yellow | [Sensitive ]
moisture sensitive | [InChI]
InChI=1S/C20H24.2ClH.Zr/c1-3-7-19-15(5-1)9-11-17(19)13-14-18-12-10-16-6-2-4-8-20(16)18;;;/h9-12H,1-8,13-14H2;2*1H;/q;;;+2/p-2 | [InChIKey]
AKXWJOYQORUUHS-UHFFFAOYSA-L | [SMILES]
[C]12[C]([CH][CH][C]1CCCC2)CC[C]1[CH][CH][C]2CCCC[C]12.[Zr](Cl)Cl |^1:0,1,2,3,4,11,12,13,14,19| |
| Questions And Answer | Back Directory | [Stability]
Stable under normal temperature and pressure, avoid contact with water and oxidants. | [Storage]
sealed storage, stored in a cool, dry warehouse. Keep away from oxidants, water sources. |
| Hazard Information | Back Directory | [Chemical Properties]
White to pale yellow powder,it can carry out catalytic reaction. | [Uses]
Catalyst for:
Regiochemistry in Negishi carboaluminations
Polymerization of olefins
Diastereoselective intramolecular olefin alkylations
Asymmetric carbomagnesiation
Reduction of esters to alcohols
Enantioselective synthesis of allylic amines | [Uses]
Rac-Ethylenebis(tetrahydroindenyl)zirconium Dichloride is a catalyst for enantioselective methylalumination of monosubstituted alkenes.The Kaminsky catalyst with co-catalyst methylaluminoxane (MAO) is a type of Ziegler-Natta catalyst, showing extremely high activity for polymerization of olefins such as ethylene, propylene, and styrene. | [reaction suitability]
core: zirconium
reagent type: catalyst |
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J & K SCIENTIFIC LTD.
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Sigma-Aldrich
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